Abstract: Residential buildings consume significant amounts of
energy and produce large amount of emissions and waste. However,
there is a substantial potential for energy savings in this sector which
needs to be evaluated over the life cycle of residential buildings. Life
Cycle Assessment (LCA) methodology has been employed to study
the primary energy uses and associated environmental impacts of
different phases (i.e., product, construction, use, end of life, and
beyond building life) for residential buildings. Four different
alternatives of residential buildings in Vancouver (BC, Canada) with
a 50-year lifespan have been evaluated, including High Rise
Apartment (HRA), Low Rise Apartment (LRA), Single family
Attached House (SAH), and Single family Detached House (SDH).
Life cycle performance of the buildings is evaluated for embodied
energy, embodied environmental impacts, operational energy,
operational environmental impacts, total life-cycle energy, and total
life cycle environmental impacts. Estimation of operational energy
and LCA are performed using DesignBuilder software and Athena
Impact estimator software respectively.
The study results revealed that over the life span of the buildings,
the relationship between the energy use and the environmental
impacts are identical. LRA is found to be the best alternative in terms
of embodied energy use and embodied environmental impacts; while,
HRA showed the best life-cycle performance in terms of minimum
energy use and environmental impacts. Sensitivity analysis has also
been carried out to study the influence of building service lifespan
over 50, 75, and 100 years on the relative significance of embodied
energy and total life cycle energy. The life-cycle energy requirements
for SDH are found to be a significant component among the four
types of residential buildings. The overall disclose that the primary
operations of these buildings accounts for 90% of the total life cycle
energy which far outweighs minor differences in embodied effects
between the buildings.
Abstract: Currently, continuous two-phase decanter process
used for olive oil production is the more internationally widespread.
The wastewaters generated from this industry (OMW) are a real
environmental problem because of its high organic load. Among
proposed treatments for these wastewaters, advanced oxidation
technologies (Fenton, ozone, photoFenton, etc.) are the most
favourable. The direct application of these processes is somewhat
expensive. Therefore, the application of a previous stage based on a
flocculation-sedimentation operation is of high importance. In this
research five commercial flocculants (three cationic, and two anionic)
have been used to achieve the separation of phases (liquid clarifiedsludge).
For each flocculant, different concentrations (0-1000 mg/L)
have been studied. In these experiments, sludge volume formed and
the final water quality were determined. The final removal
percentages of total phenols (11.3-25.1%), COD (5.6-20.4%), total
carbon (2.3-26.5%), total organic carbon (1.50-23.8%), total nitrogen
(1.45-24.8%), and turbidity (27.9-61.4%) were determined. The
variation on electric conductivity reduction percentage (1-8%) was
also determined. Finally, the best flocculants with highest removal
percentages have been determined (QG2001 and Flocudex CS49).
Abstract: This paper aims to study the effect of cold work
condition on the microstructure of Cu-1.5wt%Ti, and Cu-3.5wt%Ti
and hence mechanical properties. The samples under investigation
were machined, and solution heat treated. X-ray diffraction technique
is used to identify the different phases present after cold deformation
by compression and also different heat treatment and also measuring
the relative quantities of phases present. The metallographic
examination is used to study the microstructure of the samples. The
hardness measurements were used to indicate the change in
mechanical properties. The results are compared with the mechanical
properties obtained by previous workers. Experiments on cold
compression followed by aging of Cu-Ti alloys have indicated that
the most efficient hardening of the material results from continuous
precipitation of very fine particles within the matrix. These particles
were reported to be β`-type, Cu4Ti phase. The β`-β transformation
and particles coarsening within the matrix as well as long grain
boundaries were responsible for the overaging of Cu-1.5wt%Ti and
Cu-3.5wt%Ti alloys. It is well known that plate-like particles are β –
type, Cu3Ti phase. Discontinuous precipitation was found to start at
the grain boundaries and expand into grain interior. At the higher
aging temperature, a classic Widmanstätten morphology forms giving
rise to a coarse microstructure comprised of α and the equilibrium
phase β. Those results were confirmed by X-ray analysis, which
found that a few percent of Cu3Ti, β precipitates are formed during
aging at high temperature for long time for both Cu- Ti alloys (i.e.
