Abstract: Geometry optimizations of metal complexes of Salen(bis(Salicylidene)1,2-ethylenediamine) were carried out at HF and DFT methods employing Lanl2DZ basis set. In this work structural, energies, bond lengths and other physical properties between Mn2+,Cu2+ and Ni2+ ions coordinated by salen–type ligands are examined. All calculations were performed using Gaussian 98W program series. To investigate local aromaticities, NICS were calculated at all centers of rings. The higher the band gap indicating a higher global aromaticity. The possible binding energies have been evaluated. We have evaluated Frequencies and Zero-point energy with freq calculation. The NICS(Nucleous Independent Chemical Shift) Results show Ni(II) complexes are antiaromatic and aromaticites of Mn(II) complexes are larger than Cu(II) complexes. The energy Results show Cu(II) complexes are stability than Mn(II) and Ni(II) complexes.
Abstract: In this study is presented a general methodology to
predict the performance of a continuous near-critical fluid extraction
process to remove compounds from aqueous solutions using hollow
fiber membrane contactors. A comprehensive 2D mathematical
model was developed to study Porocritical extraction process. The
system studied in this work is a membrane based extractor of ethanol
and acetone from aqueous solutions using near-critical CO2.
Predictions of extraction percentages obtained by simulations have
been compared to the experimental values reported by Bothun et al.
[5]. Simulations of extraction percentage of ethanol and acetone
show an average difference of 9.3% and 6.5% with the experimental
data, respectively. More accurate predictions of the extraction of
acetone could be explained by a better estimation of the transport
properties in the aqueous phase that controls the extraction of this
solute.
Abstract: The problem addressed herein is the efficient management of the Grid/Cluster intense computation involved, when the preconditioned Bi-CGSTAB Krylov method is employed for the iterative solution of the large and sparse linear system arising from the discretization of the Modified Helmholtz-Dirichlet problem by the Hermite Collocation method. Taking advantage of the Collocation ma-trix's red-black ordered structure we organize efficiently the whole computation and map it on a pipeline architecture with master-slave communication. Implementation, through MPI programming tools, is realized on a SUN V240 cluster, inter-connected through a 100Mbps and 1Gbps ethernet network,and its performance is presented by speedup measurements included.
Abstract: Self-organizing map (SOM) is a well known data
reduction technique used in data mining. It can reveal structure in
data sets through data visualization that is otherwise hard to detect
from raw data alone. However, interpretation through visual
inspection is prone to errors and can be very tedious. There are
several techniques for the automatic detection of clusters of code
vectors found by SOM, but they generally do not take into account
the distribution of code vectors; this may lead to unsatisfactory
clustering and poor definition of cluster boundaries, particularly
where the density of data points is low. In this paper, we propose the
use of an adaptive heuristic particle swarm optimization (PSO)
algorithm for finding cluster boundaries directly from the code
vectors obtained from SOM. The application of our method to
several standard data sets demonstrates its feasibility. PSO algorithm
utilizes a so-called U-matrix of SOM to determine cluster boundaries;
the results of this novel automatic method compare very favorably to
boundary detection through traditional algorithms namely k-means
and hierarchical based approach which are normally used to interpret
the output of SOM.
Abstract: Kernel function, which allows the formulation of nonlinear variants of any algorithm that can be cast in terms of dot products, makes the Support Vector Machines (SVM) have been successfully applied in many fields, e.g. classification and regression. The importance of kernel has motivated many studies on its composition. It-s well-known that reproducing kernel (R.K) is a useful kernel function which possesses many properties, e.g. positive definiteness, reproducing property and composing complex R.K by simple operation. There are two popular ways to compute the R.K with explicit form. One is to construct and solve a specific differential equation with boundary value whose handicap is incapable of obtaining a unified form of R.K. The other is using a piecewise integral of the Green function associated with a differential operator L. The latter benefits the computation of a R.K with a unified explicit form and theoretical analysis, whereas there are relatively later studies and fewer practical computations. In this paper, a new algorithm for computing a R.K is presented. It can obtain the unified explicit form of R.K in general reproducing kernel Hilbert space. It avoids constructing and solving the complex differential equations manually and benefits an automatic, flexible and rigorous computation for more general RKHS. In order to validate that the R.K computed by the algorithm can be used in SVM well, some illustrative examples and a comparison between R.K and Gaussian kernel (RBF) in support vector regression are presented. The result shows that the performance of R.K is close or slightly superior to that of RBF.
