Abstract: Huge losses in apple production are caused by pathogens that cannot be seen shortly after harvest. After-harvest thermotherapy treatments can considerably improve control of storage diseases on apples and become an alternative to chemical pesticides. In the years 2010-2012 carried out research in this area. Apples of 'Topaz' cultivar were harvested at optimal maturity time for long storage and subject to water bath treatment at 45, 50, 52, 55°C for 60, 120, 180 and 240 seconds. The control was untreated fruits. After 12 and 24 weeks and during so called simulated trade turnover the fruits were checked for their condition and the originators of diseases were determined by using the standard phytopathological methods. The most common originator of 'Topaz' apple infection during storage were the fungi of genus Gloeosporium. In this paper it was proven that for effective protection of 'Topaz' apples against diseases, thermotherapy by using water treatments at temperature range of 50-52°C is quite sufficient.
Abstract: This paper describes technological possibilities to
enhance methane productionin the anaerobic stabilization of wastewater treatment plant excess sludge. This objective can be achieved by the addition of waste residues: crude glycerol from biodiesel production and residues from fishery. The addition
ofglycerol in an amount by weight of 2 – 5% causes enhancement of methane production of about 250 – 400%. At the same time the
percentage increase of total solids concentration in the outgoing sludge is ten or more times less. The containment of methane in
biogas is higher in case of admixed substrate.
Abstract: The abundance and availability of rice husk, an agricultural waste, make them as a good source for precursor of activated carbon. In this work, rice husk-based activated carbons were prepared via base treated chemical activation process prior the carbonization process. The effect of carbonization temperatures (400, 600 and 800oC) on their pore structure was evaluated through morphology analysis using scanning electron microscope (SEM). Sample carbonized at 800oC showed better evolution and development of pores as compared to those carbonized at 400 and 600oC. The potential of rice husk-based activated carbon as an alternative adsorbent was investigated for the removal of Ni(II), Zn(II) and Pb(II) from single metal aqueous solution. The adsorption studies using rice husk-based activated carbon as an adsorbent were carried out as a function of contact time at room temperature and the metal ions were analyzed using atomic absorption spectrophotometer (AAS). The ability to remove metal ion from single metal aqueous solution was found to be improved with the increasing of carbonization temperature. Among the three metal ions tested, Pb(II) ion gave the highest adsorption on rice husk-based activated carbon. The results obtained indicate the potential to utilize rice husk as a promising precursor for the preparation of activated carbon for removal of heavy metals.
Abstract: Excilamps are new UV sources with great potential
for application in wastewater treatment. In the present work, a XeBr
excilamp emitting radiation at 283 nm has been used for the
photodegradation of 4-chlorophenol within a range of concentrations
from 50 to 500 mg L-1. Total removal of 4-chlorophenol was
achieved for all concentrations assayed. The two main photoproduct
intermediates formed along the photodegradation process,
benzoquinone and hydroquinone, although not being completely
removed, remain at very low residual concentrations. Such
concentrations are insignificant compared to the 4-chlorophenol
initial ones and non-toxic. In order to simulate the process and scaleup,
a kinetic model has been developed and validated from the
experimental data.
Abstract: A unique combination of adsorption and
electrochemical regeneration with a proprietary adsorbent material
called Nyex 100 was introduced at the University of Manchester for
waste water treatment applications. Nyex 100 is based on graphite
intercalation compound. It is non porous and electrically conducing
adsorbent material. This material exhibited very small BET surface
area i.e. 2.75 m2g-1, in consequence, small adsorptive capacities for
the adsorption of various organic pollutants were obtained. This work
aims to develop composite adsorbent material essentially capable of
electrochemical regeneration coupled with improved adsorption
characteristics. An organic dye, acid violet 17 was used as standard
organic pollutant. The developed composite material was
successfully electrochemically regenerated using a DC current of 1 A
for 60 minutes. Regeneration efficiency was maintained at around
100% for five adsorption-regeneration cycles.
Abstract: The purpose of this research was develop a biological
nutrient removal (BNR) system which has low energy consumption, sludge production, and land usage. These indicate that BNR system could be a alternative of future wastewater treatment in ubiquitous
city(U-city). Organics and nitrogen compounds could be removed by this system so that secondary or tertiary stages of wastewater treatment satisfy their standards. This system was composed of oxic and anoxic
filter filed with PVDC and POM media. Anoxic/oxic filter system operated under empty bed contact time of 4 hours by increasing
recirculation ratio from 0 to 100 %. The system removals of total nitrogen and COD were 76.3% and 93%, respectively. To be observed
internal behavior in this system SCOD, NH3-N, and NO3-N were
conducted and removal shows range of 25~100%, 59~99%, and
70~100%, respectively.