Cu-1.5wt%Ti and Cu-3.5wt%Ti).
Abstract: In this study, we demonstrate the production of natural gas hydrates from permeable marine sediments with simultaneous mechanisms for methane recovery and methane-air or methane-air/carbon dioxide replacement. The simultaneous melting happens until the chemical potentials become equal in both phases as natural gas hydrate depletion continues and self-regulated methane-air replacement occurs over an arbitrary point. We observed certain point between dissociation and replacement mechanisms in the natural gas hydrate reservoir, and we call this boundary as critical methane concentration. By the way, when carbon dioxide was added, the process of chemical exchange of methane by air/carbon dioxide was observed in the natural gas hydrate. The suggested process will operate well for most global natural gas hydrate reservoirs, regardless of the operating conditions or geometrical constraints.
Abstract: The nanoindentation behaviour and phase
transformation of annealed single-crystal silicon wafers are examined.
The silicon specimens are annealed at temperatures of 250, 350 and
450ºC, respectively, for 15 minutes and are then indented to maximum
loads of 30, 50 and 70 mN. The phase changes induced in the indented
specimens are observed using transmission electron microscopy
(TEM) and micro-Raman scattering spectroscopy (RSS). For all
annealing temperatures, an elbow feature is observed in the unloading
curve following indentation to a maximum load of 30 mN. Under
higher loads of 50 mN and 70 mN, respectively, the elbow feature is
replaced by a pop-out event. The elbow feature reveals a complete
amorphous phase transformation within the indented zone, whereas
the pop-out event indicates the formation of Si XII and Si III phases.
The experimental results show that the formation of these crystalline
silicon phases increases with an increasing annealing temperature and
indentation load. The hardness and Young’s modulus both decrease as
the annealing temperature and indentation load are increased.
Abstract: In this paper, the dependence of soliton pulses with
respect to phase in a 10Gbps, single channel, dispersion
uncompensated telecommunication system was studied. The
characteristic feature of periodic soliton interaction was noted at the
Interaction point (I=6202.5Km) in one collision length of L=12405.1
Km. The interaction point is located for 10Gbps system with an
initial relative spacing (qo) of soliton as 5.28 using Perturbation
theory. It is shown that, when two in-phase solitons are launched,
they interact at the point I=6202.5 Km, but the interaction could be
restricted with introduction of different phase initially. When the
phase of the input solitons increases, the deviation of soliton pulses at
the ‘I’ also increases. We have successfully demonstrated this effect
in a telecommunication set-up in terms of Quality factor (Q), where
the Q=0 for in-phase soliton. The Q was noted to be 125.9, 38.63,
47.53, 59.60, 161.37, and 78.04 for different phases such as 10o, 20o,
30o, 45o, 60o and 90o degrees respectively at Interaction point (I).
Abstract: We present a gas-liquid microfluidic system as a
reactor to obtain magnetite nanoparticles with an excellent degree of
control regarding their crystalline phase, shape and size. Several
types of microflow approaches were selected to prevent nanomaterial
aggregation and to promote homogenous size distribution. The
selected reactor consists of a mixer stage aided by ultrasound waves
and a reaction stage using a N2-liquid segmented flow to prevent
magnetite oxidation to non-magnetic phases. A milli-fluidic reactor
was developed to increase the production rate where a magnetite
throughput close to 450 mg/h in a continuous fashion was obtained.
Abstract: Chitosan functionalized Fe3O4-Au core shell
nanoparticles have been prepared using a two-step wet chemical
approach using NaBH4 as reducing agent for formation of Au in
ethylene glycol. X-ray diffraction studies shows individual phases of
Fe3O4 and Au in the as prepared samples with crystallite size of 5.9
and 11.4 nm respectively. The functionalization of the core-shell
nanostructure with Chitosan has been confirmed using Fourier
transform infrared spectroscopy along with signatures of octahedral
and tetrahedral sites of Fe3O4 below 600cm-1. Mössbauer
spectroscopy shows decrease in particle-particle interaction in
presence of Au shell (72% sextet) than pure oleic coated Fe3O4
nanoparticles (88% sextet) at room temperature. At 80K, oleic acid
coated Fe3O4 shows only sextets whereas the Chitosan functionalized
Fe3O4 and Chitosan functionalized Fe3O4@Au core shell show
presence of 5 and 11% doublet, respectively.
