Abstract: The production of Dimethyl acetal, Isovaleradehyde and Pyridine were simulated using Aspen Plus simulation. Upgrading cleaning water from wine industrial production is the main objective of the project. The winery waste composes of Acetaldehyde, Methanol, Ethyl Acetate, 1-propanol, water, iso-amyl alcohol and iso-butyl alcohol. The project is separated into three parts; separation, reaction, and purification. Various processes were considered to maximize the profit along with obtaining high purity and recovery of each component with optimum heat duty. The results show a significant value of the product with purity more than 75% and recovery over 98%.
Abstract: Sulfide ion (S2-) is one of the most important ions to be
monitored due to its high toxicity, especially for aquatic organisms. In
this work, [Ca(2,2'-bipyridine)3]2+-intercalated montmorillonite was
prepared and used as a sensor to construct a potentiometric electrode to
measure sulfide ion in solution. The formation of [Ca(2,2'-
bipyridine)3]2+ in montmorillonite was confirmed by Fourier Transform
Infrared spectra. The electrode worked well at pH 4-12 and 4-10 in
sulfide solution 10-2 M and 10-3 M, respectively, in terms of Nernstian
slope. The sensor gave good precision and low cost.