Abstract: The Beshar River is one aquatic ecosystem, which is
located next to the city of Yasuj in southern Iran. The Beshar river
has been contaminated by industrial factories such as effluent of
sugar factory, agricultural and other activities in this region such as,
Imam Sajjad hospital, drainage from agricultural farms, Yasuj urban
surface runoff and effluent of wastewater treatment plants ,specially
Yasuj waste water treatment plant. In order to evaluate the effects of
these pollutants on the quality of the Beshar river, five monitoring
stations were selected along its course. The first station is located
upstream of Yasuj near the Dehnow village; stations 2 to 4 are
located east, south and west of city; and the 5th station is located
downstream of Yasuj. Several water quality parameters were
sampled. These include pH, dissolved oxygen, biological oxygen
demand (BOD), temperature, conductivity, turbidity, total dissolved
solids and discharge or flow measurements. Water samples from the
five stations were collected and analyzed to determine the following
physicochemical parameters: EC, pH, T.D.S, T.H, No2, DO, BOD5,
COD during 2008 to 2010. The study shows that the BOD5 value of
station 1 is at a minimum (1.7 ppm) and increases downstream from
stations 2 to 4 to a maximum (11.6 ppm), and then decreases at
station 5. The DO values of station 1 is a maximum (8.45 ppm),
decreases downstream to stations 2 - 4 which are at a minimum (3.1
ppm), before increasing at station 5. The amount of BOD and TDS
are highest at the 4th station and the amount of DO is lowest at this
station, marking the 4th station as more highly polluted than the
other stations .This study shows average amount of the water quality
parameters in first year of sampling (2008) have had a better quality
relation to third year in 2010 because of recent drought in this region
and pollutant increasing .As the Beshar river path after 5th station
goes through the mountain area with more slope and flow velocity
,so the physicochemical parameters improve at the 5th station due to
pollutant degradation and dilution. Finally the point and nonpoint
pollutant sources of Beshar river were determined and compared to
the monitoring results.
Abstract: Perth will run out of available sustainable natural
water resources by 2015 if nothing is done to slow usage rates,
according to a Western Australian study [1]. Alternative water
technology options need to be considered for the long-term
guaranteed supply of water for agricultural, commercial, domestic
and industrial purposes. Seawater is an alternative source of water for
human consumption, because seawater can be desalinated and
supplied in large quantities to a very high quality.
While seawater desalination is a promising option, the technology
requires a large amount of energy which is typically generated from
fossil fuels. The combustion of fossil fuels emits greenhouse gases
(GHG) and, is implicated in climate change. In addition to
environmental emissions from electricity generation for desalination,
greenhouse gases are emitted in the production of chemicals and
membranes for water treatment. Since Australia is a signatory to the
Kyoto Protocol, it is important to quantify greenhouse gas emissions
from desalinated water production.
A life cycle assessment (LCA) has been carried out to determine
the greenhouse gas emissions from the production of 1 gigalitre (GL)
of water from the new plant. In this LCA analysis, a new desalination
plant that will be installed in Bunbury, Western Australia, and known
as Southern Seawater Desalinization Plant (SSDP), was taken as a
case study. The system boundary of the LCA mainly consists of three
stages: seawater extraction, treatment and delivery. The analysis
found that the equivalent of 3,890 tonnes of CO2 could be emitted
from the production of 1 GL of desalinated water. This LCA analysis
has also identified that the reverse osmosis process would cause the
most significant greenhouse emissions as a result of the electricity
used if this is generated from fossil fuels
Abstract: “Garbage enzyme", a fermentation product of kitchen waste, water and brown sugar, is claimed in the media as a multipurpose solution for household and agricultural uses. This study assesses the effects of dilutions (5% to 75%) of garbage enzyme in reducing pollutants in domestic wastewater. The pH of the garbage enzyme was found to be 3.5, BOD concentration about 150 mg/L. Test results showed that the garbage enzyme raised the wastewater-s BOD in proportion to its dilution due to its high organic content. For mixtures with more than 10% garbage enzyme, its pH remained acidic after the 5-day digestion period. However, it seems that ammonia nitrogen and phosphorus could be removed by the addition of the garbage enzyme. The most economic solution for removal of ammonia nitrogen and phosphorus was found to be 9%. Further tests are required to understand the removal mechanisms of the ammonia nitrogen and phosphorus.
