Abstract: Land use change, if not based on proper scientific
investigation affects other physical, chemical, and biological
properties of soil and leading to increased destruction and erosion. It
was imperative to study the effects of changing rangelands to
farmlands on some Soil quality indexes. Undisturbed soil samples
were collected from the depths of 0-10 and 10-30 centimeter in
pasture with good vegetation cover(GP), pasture with medium
vegetation cover(MP), abandoned dry land farming(ADF) and
degraded dry land farming(DDF) land uses in Ghareh Aghaj
watershed of Isfahan province. The results revealed that organic
matter(OM), cation exchange capacity(CEC) and available
potassium(AK) decreasing in the depth of 0-10 centimeter were 66.6,
38.8 and 70 percent and in the depth of 10-30 centimeter were 58,
61.4 and 83.5 percent respectively in DDF comparison with GP.
Concerning to the results, it seems that land use change can decrease
soil quality and increase soil degradation and lead in undesirable
consequences.
Abstract: There are few studies on eggshell of leatherback turtle
which is endangered species in Thailand. This study was focusing on
the ultrastructure and elemental composition of leatherback turtle
eggshells collected from Andaman Sea Shore, Thailand during the
nesting season using scanning electron microscope (SEM). Three
eggshell layers of leatherback turtle; the outer cuticle layer or
calcareous layer, the middle layer or middle multistrata layer and the
inner fibrous layer were recognized. The outer calcareous layer was
thick and porosity which consisted of loose nodular units of various
crystal shapes and sizes. The loose attachment between these units
resulted in numerous spaces and openings. The middle layer was
compact thick with several multistrata and contained numerous
openings connecting to both outer cuticle layer and inner fibrous
layer. The inner fibrous layer was compact and thin, and composed of
numerous reticular fibers. Energy dispersive X-ray microanalysis
detector revealed energy spectrum of X-rays character emitted from
all elements on each layer. The percentages of all elements were
found in the following order: carbon (C) > oxygen (O) > calcium
(Ca) > sulfur (S) > potassium (K) > aluminum (Al) > iodine (I) >
silicon (Si) > chlorine (Cl) > sodium (Na) > fluorine (F) >
phosphorus (P) > magnesium (Mg). Each layer consisted of high
percentage of CaCO3 (approximately 98%) implying that it was
essential for turtle embryonic development. A significant difference
was found in the percentages of Ca and Mo in the 3layers. Moreover,
transition metal, metal and toxic non-metal contaminations were
found in leatherback turtle eggshell samples. These were palladium
(Pd), molybdenum (Mo), copper (Cu), aluminum (Al), lead (Pb), and
bromine (Br). The contamination elements were seen in the outer
layers except for Mo. All elements were readily observed and
mapped using Smiling program. X-ray images which mapped the
location of all elements were showed. Calcium containing in the
eggshell appeared in high contents and was widely distributing in
clusters of the outer cuticle layer to form CaCO3 structure. Moreover,
the accumulation of Na and Cl was observed to form NaCl which was
widely distributing in 3 eggshell layers. The results from this study
would be valuable on assessing the emergent success in this
endangered species.
Abstract: In this study, we used a two-stage process and
potassium hydroxide (KOH) to transform waste biomass (rice straw)
into activated carbon and then evaluated the adsorption capacity of the
waste for removing carbofuran from an aqueous solution. Activated
carbon was fast and effective for the removal of carbofuran because of
its high surface area. The native and carbofuran-loaded adsorbents
were characterized by elemental analysis. Different adsorption
parameters, such as the initial carbofuran concentration, contact time,
temperature and pH for carbofuran adsorption, were studied using a
batch system. This study demonstrates that rice straw can be very
effective in the adsorption of carbofuran from bodies of water.
