Abstract: One of the causes of water pollution is the presence of heavy metals in water. In the present study, an adsorbent prepared from the raw bark of the Pongamia pinnata tree is used for the removal of ferrous or ferric ions from aqueous and waste water containing heavy metals. Adsorption studies were conducted at different pH, concentration of metal ion, amount of adsorbent, contact time, agitation and temperature. The Langmuir and Freundlich adsorption isotherm models were applied for the results. The Langmuir isotherms were best fitted by the equilibrium data. The maximum adsorption was found to 146mg/g in waste water at a temperature of 30°C which is in agreement as comparable to the adsorption capacity of different adsorbents reported in literature. Pseudo second order model best fitted the adsorption of both ferrous and ferric ions.
Abstract: The objective of this work was to examine the
changes in the microstructure and macro physical properties caused
by the carbonation of normalised CEM II mortar. Samples were
prepared and subjected to accelerated carbonation at 20°C, 65%
relative humidity and 20% CO2 concentration. On the microstructure
scale, the evolutions of the cumulative pore volume, pore size
distribution, and specific surface area during carbonation were
calculated from the adsorption desorption isotherms of nitrogen. We
also examined the evolution of macro physical properties such as the
porosity accessible to water, the gas permeability, and thermal
conductivity. The conflict between the results of nitrogen porosity
and water porosity indicated that the porous domains explored using
these two techniques are different and help to complementarily
evaluate the effects of carbonation. This is a multi-scale study where
results on microstructural changes can help to explain the evolution
of macro physical properties.
Abstract: The periodic mixed convection of a water-copper
nanofluid inside a rectangular cavity with aspect ratio of 3 is
investigated numerically. The temperature of the bottom wall of the
cavity is assumed greater than the temperature of the top lid which
oscillates horizontally with the velocity defined as u = u0 sin (ω t).
The effects of Richardson number, Ri, and volume fraction of
nanoparticles on the flow and thermal behavior of the nanofluid are
investigated. Velocity and temperature profiles, streamlines and
isotherms are presented. It is observed that when Ri < 1, heat transfer
rate is much greater than when Ri > 1. The higher value of Ri
corresponds to a lower value of the amplitude of the oscillation of
Num in the steady periodic state. Moreover, increasing the volume
fraction of the nanoparticles increases the heat transfer rate.
Abstract: The persistent nature of perfluorochemicals (PFCs) has attracted global concern in recent years. Perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA) are the most commonly found PFC compounds, and thus their fate and transport play key roles in PFC distribution in the natural environment. The kinetic behavior of PFOS or PFOA on boehmite consists of a fast adsorption process followed by a slow adsorption process which may be attributed to the slow transport of PFOS or PFOA into the boehmite pore surface. The adsorption isotherms estimated the maximum adsorption capacities of PFOS and PFOA on boehmite as 0.877 μg/m2 and 0.633 μg/m2, with the difference primarily due to their different functional groups. The increase of solution pH led to a moderate decrease of PFOS and PFOA adsorption, owing to the increase of ligand exchange reactions and the decrease of electrostatic interactions. The presence of NaCl in solution demonstrated negative effects for PFOS and PFOA adsorption on boehmite surfaces, with potential mechanisms being electrical double layer compression, competitive adsorption of chloride.
Abstract: The occurrence and removal of trace organic
contaminants in the aquatic environment has become a focus of
environmental concern. For the selective removal of carbamazepine
from loaded waters molecularly imprinted polymers (MIPs) were
synthesized with carbamazepine as template. Parameters varied were
the type of monomer, crosslinker, and porogen, the ratio of starting
materials, and the synthesis temperature. Best results were obtained
with a template to crosslinker ratio of 1:20, toluene as porogen, and
methacrylic acid (MAA) as monomer. MIPs were then capable to
recover carbamazepine by 93% from a 10-5 M landfill leachate
solution containing also caffeine and salicylic acid. By comparison,
carbamazepine recoveries of 75% were achieved using a nonimprinted
polymer (NIP) synthesized under the same conditions, but
without template. In landfill leachate containing solutions
carbamazepine was adsorbed by 93-96% compared with an uptake of
73% by activated carbon. The best solvent for desorption was
acetonitrile, with which the amount of solvent necessary and dilution
with water was tested. Selected MIPs were tested for their reusability
and showed good results for at least five cycles. Adsorption
isotherms were prepared with carbamazepine solutions in the
concentration range of 0.01 M to 5*10-6 M. The heterogeneity index
showed a more homogenous binding site distribution.