Abstract: The growth of the aquaculture industry has been
associated with negative environmental impacts through the
discharge of raw effluents into the adjacent receiving water bodies.
Macrophytes from natural saline lakes, which have adaptability to the
high salinity, can be suitable for saline effluent treatment. Eight
emergent species from natural saline area were planted in an
experimental gravel bed hydroponic mesocosm (GBH) which was
treated with effluent water from an intensive fish farm using
geothermal water. In order to examine the applicability of the
halophytes in treatment processes, we tested the relative efficacy of
total nitrogen (TN), total phosphorus (TP), potassium (K), sodium
(Na), magnesium (Mg) and calcium (Ca) removal for the saline
wastewater treatment. Four of the eight species, which were
Phragmites australis, Typha angustifolia, Glyceria maxima, Scirpus
lacustris spp. tabernaemontani could survive and contribute the
experimental treatment.
Abstract: From environmental aspect purification of ammonia
containing wastewater is expected. High efficiency ammonia
desorption can be done from the water by air on proper temperature.
After the desorption process, ammonia can be recovered and used in
another technology. The calculation method described below give
some methods to find either the minimum column height or ammonia
rich solution of the effluent.
Abstract: Water pollution assessment problems arise frequently
in environmental science. In this research, a finite difference method
for solving the one-dimensional steady convection-diffusion equation
with variable coefficients is proposed; it is then used to optimize
water treatment costs.
Abstract: Chicken feathers were used as biosorbent for Pb
removal from aqueous solution. In this paper, the kinetics and
equilibrium studies at several pH, temperature, and metal
concentration values are reported. For tested conditions, the Pb
sorption capacity of this poultry waste ranged from 0.8 to 8.3 mg/g.
Optimal conditions for Pb removal by chicken feathers have been
identified. Pseudo-first order and pseudo-second order equations
were used to analyze the experimental data. In addition, the sorption
isotherms were fitted to classical Langmuir and Freundlich models.
Finally, thermodynamic parameters for the sorption process have
been determined. In summary, the results showed that chicken
feathers are an alternative and promising sorbent for the treatment of
effluents polluted by Pb ions.
Abstract: Magnetic and semiconductor nanomaterials exhibit
novel magnetic and optical properties owing to their unique size and
shape-dependent effects. With shrinking the size down to nanoscale
region, various anomalous properties that normally not present in bulk
start to dominate. Ability in harnessing of these anomalous properties
for the design of various advance electronic devices is strictly
dependent on synthetic strategies. Hence, current research has focused
on developing a rational synthetic control to produce high quality
nanocrystals by using organometallic approach to tune both size and
shape of the nanomaterials. In order to elucidate the growth
mechanism, transmission electron microscopy was employed as a
powerful tool in performing real time-resolved morphologies and
structural characterization of magnetic (Fe3O4) and semiconductor
(ZnO) nanocrystals. The current synthetic approach is found able to
produce nanostructures with well-defined shapes. We have found that
oleic acid is an effective capping ligand in preparing oxide-based
nanostructures without any agglomerations, even at high temperature.
The oleate-based precursors and capping ligands are fatty acid
compounds, which are respectively originated from natural palm oil
with low toxicity. In comparison with other synthetic approaches in
producing nanostructures, current synthetic method offers an effective
route to produce oxide-based nanomaterials with well-defined shapes
and good monodispersity. The nanocystals are well-separated with
each other without any stacking effect. In addition, the as-synthesized
nanopellets are stable in terms of chemically and physically if
compared to those nanomaterials that are previous reported. Further
development and extension of current synthetic strategy are being
pursued to combine both of these materials into nanocomposite form
that will be used as “smart magnetic nanophotocatalyst" for industry
waste water treatment.
Abstract: Shortening of natural resources will impose greater
limitations of electric energy consumption in various fields including
water treatment technologies. Small water treatment installations
supplied with electric energy from solar sources are perfect example of
zero-emission technology. Possibility of solar energy application, as
one of the alternative energy resources for decontamination processes
is strongly dependent on geographical location. Various examples of
solar driven water purification systems are given and design of
solar-water treatment installation based on ozone for the geographical
conditions in Poland are presented.
Abstract: The present study focuses on the discussion over the
parameter of Artificial Neural Network (ANN). Sensitivity analysis is
applied to assess the effect of the parameters of ANN on the prediction
of turbidity of raw water in the water treatment plant. The result shows
that transfer function of hidden layer is a critical parameter of ANN.
