Abstract: The separation of Hg (II) from produced water by
hollow fiber contactors (HFC) was investigation. This system
included of two hollow fiber modules in the series connecting. The
first module used for the extraction reaction and the second module
for stripping reaction. Aliquat336 extractant was fed from the organic
reservoirs into the shell side of the first hollow fiber module and
continuous to the shell side of the second module. The organic liquid
was continuously feed recirculate and back to the reservoirs. The feed
solution was pumped into the lumen (tube side) of the first hollow
fiber module. Simultaneously, the stripping solution was pumped in
the same way in tube side of the second module. The feed and
stripping solution was fed which had a countercurrent flow. Samples
were kept in the outlet of feed and stripping solution at 1 hour and
characterized concentration of Hg (II) by Inductively Couple Plasma
Atomic Emission Spectroscopy (ICP-AES). Feed solution was
produced water from natural gulf of Thailand. The extractant was
Aliquat336 dissolved in kerosene diluent. Stripping solution used was
nitric acid (HNO3) and thiourea (NH2CSNH2). The effect of carrier
concentration and type of stripping solution were investigated.
Results showed that the best condition were 10 % (v/v) Aliquat336
and 1.0 M NH2CSNH2. At the optimum condition, the extraction and
stripping of Hg (II) were 98% and 44.2%, respectively.
Abstract: Palm shell obtained from coastal part of southern
India was studied for the removal for the adsorption of Hg (II) ions.
Batch adsorption experiments were carried out as a function of pH,
concentration of Hg (II) ions, time, temperature and adsorbent dose.
Maximum removal was seen in the range pH 4.0- pH 7.0. The palm
shell powder used as adsorbent was characterized for its surface area,
SEM, PXRD, FTIR, ion exchange capacity, moisture content, and
bulk density, soluble content in water and acid and pH. The
experimental results were analyzed using Langmuir I, II, III, IV and
Freundlich adsorption isotherms. The batch sorption kinetics was
studied for the first order reversible reaction, pseudo first order;
pseudo second order reaction and the intra-particle diffusion reaction.
The biomass was successfully used for removal Hg (II) from
synthetic and industrial effluents and the technique appears
industrially applicable and viable.