Abstract: Reduction of CO2 emissions has become a priority for
several countries due to increasing concerns about global warming
and climate change, especially in the developed countries. Residential
sector is considered one of the most important sectors for
considerable reduction of CO2 emissions since it represents a
significant amount of the total consumed energy in those countries. A
significant CO2 reduction cannot be achieved unless some initiatives
have been adopted in the policy of these countries. Introducing micro
combined heat and power (!CHP) systems into residential energy
systems is one of these initiatives, since such a technology offers
several advantages. Moreover, !CHP technology has the opportunity
to be operated not only by natural gas but it could also be operated by
renewable fuels. However, this technology can be operated by
different operation strategies. Each strategy has some advantages and
disadvantages.
This paper provides a review of different operation strategies of
such a technology used for residential energy systems, especially for
single dwellings. The review summarizes key points that outline the
trend of previous research carried out in this field.
Abstract: Heightened concerns over the amount of carbon
emitted from coal-related processes are generating shifts to the
application of biomass. In co-gasification, where coal is gasified
along with biomass, the biomass may be fed together with coal (cofeeding)
or an independent biomass gasifier needs to be integrated
with the coal gasifier. The main aim of this work is to evaluate the
biomass introduction methods in coal co-gasification. This includes
the evaluation of biomass concentration input (B0 to B100) and its
gasification performance. A process model is developed and
simulated in Aspen HYSYS, where both coal and biomass are
modelled according to its ultimate analysis. It was found that the
syngas produced increased with increasing biomass content for both
co-feeding and independent schemes. However, the heating values
and heat duties decreases with biomass concentration as more CO2
are produced from complete combustion.
Abstract: Immunomodulators are substances that alter immune
system via dynamic regulation of messenger molecules. It can be
divided into immunostimulant and immunosuppressant. It can help to
increase immunity of people with a low immune system, and also can
help to normalize an overactive immune system. Aim of this study is
to investigate the effects of in vitro exposure to low and high doses of
several immunomodulators which include caffeine, kaloba and
quercetin on antigen-stimulated whole blood culture cytokine
production. Whole blood samples were taken from 5 healthy males
(age: 32 ± 12 years; weight: 75.7 ± 6.1 kg; BMI: 24.3 ± 1.5 kg/m2)
following an overnight fast with no vigorous activity during the
preceding 24 h. The whole blood was then stimulated with 50 μl of
100 x diluted Pediacel vaccine and low or high dose of
immunomodulators in the culture plate. After 20 h incubation (5%
CO2, 37°C), it was analysed using the Evidence Investigator to
determine the production of cytokines including IL-2, IL-4, IL-10,
IFN-γ, and IL-1α. Caffeine and quercetin showed a tendency towards
decrease cytokine production as the doses were increased. On the
other hand, an upward trend was evident with kaloba, where a high
dose of kaloba seemed to increase the cytokine production. In
conclusion, we found that caffeine and quercetin have potential as
immunosuppressant and kaloba as immunostimulant.
Abstract: The detection of environmental gases, 12CO2, 13CO2,
and CH4, using near-infrared semiconductor lasers with a short
laser path length is studied by means of wavelength-modulation
spectroscopy. The developed system is compact and has high
sensitivity enough to detect the absorption peaks of isotopic 13CO2
of a 3-% CO2 gas at 2 μm with a path length of 2.4 m, where
its peak size is two orders of magnitude smaller than that of the
ordinary 12CO2 peaks. In addition, the detection of 12CO2 peaks of
a 385-ppm (0.0385-%) CO2 gas in the air is made at 2 μm with a
path length of 1.4 m. Furthermore, in pursuing the detection of an
ancient environmental CH4 gas confined to a bubble in ice at the
polar regions, measurements of the absorption spectrum for a trace
gas of CH4 in a small area are attempted. For a 100-% CH4 gas
trapped in a ∼ 1 mm3 glass container, the absorption peaks of CH4
are obtained at 1.65 μm with a path length of 3 mm, and also the
gas pressure is extrapolated from the measured data.
