Abstract: This work focuses on the remediation of polycyclic
aromatic hydrocarbons (PAHs)-contaminated soil via Fenton
treatment coupled with novel chelating agent (CA). The feasibility of
chelated modified Fenton (MF) treatment to promote PAH oxidation
in artificially contaminated soils was investigated in laboratory scale
batch experiments at natural pH. The effects of adding inorganic and
organic CA are discussed. Experiments using different iron catalyst
to CA ratios were conducted, resulting in hydrogen peroxide: soil:
iron: CA weight ratios that varied from 0.049: 1: 0.072: 0.008 to
0.049: 1: 0.072: 0.067. The results revealed that (1) inorganic CA
could provide much higher PAH removal efficiency and (2) most of
the proposed CAs were more efficient than commonly utilised CAs
even at mild ratio. This work highlights the potential of novel
chelating agents in maintaining a suitable environment throughout
the Fenton treatment, particularly in soils with high buffer capacity.
Abstract: The photochemical and photo-Fenton oxidation of 1,3-dichloro-2-propanol was performed in a batch reactor, at room temperature, using UV radiation, H2O2 as oxidant, and Fenton-s reagent. The effect of the oxidative agent-s initial concentration was investigated as well as the effect of the initial concentration of Fe(II) by following the target compound degradation, the total organic carbon removal and the chloride ion production. Also, from the kinetic analysis conducted and proposed reaction scheme it was deduced that the addition of Fe(II) significantly increases the production and the further oxidation of the chlorinated intermediates.
Abstract: The performance of modified Fenton (MF) treatment
to promote PAH oxidation in artificially contaminated soil was
investigated in packed soil column with a hydrogen peroxide (H2O2)
delivery system simulating in situ injection. Soil samples were spiked
with phenanthrene (low molecular weight PAH) and fluoranthene
(high molecular weight PAH) to an initial concentration of 500
mg/kg dried soil each. The effectiveness of process parameters
H2O2/soil, iron/soil, chelating agent/soil weight ratios and reaction
time were studied using a 24 three level factorial design experiments.
Statistically significant quadratic models were developed using
Response Surface Methodology (RSM) for degrading PAHs from the
soil samples. Optimum operating condition was achieved at mild
range of H2O2/soil, iron/soil and chelating agent/soil weight ratios,
indicating cost efficient method for treating highly contaminated
lands.
Abstract: As the Textile Industry is the second largest industry
in Egypt and as small and medium-sized enterprises (SMEs) make up
a great portion of this industry therein it is essential to apply the
concept of Cleaner Production for the purpose of reducing pollution.
In order to achieve this goal, a case study concerned with ecofriendly
stone-washing of jeans-garments was investigated. A raw
material-substitution option was adopted whereby the toxic
potassium permanganate and sodium sulfide were replaced by the
environmentally compatible hydrogen peroxide and glucose
respectively where the concentrations of both replaced chemicals
together with the operating time were optimized. In addition, a
process-rationalization option involving four additional processes
was investigated. By means of criteria such as product quality,
effluent analysis, mass and heat balance; and cost analysis with the
aid of a statistical model, a process optimization treatment revealed
that the superior process optima were 50%, 0.15% and 50min for
H2O2 concentration, glucose concentration and time, respectively.
With these values the superior process ought to reduce the annual
cost by about EGP 105 relative to the currently used conventional
method.
Abstract: All around the world pulp and paper industries are the
biggest plant production with the environmental pollution as the
biggest challenge facing the pulp manufacturing operations. The
concern among these industries is to produce a high volume of papers
with the high quality standard and of low cost without affecting the
environment. This result obtained from this bleaching study show
that the activation of peroxide was an effective method of reducing
the total applied charge of chlorine dioxide which is harmful to our
environment and also show that softwood and hardwood Kraft pulps
responded linearly to the peroxide treatments. During the bleaching
process the production plant produce chlorines. Under the trial stages
chloride dioxide has been reduced by 3 kg/ton to reduce the
brightness from 65% ISO to 60% ISO of pulp and the dosing point
returned to the E stage charges by pre-treating Kraft pulps with
hydrogen peroxide. The pulp and paper industry has developed
elemental chlorine free (ECF) and totally chlorine free (TCF)
bleaching, in their quest for being environmental friendly, they have
been looking at ways to turn their ECF process into a TCF process
while still being competitive. This prompted the research to
investigate the capability of the hydrogen peroxide as catalyst to
reduce chloride dioxide.
Abstract: The hydrogen peroxide treatment was able to
remediate chlorophenols, polycyclic aromatic hydrocarbons, diesel
and transformer oil contaminated soil. Chemical treatment of
contaminants adsorbed in peat resulted in lower contaminants-
removal and required higher addition of chemicals than the treatment
of contaminants in sand. The hydrogen peroxide treatment was found
to be feasible for soil remediation at natural soil pH. Contaminants in
soil could degrade with the addition of hydrogen peroxide only
indicating the ability of transition metals ions and minerals of these
metals presented in soil to catalyse the reaction of hydrogen peroxide
decomposition.
Abstract: Theobjective of this study was to evaluate the optimal
treatment condition of Fenton oxidation process to removal
contaminant in soil slurry contaminated by petroleum hydrocarbons.