Abstract: In this study, the possibility of using potato as a
substrate for glutamic acid production by Brevibacterium linens
was investigated. For preparation of fermentation medium, potato
was hydrolyzed by hydrochloridric acid. The medium contained
potato hydrolysate, tween 80, mineral solution, glucose, and
potassium hydrogen phosphate. The initial pH of the medium was
adjusted to 7-7.5. For achieving the optimum time with maximum
yield, the beakers containing the medium and the inoculums were
incubated in a rotary water bath flask shaker for one to five days.
Thin layer choromatography was used for quantitative and
qualitative assay of the glutamic acid produced. The results
revealed that as fermentation time increased, pH of the
fermentation medium significantly decreased (P
Abstract: Chicken fat was employed as a feedstock for
producing of biodiesel by trasesterification reaction with methanol
and alkali catalyst (KOH). In this study chicken fat biodiesel with
1.4% free fatty acid, methanol and various amount of potassium
hydroxide for 2 hour were studied. The progression of reaction and
conversion of triglycerides to methyl ester were checked by IR
spectrum method.
Abstract: In this paper spatial variability of some chemical and
physical soil properties were investigated in mountain rangelands of
Nesho, Mazandaran province, Iran. 110 soil samples from 0-30 cm
depth were taken with systematic method on grid 30×30 m2 in
regions with different vegetation cover and transported to laboratory.
Then soil chemical and physical parameters including Acidity (pH),
Electrical conductivity, Caco3, Bulk density, Particle density, total
phosphorus, total Nitrogen, available potassium, Organic matter,
Saturation moisture, Soil texture (percentage of sand, silt and clay),
Sodium, Calcium, magnesium were measured in laboratory. Data
normalization was performed then was done statistical analysis for
description of soil properties and geostatistical analysis for indication
spatial correlation between these properties and were perpetrated
maps of spatial distribution of soil properties using Kriging method.
Results indicated that in the study area Saturation moisture and
percentage of Sand had highest and lowest spatial correlation
respectively.
Abstract: For sterilization of Phalaenopsis culture medium without autoclaving, selected single sterilizing agents and in combinations were added to a 25ml Hyponex medium in a 120ml glass container. Treated liquid and solid media, supplemented with sterilizing agents, were compared to a control medium, autoclaved at 121°C for 15min. It was found that 90(L of 10% povidone-iodine, 150(L of 5.25% sodium hypochlorite, 150(L of 2% mercurochrome, 90(L of 2.5% iodine + 2.5% potassium iodine in combination with 10% providone-iodine (1:3) and 30(L of 2.5% iodine + 2.5% potassium iodide in combination with 2% mercurochrome showed 100% sterile conditions in liquid medium but provided 75, 100, 50, 75 and 80% sterile conditions, respectively, in solid medium. For growth of Phalaenopsis protocorms, 90(L of 10% povidone-iodine in liquid Hyponex medium gave the comparable growth of protocorms to control medium while 150(L of 5.25% sodium hypochlorite in solid medium provided the promising growth of protocorms. Growth of protocorms, whole fresh weight, numbers of leaf and root, root length and number of protocorm-like bodies, was discussed.
Abstract: Palladium-catalyzed hydrodechlorination is a
promising alternative for the treatment of environmentally relevant
water bodies, such as groundwater, contaminated with chlorinated
organic compounds (COCs). In the aqueous phase
hydrodechlorination of COCs, Pd-based catalysts were found to have
a very high catalytic activity. However, the full utilization of the
catalyst-s potential is impeded by the sensitivity of the catalyst to
poisoning and deactivation induced by reduced sulfur compounds
(e.g. sulfides). Several regenerants have been tested before to recover
the performance of sulfide-fouled Pd catalyst. But these only
delivered partial success with respect to re-establishment of the
catalyst activity. In this study, the deactivation behaviour of
Pd/Al2O3 in the presence of sulfide was investigated. Subsequent to
total deactivation the catalyst was regenerated in the aqueous phase
using potassium permanganate. Under neutral pH condition,
oxidative regeneration with permanganate delivered a slow recovery
of catalyst activity. However, changing the pH of the bulk solution to
acidic resulted in the complete recovery of catalyst activity within a
regeneration time of about half an hour. These findings suggest the
superiority of permanganate as regenerant in re-activating Pd/Al2O3
by oxidizing Pd-bound sulfide.