Abstract: The reduction of greenhouse gases emissions is highly
discussed ecological theme at present. In addition to power industry
also main production sectors of binders, i.e. cement, air and hydraulic
lime are very sensitive to these questions. One of the possibilities
how CO2 emissions can be reduced directly at clinker burnout is
represented by partial substitution of lime with a material containing
limy ions at absence of carbonate group. Fluidised fly ash is one of
such potential raw materials where CaO can be found free and also
bound in anhydrite, CaSO4. At application of FBC (fluidized bed
combustion) fly ash with approximate 20% CaO content and its
dosing ratio to high percent lime 1:2, corresponding stechiometrically
to the preparation of raw material powder, approximately 0,37 t CO2
per 1 ton of one-component cement would be released at clinker
burnout compared to 0,46 t CO2 when orthodox raw materials are
used. The reduction of CO2 emissions thus could reach even 20%.
Abstract: Because of high thermal efficiency and low CO2
emission, diesel engines are being used widely in many industrial
fields although it makes many PM and NOx which give both human
health and environment a negative effect. NOx regulations for diesel
engines, however, are being strengthened and it is impossible to meet
the emission standard without NOx reduction devices such as SCR
(Selective Catalytic Reduction), LNC (Lean NOx Catalyst), and LNT
(Lean NOx Trap). Among the NOx reduction devices, urea-SCR
system is known as the most stable and efficient method to solve the
problem of NOx emission. But this device has some issues associated
with the ammonia slip phenomenon which is occurred by shortage of
evaporation and thermolysis time, and that makes it difficult to achieve
uniform distribution of the injected urea in front of monolith.
Therefore, this study has focused on the mixing enhancement between
urea and exhaust gases to enhance the efficiency of the SCR catalyst
equipped in catalytic muffler by changing inlet gas temperature and
spray conditions to improve the spray uniformity of the urea water
solution. Finally, it can be found that various parameters such as inlet
gas temperature and injector and injection angles significantly affect
the evaporation and mixing of the urea water solution with exhaust
gases, and therefore, optimization of these parameters are required.
Abstract: Combustion phenomenon will be accomplished
effectively by the development of low emission combustor. One of the
significant factors influencing the entire Combustion process is the
mixing between a swirling angular jet (Primary Air) and the
non-swirling inner jet (fuel). To study this fundamental flow, the
chamber had to be designed in such a manner that the combustion
process to sustain itself in a continuous manner and the temperature of
the products is sufficiently below the maximum working temperature
in the turbine. This study is used to develop the effective combustion
with low unburned combustion products by adopting the concept of
high swirl flow and motility of holes in the secondary chamber. The
proper selection of a swirler is needed to reduce emission which can be
concluded from the emission of Nox and CO2. The capture of CO2 is
necessary to mitigate CO2 emissions from natural gas. Thus the
suppression of unburned gases is a meaningful objective for the
development of high performance combustor without affecting turbine
blade temperature.
Abstract: This research studies the electroplating of zinc coating
in the zinc chloride bath mixed with supercritical CO2. The sodium
fluoride (NaF) was used as the bath additive to change the structure
and property of the coating, and therefore the roughness and corrosion
resistance of the zinc coating was investigated. The surface
characterization was performed using optical microscope (OM), X-ray
diffractometer (XRD), and α-step profilometer. Moreover, the
potentiodynamic polarization measurement in 3% NaCl solution was
employed in the corrosion resistance evaluation. Because of the
emulsification of the electrolyte mixed in Sc-CO2, the electroplated
zinc produced the coating with smoother surface, smaller grain, better
throwing power and higher corrosion resistance. The main role played
by the NaF was to reduce the coating’s roughness and grain size. In
other words, the CO2 mixed with the electrolyte under the supercritical
condition performed the similar function as brighter and leveler in zinc
electroplating to enhance the throwing power and corrosion resistance
of the coating.
