Abstract: Lipases are enzymes particularly amenable for
immobilization by entrapment methods, as they can work equally
well in aqueous or non-conventional media and long-time stability of
enzyme activity and enantioselectivity is needed to elaborate more
efficient bioprocesses. The improvement of Pseudomonas
fluorescens (Amano AK) lipase characteristics was investigated by
optimizing the immobilization procedure in hybrid organic-inorganic
matrices using ionic liquids as additives. Ionic liquids containing a
more hydrophobic alkyl group in the cationic moiety are beneficial
for the activity of immobilized lipase. Silanes with alkyl- or aryl
nonhydrolizable groups used as precursors in combination with
tetramethoxysilane could generate composites with higher
enantioselectivity compared to the native enzyme in acylation
reactions of secondary alcohols. The optimal effect on both activity
and enantioselectivity was achieved for the composite made from
octyltrimethoxysilane and tetramethoxysilane at 1:1 molar ratio (60%
increase of total activity following immobilization and enantiomeric
ratio of 30). Ionic liquids also demonstrated valuable properties as
reaction media for the studied reactions, comparable with the usual
organic solvent, hexane.
Abstract: This study demonstrates the use of Class F fly ash in
combination with lime or lime kiln dust in the full depth reclamation
(FDR) of asphalt pavements. FDR, in the context of this paper, is a
process of pulverizing a predetermined amount of flexible pavement
that is structurally deficient, blending it with chemical additives and
water, and compacting it in place to construct a new stabilized base
course. Test sections of two structurally deficient asphalt pavements
were reclaimed using Class F fly ash in combination with lime and
lime kiln dust. In addition, control sections were constructed using
cement, cement and emulsion, lime kiln dust and emulsion, and mill
and fill. The service performance and structural behavior of the FDR
pavement test sections were monitored to determine how the fly ash
sections compared to other more traditional pavement rehabilitation
techniques. Service performance and structural behavior were
determined with the use of sensors embedded in the road and Falling
Weight Deflectometer (FWD) tests. Monitoring results of the FWD
tests conducted up to 2 years after reclamation show that the cement,
fly ash+LKD, and fly ash+lime sections exhibited two year resilient
modulus values comparable to open graded cement stabilized
aggregates (more than 750 ksi). The cement treatment resulted in a
significant increase in resilient modulus within 3 weeks of
construction and beyond this curing time, the stiffness increase was
slow. On the other hand, the fly ash+LKD and fly ash+lime test
sections indicated slower shorter-term increase in stiffness. The fly
ash+LKD and fly ash+lime section average resilient modulus values
at two years after construction were in excess of 800 ksi. Additional
longer-term testing data will be available from ongoing pavement
performance and environmental condition data collection at the two
pavement sites.
Abstract: Application of nanoparticles as additives in membrane
synthesis for improving the resistance of membranes against fouling
has triggered recent interest in new membrane types. However, most
nanoparticle-enhanced membranes suffer from the tradeoff between
permeability and selectivity. In this study, nano-WS2 was explored as
the additive in membrane synthesis by non-solvent induced phase
separation. Blended PES-WS2 flat-sheet membranes with the
incorporation of ultra-low concentrations of nanoparticles (from 0.025
to 0.25%, WS2/PES ratio) were manufactured and investigated in
terms of permeability, fouling resistance and solute rejection.
Remarkably, a significant enhancement in the permeability was
observed as a result of the incorporation of ultra-low fractions of
nano-WS2 to the membrane structure. Optimal permeability values
were obtained for modified membranes with 0.10%
nanoparticle/polymer concentration ratios. Furthermore, fouling
resistance and solute rejection were significantly improved by the
incorporation of nanoparticles into the membrane matrix. Specifically,
fouling resistance of modified membrane can increase by around 50%.
Abstract: Dynamic characteristics of a four-lobe journal bearing
of micropolar fluids are presented. Lubricating oil containing
additives and contaminants is modelled as micropolar fluid. The
modified Reynolds equation is obtained using the micropolar
lubrication theory and solving it by using finite difference technique.
The dynamic characteristics in terms of stiffness, damping
coefficients, the critical mass and whirl ratio are determined for
various values of size of material characteristic length and the
coupling number. The results show compared with Newtonian fluids,
that micropolar fluid exhibits better stability.