Abstract: We investigated the structure and electronic properties
of the compound Mg1-xBixO with varying concentrations of 0, ¼, ½,
and ¾ x bismuth in the the cesium chloride (CsCl), zinc-blende
(ZnS), nickel arsenide (NiAs) NaCl (rock-salt) and WZ (wurtzite)
phases. We calculated. The calculations were performed using the
first-principles pseudo-potential method within the framework of spin
density functional theory (DFT).
Abstract: Roadway planning and design is a very complex
process involving five key phases before a project is completed;
planning, project development, final design, right-of-way, and
construction. The planning phase for a new roadway transportation
project is a very critical phase as it greatly affects all latter phases of
the project. A location study is usually performed during the
preliminary planning phase in a new roadway project. The objective
of the location study is to develop alignment alternatives that are cost
efficient considering land acquisition and construction costs. This
paper describes a methodology to develop optimal preliminary
roadway alignments utilizing spatial-data. Four optimization criteria
are taken into consideration; roadway length, land cost, land slope,
and environmental impacts. The basic concept of the methodology is
to convert the proposed project area into a grid, which represents the
search space for an optimal alignment. The aforementioned
optimization criteria are represented in each of the grid’s cells. A
spatial-data optimization technique is utilized to find the optimal
alignment in the search space based on the four optimization criteria.
Two case studies for new roadway projects in Duval County in the
State of Florida are presented to illustrate the methodology. The
optimization output alignments are compared to the proposed Florida
Department of Transportation (FDOT) alignments. The comparison is
based on right-of-way costs for the alignments. For both case studies,
the right-of-way costs for the developed optimal alignments were
found to be significantly lower than the FDOT alignments.
Abstract: Organizational tendencies towards computer-based
information processing have been observed noticeably in the
third-world countries. Many enterprises are taking major initiatives
towards computerized working environment because of massive
benefits of computer-based information processing. However,
designing and developing information resource management software
for small and mid-size enterprises under budget costs and strict
deadline is always challenging for software engineers. Therefore, we
introduced an approach to design mid-size enterprise software by
using the Waterfall model, which is one of the SDLC (Software
Development Life Cycles), in a cost effective way. To fulfill research
objectives, in this study, we developed mid-sized enterprise software
named “BSK Management System” that assists enterprise software
clients with information resource management and perform complex
organizational tasks. Waterfall model phases have been applied to
ensure that all functions, user requirements, strategic goals, and
objectives are met. In addition, Rich Picture, Structured English, and
Data Dictionary have been implemented and investigated properly in
engineering manner. Furthermore, an assessment survey with 20
participants has been conducted to investigate the usability and
performance of the proposed software. The survey results indicated
that our system featured simple interfaces, easy operation and
maintenance, quick processing, and reliable and accurate transactions.
Abstract: A chromium-loaded ash originating from incineration of tannery sludge under anoxic conditions was mixed with low grade soda-lime glass powder coming from commercial glass bottles. The relative weight proportions of ash over glass powder tested were 30/70, 40/60 and 50/50. The solid mixtures, formed in green state compacts, were sintered at the temperature range of 800o C up to 1200o C. The resulting products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectrometry (EDXS) and micro-indentation. The above methods were employed to characterize the various phases, microstructure and hardness of the produced materials. Thermal treatment at 800o C and 1000o C produced opaque ceramic products composed of a variety of chromium-containing and chromium-free crystalline phases. Thermal treatment at 1200o C gave rise to composite products, where only chromium-containing crystalline phases were detected. Hardness results suggest that specific products are serious candidates for structural applications.