Abstract: The objective of this paper is finding the way of economic restructuring - that is, change in the shares of sectoral gross outputs - resulting in the maximum possible increase in the gross domestic product (GDP) combined with decreases in energy consumption and CO2 emissions. It uses an input-output model for the GDP and factorial models for the energy consumption and CO2 emissions to determine the projection of the gradient of GDP, and the antigradients of the energy consumption and CO2 emissions, respectively, on a subspace formed by the structure-related variables. Since the gradient (antigradient) provides a direction of the steepest increase (decrease) of the objective function, and their projections retain this property for the functions' limitation to the subspace, each of the three directional vectors solves a particular problem of optimal structural change. In the next step, a type of factor analysis is applied to find a convex combination of the projected gradient and antigradients having maximal possible positive correlation with each of the three. This convex combination provides the desired direction of the structural change. The national economy of the United States is used as an example of applications.
Abstract: This paper presents a detailed description of evaporative cooling systems used for space cooling in Mina Valley, Saudi Arabia. The thermal performance and environmental impact of the evaporative coolers were evaluated. It was found that the evaporative cooling systems used for space cooling in pilgrims’ accommodations and in the train stations could reduce energy consumption by as much as 75% and cut carbon dioxide emission by 78% compared to traditional vapour compression systems.
Abstract: Recent concerns of the growing impact of aviation on
climate change has prompted the emergence of a field referred to as
Sustainable or “Green” Aviation dedicated to mitigating the harmful
impact of aviation related CO2 emissions and noise pollution on
the environment. In the current paper, a unique “green” business
jet aircraft called the TransAtlantic was designed (using analytical
formulation common in conceptual design) in order to show the
feasibility for transatlantic passenger air travel with an aircraft
weighing less than 10,000 pounds takeoff weight. Such an advance in
fuel efficiency will require development and integration of advanced
and emerging aerospace technologies. The TransAtlantic design is
intended to serve as a research platform for the development of
technologies such as active flow control. Recent advances in the field
of active flow control and how this technology can be integrated
on a sub-scale flight demonstrator are discussed in this paper. Flow
control is a technique to modify the behavior of coherent structures
in wall-bounded flows (over aerodynamic surfaces such as wings and
turbine nozzles) resulting in improved aerodynamic cruise and flight
control efficiency. One of the key challenges to application in manned
aircraft is development of a robust high-momentum actuator that
can penetrate the boundary layer flowing over aerodynamic surfaces.
These deficiencies may be overcome in the current development
and testing of a novel electromagnetic synthetic jet actuator which
replaces piezoelectric materials as the driving diaphragm. One of
the overarching goals of the TranAtlantic research platform include
fostering national and international collaboration to demonstrate (in
numerical and experimental models) reduced CO2/ noise pollution
via development and integration of technologies and methodologies
in design optimization, fluid dynamics, structures/ composites,
propulsion, and controls.
Abstract: Carbon capture, transport and underground storage have become a major solution to reduce CO2 emissions from power plants and other large CO2 sources. A big part of this captured CO2 stream is transported at high pressure dense phase conditions and stored in offshore underground depleted oil and gas fields. CO2 is also transported in offshore pipelines to be used for enhanced oil and gas recovery. The captured CO2 stream with impurities may contain water that causes severe corrosion problems, flow assurance failure and might damage valves and instrumentations. Thus, free water formation should be strictly prevented. The purpose of this work is to study the solubility of water in pure CO2 and in CO2 mixtures under real pipeline pressure (90-150 bar) and temperature operation conditions (5-35°C). A set up was constructed to generate experimental data. The results show the solubility of water in CO2 mixtures increasing with the increase of the temperature or/and with the increase in pressure. A drop in water solubility in CO2 is observed in the presence of impurities. The data generated were then used to assess the capabilities of two mixture models: the GERG-2008 model and the EOS-CG model. By generating the solubility data, this study contributes to determine the maximum allowable water content in CO2 pipelines.