Abstract: Field experiment was conducted to investigate the combine use of animal manure and inorganic fertilizer on growth and yield performance of vegetable cowpea. The experiment was laid out in a Randomized Complete Block Design (RCBD) with seven treatments. Poultry manure, cattle manure and goat manure were evaluated with recommended level of inorganic fertilizer for vegetable cowpea. The highest crop yield was obtained by the application of poultry manure combined with the recommended level of inorganic fertilizer. The lowest yield was obtained by the application of goat manure only. In addition, the results revealed that the goat manure and cattle manure were inferior to poultry manure as a source of organic manure for vegetable cowpea cultivation. The animal manure combine with chemical fertilizer gave a higher yield when compared to the sole application of animal manure. The soil analysis showed that the nitrogen content and phosphorus content of poultry manure treated plots were higher than other treatments tested. But potassium content was higher in goat manure treated plots. The results further revealed that the poultry manure has a beneficial effect on crop growth and yield compared with other treatments. Therefore, the combined use of poultry manure with inorganic fertilizer application has been recognized as the most suitable way of ensuring high crop yield.
Abstract: Potassium monopersulfate has been decomposed in aqueous solution in the presence of Co(II). The process has been simulated by means of a mechanism based on elementary reactions. Rate constants have been taken from literature reports or, alternatively, assimilated to analogous reactions occurring in Fenton's chemistry. Several operating conditions have been successfully applied.
Abstract: Characterized as rich mineral substances, low
temperature, few bacteria, and stability with numerous implementation
aspects on aquaculture, food, drinking, and leisure, the deep sea water
(DSW) development has become a new industry in the world. It has
been report that marine algae contain various biologically active
compounds. This research focued on the affections in cultivating
Sagrassum cristaefolium with different concentration of deep sea
water(DSW) and surface sea water(SSW). After two and four weeks,
the total phenolic contents were compared in Sagrassum cristaefolium
culturing with different ways, and the reductive activity of them was
also be tried with potassium ferricyanide. Those fresh seaweeds were
dried with oven and were ground to powder. Progressively, the marine
algae we cultured was extracted by water under the condition with
heating them at 90Ôäâ for 1hr.The total phenolic contents were be
executed using Folin–Ciocalteu method. The results were explaining
as follows: the highest total phenolic contents and the best reductive
ability of all could be observed on the 1/4 proportion of DSW to SSW
culturing in two weeks. Furthermore, the 1/2 proportion of DSW to
SSW also showed good reductive ability and plentiful phenolic
compositions. Finally, we confirmed that difference proportion of
DSW and SSW is the major point relating to ether the total phenolic
components or the reductive ability in the Sagrassum cristaefolium. In
the future, we will use this way to mass production the marine algae or
other micro algae on industry applications.
Abstract: Potassium monopersulfate has been decomposed in
aqueous solution in the presence of Co(II). The effect of the main
operating variables has been assessed. Minimum variations in pH
exert a considerable influence on the process kinetics. Thus, when no
pH adjustment is considered, the actual effect of variables like initial
monopersulfate and/or catalyst concentration may be hindered. As
expected, temperature enhances the monopersulfate decomposition
rate by following the Arrhenius law. The activation energy in the
proximity of 85 kJ/mol has been obtained. Amongst the different
solids tested in the monopersulfate decomposition, only the
perovskite LaTi0.15Cu0.85O3 has shown a significant catalytic activity.
