Abstract: A customized two-stage model has been developed to simulate, analyse, and visualize distillation of actinides as a useful alternative low-pressure separation method in the nuclear recycling cases. Under the most optimal conditions of idealized thermodynamic equilibrium stages and under total reflux of distillate the investigated cases of chloride systems for the separation of such actinides are (A) UCl4-CsCl-PuCl3 and (B) ThCl4-NaCl-PuCl3. Simulatively, uranium tetrachloride in case A is successfully separated by distillation into a six-stage distillation column, and thorium tetrachloride from case B into an eight-stage distillation column. For this, a permissible mole fraction value of 1E-06 has been assumed for the residual impurification degree. With further separation effort of eleven to seventeen required separation stages, the monochlorides of plutonium trichloride from both systems A and B are simulatively shown to be separated as high pure distillation products.
Abstract: The paper deals with the simulation of the crude distillation process using the Unisim Design simulator. The necessity of simulating this process is argued both by considerations related to the design of the crude distillation column, but also by considerations related to the design of advanced control systems. In order to use the Unisim Design simulator to simulate the crude distillation process, the identification of the simulators used in Romania and an analysis of the PRO/II, HYSYS, and Aspen HYSYS simulators were carried out. Analysis of the simulators for the crude distillation process has allowed the authors to elaborate the conclusions of the success of the crude modelling. A first aspect developed by the authors is the implementation of specific problems of petroleum liquid-vapors equilibrium using Unisim Design simulator. The second major element of the article is the development of the methodology and the elaboration of the simulation program for the crude distillation process, using Unisim Design resources. The obtained results validate the proposed methodology and will allow dynamic simulation of the process.
Abstract: The paper presents the research evolution in the propylene – propane distillation process, especially for the distillation columns equipped with heat pump. The paper is structured in three parts: separation of the propylene-propane mixture, steady state process modeling, and quality control systems. The first part is dedicated to state of art of the two distillation processes. The second part continues the author’s researches of the steady state process modeling. There has been elaborated a software simulation instrument that may be used to dynamic simulation of the process and to design the quality control systems. The last part presents the research of the control systems, especially for quality control systems.
Abstract: Reflux condensation occurs in vertical channels and tubes when there is an upward core flow of vapour (or gas-vapour mixture) and a downward flow of the liquid film. The understanding of this condensation configuration is crucial in the design of reflux condensers, distillation columns, and in loss-of-coolant safety analyses in nuclear power plant steam generators. The unique feature of this flow is the upward flow of the vapour-gas mixture (or pure vapour) that retards the liquid flow via shear at the liquid-mixture interface. The present model solves the full, elliptic governing equations in both the film and the gas-vapour core flow. The computational mesh is non-orthogonal and adapts dynamically the phase interface, thus produces a sharp and accurate interface. Shear forces and heat and mass transfer at the interface are accounted for fundamentally. This modeling is a big step ahead of current capabilities by removing the limitations of previous reflux condensation models which inherently cannot account for the detailed local balances of shear, mass, and heat transfer at the interface. Discretisation has been done based on finite volume method and co-located variable storage scheme. An in-house computer code was developed to implement the numerical solution scheme. Detailed results are presented for laminar reflux condensation from steam-air mixtures flowing in vertical parallel plate channels. The results include velocity and gas mass fraction profiles, as well as axial variations of film thickness.
Abstract: In the present study, two distinctly different approaches are followed for modeling of reactive distillation column, the equilibrium stage model and the nonequilibrium stage model. These models are simulated with a computer code developed in the present
study using MATLAB programming. In the equilibrium stage models, the vapor and liquid phases are assumed to be in equilibrium and allowance is made for finite reaction rates, where as in the nonequilibrium stage models simultaneous mass transfer and reaction rates are considered. These simulated model results are validated from the experimental data reported in the literature. The simulated results of equilibrium and nonequilibrium models are compared for concentration, temperature and reaction rate profiles in a reactive distillation column for Methyl Tert Butyle Ether (MTBE) production. Both the models show similar trend for the concentration, temperature and reaction rate profiles but the nonequilibrium model predictions are higher and closer to the experimental values reported in the literature.
Abstract: Robust stability and performance are the two most
basic features of feedback control systems. The harmonic balance
analysis technique enables to analyze the stability of limit cycles
arising from a neural network control based system operating over
nonlinear plants. In this work a robust stability analysis based on the
harmonic balance is presented and applied to a neural based control
of a non-linear binary distillation column with unstructured
uncertainty. We develop ways to describe uncertainty in the form of
neglected nonlinear dynamics and high harmonics for the plant and
controller respectively. Finally, conclusions about the performance of
the neural control system are discussed using the Nyquist stability
margin together with the structured singular values of the uncertainty
as a robustness measure.