Abstract: Steam reforming is industrially important as it is
incorporated in several major chemical processes including the
production of ammonia, methanol, hydrogen and ox alcohols. Due to
the strongly endothermic nature of the process, a large amount of heat
is supplied by fuel burning (commonly natural gas) in the furnace
chamber. Reaction conversions, tube catalyst life, energy
consumption and CO2 emission represent the principal factors
affecting the performance of this unit and are directly influenced by
the high operating temperatures and pressures.
This study presents a simulation of the performance of the
reforming of methane in a primary reformer, through a developed
empirical relation which enables to investigate the effects of
operating parameters such as the pressure, temperature, steam to
carbon ratio on the production of hydrogen, as well as the fraction of
non converted methane.
It appears from this analysis that the exit temperature Te, the
operating pressure as well the steam to carbon ratio has an important
effect on the reforming of methane.
Abstract: There are many difficulties in the purification of raw components and products. However, researchers are seeking better ways for purification. One of the recent methods is extraction using supercritical fluids. In this study, the phase equilibria of benzoic acid -supercritical carbon dioxide system were investigated. Regarding the phase equilibria of this system, the modeling of solid-supercritical fluid behavior was performed using the Perturbed-Chain Statistical Association Fluid Theory (PC-SAFT) and Peng-Robinson equations of state (PR EoS). For this purpose, five PC-SAFT EoS parameters for pure benzoic acid were obtained using its experimental vapor pressure. Benzoic acid has association sites and the behavior of the benzoic acid-supercritical fluid system was well predicted using both equations of state, while the binary interaction parameter values for PR EoS were negative. Genetic algorithm, which is one of the most accurate global optimization algorithms, was also used to optimize the pure benzoic acid parameters and the binary interaction parameters. The AAD% value for the PC-SAFT EoS, were 0.22 for the carbon dioxide-benzoic acid system.
Abstract: Global CO2 emission and increasing fuel consumption to meet energy demand has become a threat in recent decades. Effort to reduce the CO2 emission is now a matter of priority in most countries of the world including Malaysia. Transportation has been identified as the most intensive sector of carbon-based fuels and achievement of the voluntary target to meet 40% carbon intensity reduction set at the 15th Conference of the Parties (COP15) means that the emission from the transport sector must be reduced accordingly. This posed a great challenge to Malaysia and effort has to be made to embrace suitable and appropriate energy policy for sustainable energy and emission reduction of this sector. The focus of this paper is to analyze the trends of Malaysia’s energy consumption and emission of four different transport sub-sectors (road, rail, aviation and maritime). Underlying factors influencing the growth of energy consumption and emission trends are discussed. Besides, technology status towards energy efficiency in transportation sub-sectors is presented. By reviewing the existing policies and trends of energy used, the paper highlights prospective policy options towards achieving emission reduction in the transportation sector.
Abstract: This paper presents a method of economic factorial analysis of the CO2 emissions based on the extension of the Divisia index to interconnected factors. This approach, contrary to the Kaya identity, considers three main factors of the CO2 emissions: gross domestic product, energy consumption, and population - as equally important, and allows for accounting of all of them simultaneously. The three factors are included into analysis together with their carbon intensities that allows for obtaining a comprehensive picture of the change in the CO2 emissions. A computer program in R-language that is available for free download serves automation of the calculations. A case study of the U.S. carbon dioxide emissions is used as an example.