Abstract: Categorical data based on description of the
agricultural landscape imposed some mathematical and analytical
limitations. This problem however can be overcome by data
transformation through coding scheme and the use of non-parametric
multivariate approach. The present study describes data
transformation from qualitative to numerical descriptors. In a
collection of 103 random soil samples over a 60 hectare field,
categorical data were obtained from the following variables: levels of
nitrogen, phosphorus, potassium, pH, hue, chroma, value and data on
topography, vegetation type, and the presence of rocks. Categorical
data were coded, and Spearman-s rho correlation was then calculated
using PAST software ver. 1.78 in which Principal Component
Analysis was based. Results revealed successful data transformation,
generating 1030 quantitative descriptors. Visualization based on the
new set of descriptors showed clear differences among sites, and
amount of variation was successfully measured. Possible applications
of data transformation are discussed.
Abstract: The aim of this study was to investigate ammonium
exchange capacity of natural and activated clinoptilolite from
Kwazulu-Natal Province, South Africa. X – ray fluorescence (XRF)
analysis showed that the clinoptilolite contained exchangeable ions
of sodium, potassium, calcium and magnesium. This analysis also
confirmed that the zeolite sample had a high silicon composition
compared to aluminium. Batch equilibrium studies were performed
in an orbital shaker and the data fitted the Langmuir isotherm very
well. The ammonium exchange capacity was found to increase with
pH and temperature. Clinoptilolite functionalization with
hydrochloric acid increased its ammonia uptake ability.
Abstract: In this study, The physico-chemical and nutritional
properties of `Musmula` Medlar (Mespilus germanica L.) fruit and
seed grown in Northeast Anatolia was investigated. In the fruit,
length, width, thickness, weight, total soluble solids, colour (1),
colour (2) [L, a, b values], protein, crude ash, crude fiber, crude oil,
texture and pH were determinated as 4.34 cm, 4.22 cm, 3.67 cm,
38.36 g, 23.97 %, S60O60Y41,, [53.85, 17.15, 33.75], 1.06 %, 0.79 %,
4.24 %, 0.005 %, 1.21 kg/cm2 and 4.26 respectively. Also, pulp ratio,
seed ratio and pulp/seed ratio were found to be 92.88 %, 7.11 % and
14.07 %, respectively. In addition, the mineral composition of medlar
fruit in Northeast Anatolia was studied. In the fruit, 23 minerals were
analyzed and 19 minerals were present at detectable levels. The
medlar fruit was richest in potassium (6962 ppm), calcium (1186.378
ppm), magnesium (1070.08 ppm) and phosphor (763.425 ppm).
Abstract: The use of bioindicators plants (lichens, bryophytes
and Sphagnum....) in monitoring pollution by heavy metals has been
the subject of several works. However, few studies have addressed
the impact of specific type-s pollutants (fertilizers, pesticides.) on
these organisms.
We propose in this work to make the highlighting effect of NPKs
(NPK: nitrogen-phosphate-potassium-sulfate (NP2O5K2O) (15,15,15),
at concentrations of 10, 20, 30 , 40 and 50mM/L) on the activity of
detoxification enzymes (GSH/GST, CAT, APX and MDA) of plant
bioindicators (mosses and lichens) after treatment for 3 and 7 days.
This study shows the important role of the defense system in the
accumulation and tolerance to chemical pollutants through the
activation of enzymatic (GST (glutathione-S-transferase, APX
(ascorbat peroxidase), CAT (catalase)) and nonenzymatic biomarkers
(GSH (glutathione), MDA (malondialdehyde)) against oxidative
stress generated by the NPKs.
Abstract: Candida albicans ATCC 10231 had low endogenous activity of the alternative oxidase compared with that of C. albicans ATCC 10261. In C. albicans ATCC 10231 the endogenous activity declined as the cultures aged. Alternative oxidase activity could be induced in C. albicans ATCC 10231 by treatment with cyanide, but the induction of this activity required the presence of oxygen which could be replaced, at least in part, with high concentrations of potassium ferricyanide. We infer from this that the expression of the gene encoding the alternative oxidase is under the control of a redoxsensitive transcription factor.