Abstract: The Lattice Boltzmann Method (LBM) with double populations is applied to solve the steady-state laminar natural convective heat transfer in a triangular cavity filled with water. The bottom wall is heated, the vertical wall is cooled, and the inclined wall is kept adiabatic. The buoyancy effect was modeled by applying the Boussinesq approximation to the momentum equation. The fluid velocity is determined by D2Q9 LBM and the energy equation is discritized by D2Q4 LBM to compute the temperature field. Comparisons with previously published work are performed and found to be in excellent agreement. Numerical results are obtained for a wide range of parameters: the Rayleigh number from to and the inclination angle from 0° to 360°. Flow and thermal fields were exhibited by means of streamlines and isotherms. It is observed that inclination angle can be used as a relevant parameter to control heat transfer in right-angled triangular enclosures.
Abstract: Laminar natural-convective heat transfer from a
horizontal cylinder is studied by solving the Navier-Stokes and
energy equations using higher order compact scheme in cylindrical
polar coordinates. Results are obtained for Rayleigh numbers of 1,
10, 100 and 1000 for a Prandtl number of 0.7. The local Nusselt
number and mean Nusselt number are calculated and compared with
available experimental and theoretical results. Streamlines, vorticity -
lines and isotherms are plotted.
Abstract: The present study is concerned with the free
convective two dimensional flow and heat transfer, within the
framework of Boussinesq approximation, in anisotropic fluid filled
porous rectangular enclosure subjected to end-to-end temperature
difference have been investigated using Lattice Boltzmann method
fornon-Darcy flow model. Effects of the moving lid direction (top,
bottom, left, and right wall moving in the negative and positive x&ydirections),
number of moving walls (one or two opposite walls), the
sliding wall velocity, and four different constant temperatures
opposite walls cases (two surfaces are being insulated and the
twoother surfaces areimposed to be at constant hot and cold
temperature)have been conducted. The results obtained are discussed
in terms of the Nusselt number, vectors, contours, and isotherms.
Abstract: The cup method is applied for the measurement of water vapor transport properties of porous materials worldwide. However, in practical applications the experimental results are often used without taking into account some secondary effects which can play an important role under specific conditions. In this paper, the effect of temperature on water vapor transport properties of cellular concrete is studied, together with the influence of sample thickness. At first, the bulk density, matrix density, total open porosity and sorption and desorption isotherms are measured for material characterization purposes. Then, the steady state cup method is used for determination of water vapor transport properties, whereas the measurements are performed at several temperatures and for three different sample thicknesses.
Abstract: The present work is concerned with the free
convective two dimensional flow and heat transfer, in isotropic fluid
filled porous rectangular enclosure with differentially heated walls for
steady state incompressible flow have been investigated for non-
Darcy flow model. Effects of Darcy number (0.0001 £Da£ 10),
Rayleigh number (10 £Ra£ 5000), and aspect ratio (0.25 £AR£ 4), for
a range of porosity (0.4 £e£ 0.9) with and without moving lower wall
have been studied. The cavity was insulated at the lower and upper
surfaces. The right and left heated surfaces allows convective
transport through the porous medium, generating a thermal
stratification and flow circulations. It was found that the Darcy
number, Rayleigh number, aspect ratio, and porosity considerably
influenced characteristics of flow and heat transfer mechanisms. The
results obtained are discussed in terms of the Nusselt number,
vectors, contours, and isotherms.
Abstract: Boron minerals are very useful for various industrial
activities, such as glass industry and detergent industry, due to its
mechanical and chemical properties. During the production of boron
compounds, many of these are introduced into the environment in the
form of waste. Boron is also an important micro nutrient for the
plants to vegetate but if it exists in high concentrations, it could have
toxic effects. The maximum boron level in drinking water for human
health is given as 0.3 mg/L in World Health Organization (WHO)
standards. The toxic effects of boron should be noted especially for
dry regions, thus, in recent years, increasing attention has been paid
to remove the boron from waste waters. In this study, boron removal
is implemented by ion exchange process using Amberlite IRA-743
resin. Amberlite IRA-743 resin is a boron specific resin and it
belongs to the polymerizate sorbent group within the aminopolyol
functional group. Batch studies were performed to investigate the
effects of various experimental parameters, such as adsorbent dose,
initial concentration and pH, on the removal of boron. It is found
that, when the adsorbent dose increases removal of boron from the
liquid phase increases. However, an increase in the initial
concentration decreases the removal of boron. The effective pH
values for removal of boron are determined between 8.5 and 9.
Equilibrium isotherms were also analyzed by Langmuir and
Freundlich isotherm models. The Langmuir isotherm is obeyed better
than the Freundlich isotherm.