Abstract: Sputtered CoxCu100-x films with the different compositions of x = 57.7, 45.8, 25.5, 13.8, 8.8, 7.5 and 1.8 were deposited on Cr under-layer by RF-sputtering. SEM result reveals that the averaged thickness of Co-Cu film and Cr under-layer are 92 nm and 22nm, respectively. All Co-Cu films are composed of Co (FCC) and Cu (FCC) phases in (111) directions on BCC-Cr (110) under-layers. Magnetic properties, surface roughness and morphology of Co-Cu films are dependent on the film composition. The maximum and minimum surface roughness of 3.24 and 1.16nm are observed on the Co7.5Cu92.5 and Co45.8Cu54.2films, respectively. It can be described that the variance of surface roughness of the film because of the difference of the agglomeration rate of Co and Cu atoms on Cr under-layer. The Co57.5Cu42.3, Co45.8Cu54.2 and Co25.5Cu74.5 films shows the ferromagnetic phase whereas the rest of the film exhibits the paramagnetic phase at room temperature. The saturation magnetization, remnant magnetization and coercive field of Co-Cu films on Cr under-layer are slightly increased with increasing the Co composition. It can be concluded that the required magnetic properties and surface roughness of the Co-Cu film can be adapted by the adjustment of the film composition.
Abstract: In maize growing technologies, tillage technological operations are the most time-consuming and require the greatest fuel input. Substitution of conventional tillage, involving deep ploughing, by other reduced tillage methods can reduce technological production costs, diminish soil degradation and environmental pollution from greenhouse gas emissions, as well as improve economic competitiveness of agricultural produce.
Experiments designed to assess energy and environmental aspects associated with different reduced tillage systems, applied in maize cultivation were conducted at Aleksandras Stulginskis University taking into account Lithuania’s economic and climate conditions. The study involved 5 tillage treatments: deep ploughing (DP, control), shallow ploughing (SP), deep cultivation (DC), shallow cultivation (SC) and no-tillage (NT).
Our experimental evidence suggests that with the application of reduced tillage systems it is feasible to reduce fuel consumption by 13-58% and working time input by 8.4% to nearly 3-fold, to reduce the cost price of maize cultivation technological operations, decrease environmental pollution with CO2 gas by 30 to 146 kg ha-1, compared with the deep ploughing.
Abstract: When concrete is exposed to high temperatures, some changes may occur in its physical and mechanical properties. Especially, high strength concrete (HSC), may exhibit damages such as cracks and spallings. To overcome this problem, incorporating polymer fibers such as polypropylene (PP) in concrete is a well-known method. In high temperatures, PP decomposes and releases harmful gases such as CO and CO2. This study researches the use of raw rice husk (RRH) as a sustainable material, instead of PP fibers considering its several favorable properties, and its usability in HSC. RRH and PP fibers were incorporated in concrete at 0.5-3% and 0.2-0.5% by weight of cement, respectively. Concrete specimens were exposed to 20 (control), 300, 600 and 900°C. Under these temperatures, residual compressive and splitting tensile strength was determined. During the high temperature effect, the amount of released harmful gases was measured by a gas detector.
Abstract: Carbon dioxide has been well associated with greenhouse effect, and due to its corrosive nature it is an undesirable compound. A variety of physical-chemical processes are available for the removal of carbon dioxide. Previous attempts in this field have established alkanolamine group has the capability to remove carbon dioxide. So, this study combined the polymeric membrane and alkanolamine solutions to fabricate the amine polymeric membrane (APM) to remove carbon dioxide (CO2). This study entails the effect of three types of amines, monoethanolamine (MEA), diethanolamine (DEA), and methyldiethanolamine (MDEA). The effect of each alkanolamine group on the morphology and performance of polyether sulfone (PES) polymeric membranes was studied. Flat sheet membranes were fabricated by solvent evaporation method by adding polymer and different alkanolamine solutions in the N-Methyl-2-pyrrolidone (NMP) solvent. The final membranes were characterized by using Field Emission Electron Microscope (FESEM), Fourier Transform Infrared (FTIR), and Thermo-Gravimetric Analysis (TGA). The membrane separation performance was studied. The PES-DEA and PES-MDEA membrane has good ability to remove carbon dioxide.