When the transfer function changes, the reliability of prediction of
water turbidity is greatly different. Moreover, the estimated water
turbidity is less sensitive to training times and learning velocity than
the number of neurons in the hidden layer. Therefore, it is important to
select an appropriate transfer function and suitable number of neurons
in the hidden layer in the process of parameter training and validation.
Abstract: A laboratory set-up was designed to survey the
effectiveness of UV/O3 advanced oxidation process (AOP) for the
removal of Carbaryl from polluted water in batch reactor. The study
was carried out by UV/O3 process for water samples containing 1 to
20 mg/L of Carbaryl in distilled water. Also the range of drinking
water resources adjusted in synthetic water and effects of contact
time, pH and Carbaryl concentration were studied. The residual
pesticide concentration was determined by applying high
performance liquid chromatography (HPLC). The results indicated
that increasing of retention time and pH, enhances pesticide removal
efficiency. The removal efficiency has been affected by pesticide
initial concentration. Samples with low pesticide concentration
showed a remarkable removal efficiency compared to the samples
with high pesticide concentration. AOP method showed the removal
efficiencies of 80% to 100%. Although process showed high
performance for removal of pesticide from water samples, this
process has different disadvantages including complication,
intolerability, difficulty of maintenance and equipmental and
structural requirements.
Abstract: Residual dye contents in textile dyeing wastewater have complex aromatic structures that are resistant to degrade in biological wastewater treatment. The objectives of this study were to determine the effectiveness of nanoscale zerovalent iron (NZVI) to decolorize Reactive Black 5 (RB5) and Reactive Red 198 (RR198) in synthesized wastewater and to investigate the effects of the iron particle size, iron dosage and solution pHs on the destruction of RB5 and RR198. Synthesized NZVI was confirmed by transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The removal kinetic rates (kobs) of RB5 (0.0109 min-1) and RR198 (0.0111 min-1) by 0.5% NZVI were many times higher than those of microscale zerovalent iron (ZVI) (0.0007 min-1 and 0.0008 min-1, respectively). The iron dosage increment exponentially increased the removal efficiencies of both RB5 and RR198. Additionally, lowering pH from 9 to 5 increased the decolorization kinetic rates of both RB5 and RR198 by NZVI. The destruction of azo bond (N=N) in the chromophore of both reactive dyes led to decolorization of dye solutions.
Abstract: The main objective of this study was to remove and recover Ni, Cu and Fe from a mixed metal system using sodium hypophosphite as a reducing agent and nickel powder as seeding material. The metal systems studied consisted of Ni-Cu, Ni-Fe and Ni-Cu-Fe solutions. A 5 L batch reactor was used to conduct experiments where 100 mg/l of each respective metal was used. It was found that the metals were reduced to their elemental form with removal efficiencies of over 80%. The removal efficiency decreased in the order Fe>Ni>Cu. The metal powder obtained contained between 97-99% Ni and was almost spherical and porous. Size enlargement by aggregation was the dominant particulate process.
Abstract: Coagulation of water involves the use of coagulating
agents to bring the suspended matter in the raw water together for
settling and the filtration stage. Present study is aimed to examine the
effects of aluminum sulfate as coagulant in conjunction with Moringa
Oleifera Coagulant Protein as coagulant aid on turbidity, hardness,
and bacteria in turbid water. A conventional jar test apparatus was
employed for the tests. The best removal was observed at a pH of 7
to 7.5 for all turbidities. Turbidity removal efficiency was resulted
between % 80 to % 99 by Moringa Oleifera Coagulant Protein as
coagulant aid. Dosage of coagulant and coagulant aid decreased with
increasing turbidity. In addition, Moringa Oleifera Coagulant Protein
significantly has reduced the required dosage of primary coagulant.
Residual Al+3 in treated water were less than 0.2 mg/l and meets the
environmental protection agency guidelines. The results showed that
turbidity reduction of % 85.9- % 98 paralleled by a primary
Escherichia coli reduction of 1-3 log units (99.2 – 99.97%) was
obtained within the first 1 to 2 h of treatment. In conclusions,
Moringa Oleifera Coagulant Protein as coagulant aid can be used for
drinking water treatment without the risk of organic or nutrient
release. We demonstrated that optimal design method is an efficient
approach for optimization of coagulation-flocculation process and
appropriate for raw water treatment.