Abstract: LabVIEW and SIMULINK are two most widely used
graphical programming environments for designing digital signal
processing and control systems. Unlike conventional text-based
programming languages such as C, Cµ and MATLAB, graphical
programming involves block-based code developments, allowing a
more efficient mechanism to build and analyze control systems. In
this paper a LabVIEW environment has been employed as a
graphical user interface for monitoring the operation of a controlled
distillation column, by visualizing both the closed loop performance
and the user selected control conditions, while the column dynamics
has been modeled under the SIMULINK environment. This tool has
been applied to the PID based decoupled control of a binary
distillation column. By means of such integrated environments the
control designer is able to monitor and control the plant behavior and
optimize the response when both, the quality improvement of
distillation products and the operation efficiency tasks, are
considered.
Abstract: Distillation column is one of the most common
operations in process industries and is while the most expensive unit
of the amount of energy consumption. Many ideas have been
presented in the related literature for optimizing energy consumption
in distillation columns. This paper studies the different heat
integration methods in a distillation column which separate Benzene,
Toluene, Xylene, and C9+. Three schemes of heat integration
including, indirect sequence (IQ), indirect sequence with forward
energy integration (IQF), and indirect sequence with backward
energy integration (IQB) has been studied in this paper. Using
shortcut method these heat integration schemes were simulated with
Aspen HYSYS software and compared with each other with
regarding economic considerations. The result shows that the energy
consumption has been reduced 33% in IQF and 28% in IQB in
comparison with IQ scheme. Also the economic result shows that the
total annual cost has been reduced 12% in IQF and 8% in IQB
regarding with IQ scheme. Therefore, the IQF scheme is most
economic than IQB and IQ scheme.
Abstract: The paper considers the effect of feed plate location
on the interactions in a seven plate binary distillation column. The
mathematical model of the distillation column is deduced based on
the equations of mass and energy balances for each stage, detailed
model for both reboiler and condenser, and heat transfer equations.
The Dynamic Relative Magnitude Criterion, DRMC is used to assess
the interactions in different feed plate locations for a seven plate
(Benzene-Toluene) binary distillation column ( the feed plate is
originally at stage 4). The results show that whenever we go far from
the optimum feed plate position, the level of interaction augments.
Abstract: In this paper we will consider the most known ratios
control schemes ((L/D, V/B),(L/D,V/F), Ryskamp-s, and
(D/(L+D),V/B)) for binary distillation column and we compare them
in the basis of interactions and disturbance propagation. The models
for these configurations are deuced using mathematical
transformations taking the energy balance structure (LV) as a base
model. The dynamic relative magnitude criterion (DRMC) is used to
assess the interactions. The results show that the introduction of
ratios in controlling the column tends to minimize the degree of
interactions between the loops.
Abstract: LABVIEW is a graphical programming language that has its roots in automation control and data acquisition. In this paper we have utilized this platform to provide a powerful toolset for process identification and control of nonlinear systems based on artificial neural networks (ANN). This tool has been applied to the monitoring and control of a lab-scale distillation column DELTALAB DC-SP. The proposed control scheme offers high speed of response for changes in set points and null stationary error for dual composition control and shows robustness in presence of externally imposed disturbance.
Abstract: Vapour recompression system has been used to
enhance reduction in energy consumption and improvement in
energy effectiveness of distillation columns. However, the effects of
certain parameters have not been taken into consideration. One of
such parameters is the column heat loss which has either been
assumed to be a certain percent of reboiler heat transfer or negligible.
The purpose of this study was to evaluate the heat loss from an
ethanol-water vapour recompression distillation column with
pressure increase across the compressor (VRCAS) and compare the
results obtained and its effect on some parameters in similar system
(VRCCS) where the column heat loss has been assumed or neglected.
Results show that the heat loss evaluated was higher when compared
with that obtained for the column VRCCS. The results also showed
that increase in heat loss could have significant effect on the total
energy consumption, reboiler heat transfer, the number of trays and
energy effectiveness of the column.
Abstract: Equilibrium and rate based models have been applied
in the simulation of methyl tertiary-butyl ether (MTBE) synthesis
through reactive distillation. Temperature and composition profiles
were compared for both the models and found that both the profiles
trends, though qualitatively similar are significantly different
quantitatively. In the rate based method (RBM), multicomponent
mass transfer coefficients have been incorporated to describe
interphase mass transfer. MTBE mole fraction in the bottom stream is
found to be 0.9914 in the Equilibrium Model (EQM) and only 0.9904
for RBM when the same column configuration was preserved. The
individual tray efficiencies were incorporated in the EQM and
simulations were carried out. Dynamic simulation have been also
carried out for the two column configurations and compared.
Abstract: Neural networks offer an alternative approach both
for identification and control of nonlinear processes in process
engineering. The lack of software tools for the design of controllers
based on neural network models is particularly pronounced in this
field. SIMULINK is properly a widely used graphical code
development environment which allows system-level developers to
perform rapid prototyping and testing. Such graphical based
programming environment involves block-based code development
and offers a more intuitive approach to modeling and control task in
a great variety of engineering disciplines. In this paper a
SIMULINK based Neural Tool has been developed for analysis and
design of multivariable neural based control systems. This tool has
been applied to the control of a high purity distillation column
including non linear hydrodynamic effects. The proposed control
scheme offers an optimal response for both theoretical and practical
challenges posed in process control task, in particular when both,
the quality improvement of distillation products and the operation
efficiency in economical terms are considered.