Abstract: As a by-product of the biodiesel industries, glycerol
has been vastly generated which surpasses the market demand. It is
imperative to develop an efficient glycerol valorization processes in
minimizing the net energy requirement and intensifying the biodiesel
production. In this study, base-catalyzed transesterification of
glycerol with dimethyl carbonate using microwave irradiation as
heating method to produce glycerol carbonate was conducted by
varying grades of glycerol, i.e. 70%, 86% and 99% purity, that is
obtained from biodiesel plant. Metal oxide catalysts were used with
varying operating parameters including reaction time, DMC/glycerol
molar ratio, catalyst weight %, temperature and stirring speed. From
the study on the effect of different operating parameters it was found
that the type of catalyst used has the most significant effect on the
transesterification reaction. Amidst the metal oxide catalysts
examined, CaO gave the best performance. This study indicates the
feasibility of producing glycerol carbonate using different grade of
glycerol in both conventional thermal activation and microwave
irradiation with CaO as catalyst. Microwave assisted
transesterification (MAT) of glycerol into glycerol carbonate has
demonstrated itself as an energy efficient route by achieving 94.2%
yield of GC at 65°C, 5 minutes reaction time, 1 wt% CaO and
DMC/glycerol molar ratio of 2. The advantages of MAT
transesterification route has made the direct utilization of bioglycerol
from biodiesel production without the need of purification. This has
marked a more economical and less-energy intensive glycerol
carbonate synthesis route.
Abstract: Compression algorithms reduce the redundancy in
data representation to decrease the storage required for that data.
Lossless compression researchers have developed highly
sophisticated approaches, such as Huffman encoding, arithmetic
encoding, the Lempel-Ziv (LZ) family, Dynamic Markov
Compression (DMC), Prediction by Partial Matching (PPM), and
Burrows-Wheeler Transform (BWT) based algorithms.
Decompression is also required to retrieve the original data by
lossless means. A compression scheme for text files coupled with
the principle of dynamic decompression, which decompresses only
the section of the compressed text file required by the user instead of
decompressing the entire text file. Dynamic decompressed files offer
better disk space utilization due to higher compression ratios
compared to most of the currently available text file formats.
Abstract: This paper presents a new adaptive DMC controller
that improves the controller performance in case of plant-model
mismatch. The new controller monitors the plant measured output,
compares it with the model output and calculates weights applied to
the controller move. Simulations show that the new controller can
help improve control performance and avoid instability in case of
severe model mismatches.
Abstract: In automatic manufacturing and assembling of mechanical, electrical and electronic parts one needs to reliably identify the position of components and to extract the information of these components. Data Matrix Codes (DMC) are established by these days in many areas of industrial manufacturing thanks to their concentration of information on small spaces. In today’s usually order-related industry, where increased tracing requirements prevail, they offer further advantages over other identification systems. This underlines in an impressive way the necessity of a robust code reading system for detecting DMC on the components in factories. This paper compares two methods for estimating the angle of orientation of Data Matrix Codes: one method based on the Hough Transform and the other based on the Mean Shift Algorithm. We concentrate on Data Matrix Codes in industrial environment, punched, milled, lasered or etched on different materials in arbitrary orientation.