This research studied somefactors that affect the removal efficiency
of petroleum hydrocarbons in soil slurry including molar ratio of
hydrogen peroxide (H2O2) to ferrous ion(Fe2+), pH condition and
reaction time.The resultsdemonstrated that the optimum condition
was that the molar ratio of H2O2:Fe3+ was 200:1,the pHwas 4.0and
the rate of reaction was increasing rapidly from starting point to 7th
hour and destruction kinetic rate (k) was 0.24 h-1. Approximately
96% of petroleum hydrocarbon was observed(initialtotal petroleum
hydrocarbon (TPH) concentration = 70±7gkg-1)
Abstract: The removal efficiency of 4-chlorophenol with
different advanced oxidation processes have been studied. Oxidation
experiments were carried out using two 4-chlorophenol
concentrations: 100 mg L-1 and 250 mg L-1 and UV generated from a
KrCl excilamp with (molar ratio H2O2: 4-chlorophenol = 25:1) and
without H2O2, and, with Fenton process (molar ratio H2O2:4-
chlorophenol of 25:1 and Fe2+ concentration of 5 mg L-1).
The results show that there is no significant difference in the 4-
chlorophenol conversion when using one of the three assayed
methods. However, significant concentrations of the photoproductos
still remained in the media when the chosen treatment involves UV
without hydrogen peroxide. Fenton process removed all the
intermediate photoproducts except for the hydroquinone and the
1,2,4-trihydroxybenzene. In the case of UV and hydrogen peroxide
all the intermediate photoproducts are removed.
Microbial bioassays were carried out utilising the naturally
luminescent bacterium Vibrio fischeri and a genetically modified
Pseudomonas putida isolated from a waste treatment plant receiving
phenolic waste. The results using V. fischeri show that with samples
after degradation, only the UV treatment showed toxicity (IC50 =38)
whereas with H2O2 and Fenton reactions the samples exhibited no
toxicity after treatment in the range of concentrations studied. Using
the Pseudomonas putida biosensor no toxicity could be detected for
all the samples following treatment due to the higher tolerance of the
organism to phenol concentrations encountered.
Abstract: The elimination of ranitidine (a pharmaceutical
compound) has been carried out in the presence of UV-C radiation.
After some preliminary experiments, it has been experienced the no
influence of the gas nature (air or oxygen) bubbled in photolytic
experiments. From simple photolysis experiments the quantum yield
of this compound has been determined. Two photolytic
approximation has been used, the linear source emission in parallel
planes and the point source emission in spherical planes. The
quantum yield obtained was in the proximity of 0.05 mol Einstein-1
regardless of the method used. Addition of free radical promoters
(hydrogen peroxide) increases the ranitidine removal rate while the
use of photocatalysts (TiO2) negatively affects the process.
Abstract: A sequential treatment of ozonation followed by a
Fenton or photo-Fenton process, using black light lamps (365 nm) in
this latter case, has been applied to remove a mixture of
pharmaceutical compounds and the generated by-products both in
ultrapure and secondary treated wastewater. The scientifictechnological
innovation of this study stems from the in situ
generation of hydrogen peroxide from the direct ozonation of
pharmaceuticals, and can later be used in the application of Fenton
and photo-Fenton processes. The compounds selected as models
were sulfamethoxazol and acetaminophen. It should be remarked that
the use of a second process is necessary as a result of the low
mineralization yield reached by the exclusive application of ozone.
Therefore, the influence of the water matrix has been studied in terms
of hydrogen peroxide concentration, individual compound
concentration and total organic carbon removed. Moreover, the
concentration of different iron species in solution has been measured.
Abstract: The C3 plants are frequently suffering from exposure
to high temperature stress which limits the growth and yield of these
plants. This study seeks to clarify the physiological mechanisms of
heat tolerance in relation to oxidative stress in C3 species. Fifteen C3
species were exposed to prolonged moderately high temperature
stress 36/30°C for 40 days in a growth chamber. Chlorophyll
fluorescence (Fv/Fm) showed great difference among species at 40
days of the stress. The species showed decreases in Fv/Fm and
increases in malondialdehyde (MDA) content under stress condition
as well as negative correlation between Fv/Fm and MDA (r = -0.61*)
at 40 days of the stress. Hydrogen peroxide (H2O2) content before
and after stress in addition to its response under stress showed great
differences among species. The results suggest that the difference in
heat tolerance among C3 species is closely associated with the ability
to suppress oxidative damage but not with the content of reactive
oxygen species (ROS) which is regulated by complex network.
Abstract: Green propellants used for satellite-level propulsion
system become attractive in recent years because the non-toxicity and
lower requirements of safety protection. One of the green propellants,
high-concentration hydrogen peroxide H2O2 solution (≥70% w/w,
weight concentration percentage), often known as high-test peroxide
(HTP), is considered because it is ITAR-free, easy to manufacture and
the operating temperature is lower than traditional monopropellant
propulsion. To establish satellite propulsion technology, the National
Space Organization (NSPO) in Taiwan has initialized a long-term
cooperation project with the National Cheng Kung University to
develop compatible tank and thruster. An experimental propulsion
payload has been allocated for the future self-reliant satellite to
perform orbit transfer and maintenance operations. In the present
research, an 1-Newton thruster prototype is designed and the thrusting
force is measured by a pendulum-type platform. The preliminary
hot-firing test at ambient environment showed the generated thrust and
the specific impulse are about 0.7 Newton and 102 seconds,
respectively.