Abstract: The purpose of this study is to investigate the capacity
of natural Turkish zeolite for NH4-N removal from landfill leachate.
The effects of modification and initial concentration on the removal
of NH4-N from leachate were also investigated. The kinetics of
adsorption of NH4-N has been discussed using three kinetic models,
i.e., the pseudo-second order model, the Elovich equation, the
intraparticle diffuion model. Kinetic parameters and correlation
coefficients were determined. Equilibrium isotherms for the
adsorption of NH4-N were analyzed by Langmuir, Freundlich and
Tempkin isotherm models. Langmuir isotherm model was found to
best represent the data for NH4-N.
Abstract: This work was to study batch biosorption of Pb(II)
ions from aqueous solution by Luffa charcoal. The effect of operating
parameters such as adsorption contact time, initial pH solution and
different initial Pb(II) concentration on the sorption of Pb(II) were
investigated. The results showed that the adsorption of Pb(II) ions
was initially rapid and the equilibrium time was 10 h. Adsorption
kinetics of Pb(II) ions onto Luffa charcoal could be best described by
the pseudo-second order model. At pH 5.0 was favorable for the
adsorption and removal of Pb(II) ions. Freundlich adsorption
isotherm model was better fitted for the adsorption of Pb(II) ions than
Langmuir and Timkin isotherms, respectively. The highest monolayer
adsorption capacity obtained from Langmuir isotherm model was
51.02 mg/g. This study demonstrated that Luffa charcoal could be
used for the removal of Pb(II) ions in water treatment.
Abstract: The potential of economically cheaper cellulose
containing natural materials like rice husk was assessed for nickel
adsorption from aqueous solutions. The effects of pH, contact time,
sorbent dose, initial metal ion concentration and temperature on the
uptake of nickel were studied in batch process. The removal of nickel
was dependent on the physico-chemical characteristics of the
adsorbent, adsorbate concentration and other studied process
parameters. The sorption data has been correlated with Langmuir,
Freundlich and Dubinin-Radush kevich (D-R) adsorption models. It
was found that Freundlich and Langmuir isotherms fitted well to the
data. Maximum nickel removal was observed at pH 6.0. The
efficiency of rice husk for nickel removal was 51.8% for dilute
solutions at 20 g L-1 adsorbent dose. FTIR, SEM and EDAX were
recorded before and after adsorption to explore the number and
position of the functional groups available for nickel binding on to
the studied adsorbent and changes in surface morphology and
elemental constitution of the adsorbent. Pseudo-second order model
explains the nickel kinetics more effectively. Reusability of the
adsorbent was examined by desorption in which HCl eluted 78.93%
nickel. The results revealed that nickel is considerably adsorbed on
rice husk and it could be and economic method for the removal of
nickel from aqueous solutions.
Abstract: Absorptive characteristics of polyaniline synthesized
in mixture of water and acetonitrile in 50/50 volume ratio was
studied. Synthesized polyaniline in powder shape is used as an
adsorbent to remove toxic hexavalent chromium from aqueous
solutions. Experiments were conducted in batch mode with different
variables such as agitation time, solution pH and initial concentration
of hexavalent chromium. Removal mechanism is the combination of
surface adsorption and reduction. The equilibrium time for removal
of Cr(T) and Cr(VI) was about 2 and 10 minutes respectively. The
optimum pH for total chromium removal occurred at pH 7 and
maximum hexavalent chromium removal took place under acidic
condition at pH 3. Investigating the isothermal characteristics showed
that the equilibrium adsorption data fitted both Freundlich-s and
Langmuir-s isotherms. The maximum adsorption of chromium was
calculated 36.1 mg/g for polyaniline
Abstract: CTMA-bentonite and BTEA-Bentonite prepared by Na-bentonite cation exchanged with cetyltrimethylammonium(CTMA) and benzyltriethylammonium (BTEA). Products were characterized by XRD and IR techniques.The d001 spacing value of CTMA-bentonite and BTEA-bentonite are 7.54Å and 3.50Å larger than that of Na-bentonite at 100% cation exchange capacity, respectively. The IR spectrum showed that the intensities of OH stretching and bending vibrations of the two organoclays decreased greatly comparing to untreated Na-bentonite. Batch experiments were carried out at 303 K, 318 K and 333 K to obtain the sorption isotherms of Crystal violet onto the two organoclays. The results show that the sorption isothermal data could be well described by Freundlich model. The dynamical data for the two organoclays fit well with pseudo-second-order kinetic model. The adsorption capacity of CTMA-bentonite was found higher than that of BTEA-Bentonite. Thermodynamic parameters such as changes in the free energy (ΔG°), the enthalpy (ΔH°) and the entropy (ΔS°) were also evaluated. The overall adsorption process of Crystal violet onto the two organoclays were spontaneous, endothermic physisorption. The CTMA-bentonite and BTEA-Bentonite could be employed as low-cost alternatives to activated carbon in wastewater treatment for the removal of color which comes from textile dyes.