Abstract: The paper presents a new method for efficient
innovation process management. Even though the innovation
management methods, tools and knowledge are well established and
documented in literature, most of the companies still do not manage it
efficiently. Especially in SMEs the front end of innovation - problem
identification, idea creation and selection - is often not optimally
performed. Our eMIPS methodology represents a sort of "umbrella
methodology" - a well-defined set of procedures, which can be
dynamically adapted to the concrete case in a company. In daily
practice, various methods (e.g. for problem identification and idea
creation) can be applied, depending on the company's needs. It is
based on the proactive involvement of the company's employees
supported by the appropriate methodology and external experts. The
presented phases are performed via a mixture of face-to-face
activities (workshops) and online (eLearning) activities taking place
in eLearning Moodle environment and using other e-communication
channels. One part of the outcomes is an identified set of
opportunities and concrete solutions ready for implementation. The
other also very important result is connected to innovation
competences for the participating employees related with concrete
tools and methods for idea management. In addition, the employees
get a strong experience for dynamic, efficient and solution oriented
managing of the invention process. The eMIPS also represents a way
of establishing or improving the innovation culture in the
organization. The first results in a pilot company showed excellent
results regarding the motivation of participants and also as to the
results achieved.
Abstract: Control of honey frauds is needed in Ecuador to
protect bee keepers and consumers because simple syrups and new
syrups with eucalyptus are sold as genuine honeys. Authenticity of
Ecuadorian commercial honeys was tested with a vortex emulsion
consisting on one volume of honey:water (1:1) dilution, and two
volumes of diethyl ether. This method allows a separation of phases
in one minute to discriminate genuine honeys that form three phase
and fake honeys that form two phases; 34 of the 42 honeys analyzed
from five provinces of Ecuador were genuine. This was confirmed
with 1H NMR spectra of honey dilutions in deuterated water with an
enhanced amino acid region with signals for proline, phenylalanine
and tyrosine. Classic quality indicators were also tested with this
method (sugars, HMF), indicators of fermentation (ethanol, acetic
acid), and residues of citric acid used in the syrup manufacture. One
of the honeys gave a false positive for genuine, being an admixture of
genuine honey with added syrup, evident for the high sucrose.
Sensory analysis was the final confirmation to recognize the honey
groups studied here, namely honey produced in combs by Apis
mellifera, fake honey, and honey produced in cerumen pots by
Geotrigona, Melipona, and Scaptotrigona. Chloroform extractions of
honey were also done to search lipophilic additives in NMR spectra.
This is a valuable contribution to protect honey consumers, and to
develop the beekeeping industry in Ecuador.
Abstract: Interaction of Schiff base complexes of Iron and
Manganese: Iron [N, N’ Bis (5- (triphenyl phosphonium methyl)
salicylidene) -1, 2 ethanediamine) chloride, [Fe Salen]Cl; Manganese
[N, N’ Bis (5- (triphenyl phosphonium methyl) salicylidene) -1, 2
ethanediamine) acetate, were investigated by spectroscopic and
isothermal titration calorimetry techniques (ITC).
The absorbance spectra of complexes have shown hyper and
hypochromism in the presence of DNA that is indication of
interaction of complexes with DNA. The linear dichroism (LD)
measurements confirmed the bending of DNA in the presence of
complexes.
Furthermore, Isothermal titration calorimetry experiments
approved that complexes bound to DNA on the base of both
electrostatic and hydrophobic interactions. More, ITC profile exhibits
the existence of two binding phases for the complexes. Antibacterial
activity of ligand and complexes were tested in vitro to evaluate their
activity against the gram positive and negative bacteria.
Abstract: Ionic liquids consisting of a phosphonium cationic
moiety and a saccharinate anion are synthesized and compared with
their precursors, phosphonium chlorides, in reference to their
extraction efficiency towards L-lactic acid. On the base of
measurements of the acid and the water partitioning in the
equilibrium biphasic systems, the molar ratios between acid, water
and ionic liquid are estimated which allows to deduce the lactic acid
extractive pathway. The effect of a salting-out addition that
strengthens hydrophobicity in both phases is studied in view to reveal
the best biphasic system with respect to IL low toxicity and high
extraction efficiency.