Abstract: The experiments were performed in a batch set up
under different concentrations of Cu (II) (0.2 g.l-1 to 0.9 g.l-1), pH (4-
6), temperatures (20oC – 40oC) with varying teak leaves powder (as
biosorbent) dosage of 0.3 g.l-1 to 0.5 g.l-1. The kinetics of interactions
were tested with pseudo first order Lagergran equation and the value
for k1 was found to be 6.909 x 10-3 min-1. The biosorption data gave
a good fit with Langmuir and Fruendlich isotherms and the Langmuir
monolayer capacity (qm) was found to be 166.78 mg. g-1. Similarly
the Freundlich adsorption capacity (Kf) was estimated as 2.49 l g-1.
The mean values of the thermodynamic parameters ΔH, ΔS, and ΔG
were -62.42 KJ. mol-1, -0.219 KJ.mol-1 K-1 and -1.747 KJ.mol-1 at
293 K from a solution containing 0.4 g l-1 of Cu(II) showing the
biosorption to be thermodynamically favourable. These results show
good potentiality of using teak leaves as a biosorbent for the removal
of Cu(II) from aqueous solutions.
Abstract: Unsteady natural convection and heat transfer in a square cavity partially filled with porous media using a thermal
non-equilibrium model is studied in this paper. The left vertical wall is
maintained at a constant hot temperature Th and the right vertical wall
is maintained at a constant cold temperature Tc, while the horizontal
walls are adiabatic. The governing equations are obtained by applying
the Darcy model and Boussinesq approximation. COMSOL’s finite
element method is used to solve the non-dimensional governing
equations together with specified boundary conditions. The governing
parameters of this study are the Rayleigh number (Ra = 10^5, and Ra = 10^6 ), Darcy namber (Da = 10^−2, and Da = 10^−3),
the modified thermal conductivity ratio (10^−1 ≤ γ ≤ 10^4), the inter-phase heat transfer coefficien (10^−1 ≤ H ≤ 10^3) and the
time dependent (0.001 ≤ τ ≤ 0.2). The results presented for
values of the governing parameters in terms of streamlines in both
fluid/porous-layer, isotherms of fluid in fluid/porous-layer, isotherms
of solid in porous layer, and average Nusselt number.
Abstract: Batch adsorption of recalcitrant melanoidin using the abundantly available coal fly ash was carried out. It had low specific surface area (SBET) of 1.7287 m2/g and pore volume of 0.002245 cm3/g while qualitative evaluation of the predominant phases in it was done by XRD analysis. Colour removal efficiency was found to be dependent on various factors studied. Maximum colour removal was achieved around pH 6, whereas increasing sorbent mass from 10g/L to 200 g/L enhanced colour reduction from 25% to 86% at 298 K. Spontaneity of the process was suggested by negative Gibbs free energy while positive values for enthalpy change showed endothermic nature of the process. Non-linear optimization of error functions resulted in Freundlich and Redlich-Peterson isotherms describing sorption equilibrium data best. The coal fly ash had maximum sorption capacity of 53 mg/g and could thus be used as a low cost adsorbent in melanoidin removal.
Abstract: Ciprofloxacin (CIP) and Carbamazepine (CBZ), nonbiodegradable pharmaceutical residues, were become emerging pollutants in several aquatic environments. The objectives of this research were to study the possibility to recover these pharmaceuticals residues from pharmaceutical wastewater by increasing the selective adsorption on synthesized functionalized porous silicate, comparing with powdered activated carbon (PAC). Hexagonal mesoporous silicate (HMS), functionalized HMSs (3- aminopropyltriethoxy, 3- mercaptopropyltrimethoxy and noctyldimethyl) were synthesized and characterized physico-chemical characteristics. Obtained adsorption kinetics and isotherms showed that 3-mercaptopropyltrimethoxy functional groups grafted on HMS provided highest CIP and CBZ adsorption capacities; however, it was still lower than that of PAC. The kinetic results were compatible with pseudo-second order. The hydrophobicity and hydrogen bonding might play a key role on the adsorption. Furthermore, the capacities were affected by varying pH values due to the strength of hydrogen bonding between targeted compounds and adsorbents. Electrostatic interaction might not affect the adsorption capacities.