Abstract: The detection of moving objects from a video image
sequences is very important for object tracking, activity recognition,
and behavior understanding in video surveillance.
The most used approach for moving objects detection / tracking is
background subtraction algorithms. Many approaches have been
suggested for background subtraction. But, these are illumination
change sensitive and the solutions proposed to bypass this problem
are time consuming.
In this paper, we propose a robust yet computationally efficient
background subtraction approach and, mainly, focus on the ability to
detect moving objects on dynamic scenes, for possible applications in
complex and restricted access areas monitoring, where moving and
motionless persons must be reliably detected. It consists of three
main phases, establishing illumination changes invariance,
background/foreground modeling and morphological analysis for
noise removing.
We handle illumination changes using Contrast Limited Histogram
Equalization (CLAHE), which limits the intensity of each pixel to
user determined maximum. Thus, it mitigates the degradation due to
scene illumination changes and improves the visibility of the video
signal. Initially, the background and foreground images are extracted
from the video sequence. Then, the background and foreground
images are separately enhanced by applying CLAHE.
In order to form multi-modal backgrounds we model each channel
of a pixel as a mixture of K Gaussians (K=5) using Gaussian Mixture
Model (GMM). Finally, we post process the resulting binary
foreground mask using morphological erosion and dilation
transformations to remove possible noise.
For experimental test, we used a standard dataset to challenge the
efficiency and accuracy of the proposed method on a diverse set of
dynamic scenes.
Abstract: The aim of this work is to build a model based on
tissue characterization that is able to discriminate pathological and
non-pathological regions from three-phasic CT images. With our
research and based on a feature selection in different phases, we are
trying to design a neural network system with an optimal neuron
number in a hidden layer. Our approach consists of three steps:
feature selection, feature reduction, and classification. For each
region of interest (ROI), 6 distinct sets of texture features are
extracted such as: first order histogram parameters, absolute gradient,
run-length matrix, co-occurrence matrix, autoregressive model, and
wavelet, for a total of 270 texture features. When analyzing more
phases, we show that the injection of liquid cause changes to the high
relevant features in each region. Our results demonstrate that for
detecting HCC tumor phase 3 is the best one in most of the features
that we apply to the classification algorithm. The percentage of
detection between pathology and healthy classes, according to our
method, relates to first order histogram parameters with accuracy of
85% in phase 1, 95% in phase 2, and 95% in phase 3.
Abstract: The decision-making process is theoretically clearly
defined. Generally, it includes the problem identification and
analysis, data gathering, goals and criteria setting, alternatives
development and optimal alternative choice and its implementation.
In practice however, various modifications of the theoretical
decision-making process can occur. The managers can consider some
of the phases to be too complicated or unfeasible and thus they do not
carry them out and conversely some of the steps can be
overestimated.
The aim of the paper is to reveal and characterize the perception of
the individual phases of decision-making process by the managers.
The research is concerned with managers in the military environment
– commanders. Quantitative survey is focused cross-sectionally in the
individual levels of management of the Ministry of Defence of the
Czech Republic. On the total number of 135 respondents the analysis
focuses on which of the decision-making process phases are
problematic or not carried out in practice and which are again
perceived to be the easiest. Then it is examined the reasons of the
findings.
Abstract: Precise capture of plantar 3D surface of the foot at the
loading gait phases on rigid substrates was found to be valuable for
the assessment of the physiology, health and problems of the feet.
Photogrammetry, a precision 3D spatial data capture technique is
suitable for this type of dynamic application. In this research, the
technique is utilised to study the plantar deformation as a result of
having a strip of kinesiology tape on the plantar surface during the
loading phase of gait. For this pilot study, one healthy adult male
subject was recruited under the University’s human research ethics
guidelines for this preliminary study. The 3D plantar deformation
data with and without applying the tape were analysed. The results
and analyses are presented together with detailed findings.