Abstract: Laser Metal Deposition (LMD) is an additive manufacturing process with capabilities that include: producing new
part directly from 3 Dimensional Computer Aided Design (3D CAD)
model, building new part on the existing old component and repairing an existing high valued component parts that would have
been discarded in the past. With all these capabilities and its advantages over other additive manufacturing techniques, the
underlying physics of the LMD process is yet to be fully understood probably because of high interaction between the processing
parameters and studying many parameters at the same time makes it
further complex to understand. In this study, the effect of laser power
and powder flow rate on physical properties (deposition height and
deposition width), metallurgical property (microstructure) and
mechanical (microhardness) properties on laser deposited most
widely used aerospace alloy are studied. Also, because the Ti6Al4V
is very expensive, and LMD is capable of reducing buy-to-fly ratio
of aerospace parts, the material utilization efficiency is also studied.
Four sets of experiments were performed and repeated to establish repeatability using laser power of 1.8 kW and 3.0 kW, powder flow
rate of 2.88 g/min and 5.67 g/min, and keeping the gas flow rate and
scanning speed constant at 2 l/min and 0.005 m/s respectively. The
deposition height / width are found to increase with increase in laser
power and increase in powder flow rate. The material utilization is favoured by higher power while higher powder flow rate reduces
material utilization. The results are presented and fully discussed.
Abstract: Nowadays, the demand for high product quality
focuses extensive attention to the quality of machined surface. The
(CNC) milling machine facilities provides a wide variety of
parameters set-up, making the machining process on the glass
excellent in manufacturing complicated special products compared to
other machining processes. However, the application of grinding
process on the CNC milling machine could be an ideal solution to
improve the product quality, but adopting the right machining
parameters is required. In glass milling operation, several machining
parameters are considered to be significant in affecting surface
roughness. These parameters include the lubrication pressure, spindle
speed, feed rate and depth of cut. In this research work, a fuzzy logic
model is offered to predict the surface roughness of a machined
surface in glass milling operation using CBN grinding tool. Four
membership functions are allocated to be connected with each input
of the model. The predicted results achieved via fuzzy logic model
are compared to the experimental result. The result demonstrated
settlement between the fuzzy model and experimental results with the
93.103% accuracy.
Abstract: R&D risk management has been suggested as one of
the management approaches for accomplishing the goals of public
R&D investment. The investment in basic science and core technology
development is the essential roles of government for securing the
social base needed for continuous economic growth. And, it is also an
important role of the science and technology policy sectors to generate
a positive environment in which the outcomes of public R&D can be
diffused in a stable fashion by controlling the uncertainties and risk
factors in advance that may arise during the application of such
achievements to society and industry. Various policies have already
been implemented to manage uncertainties and variables that may
have negative impact on accomplishing public R& investment goals.
But we may derive new policy measures for complementing the
existing policies and for exploring progress direction by analyzing
them in a policy package from the viewpoint of R&D risk
management.
Abstract: Text Mining is around applying knowledge discovery techniques to unstructured text is termed knowledge discovery in text (KDT), or Text data mining or Text Mining. In Neural Network that address classification problems, training set, testing set, learning rate are considered as key tasks. That is collection of input/output patterns that are used to train the network and used to assess the network performance, set the rate of adjustments. This paper describes a proposed back propagation neural net classifier that performs cross validation for original Neural Network. In order to reduce the optimization of classification accuracy, training time. The feasibility the benefits of the proposed approach are demonstrated by means of five data sets like contact-lenses, cpu, weather symbolic, Weather, labor-nega-data. It is shown that , compared to exiting neural network, the training time is reduced by more than 10 times faster when the dataset is larger than CPU or the network has many hidden units while accuracy ('percent correct') was the same for all datasets but contact-lences, which is the only one with missing attributes. For contact-lences the accuracy with Proposed Neural Network was in average around 0.3 % less than with the original Neural Network. This algorithm is independent of specify data sets so that many ideas and solutions can be transferred to other classifier paradigms.
Abstract: The problem of mapping tasks onto a computational grid with the aim to minimize the power consumption and the makespan subject to the constraints of deadlines and architectural requirements is considered in this paper. To solve this problem, we propose a solution from cooperative game theory based on the concept of Nash Bargaining Solution. The proposed game theoretical technique is compared against several traditional techniques. The experimental results show that when the deadline constraints are tight, the proposed technique achieves superior performance and reports competitive performance relative to the optimal solution.
Abstract: Very few studies have examined performance
implications of strategic alliance announcements in the information
technologies industry from a resource-based view. Furthermore, none
of these studies have investigated resource congruence and alliance
motive as potential sources of abnormal firm performance. This paper
extends upon current resource-based literature to discover and explore
linkages between these concepts and the practical performance of
strategic alliances. This study finds that strategic alliance
announcements have provided overall abnormal positive returns, and
that marketing alliances with marketing resource incongruence have
also contributed to significant firm performance.
Abstract: We provide a supervised speech-independent voice recognition technique in this paper. In the feature extraction stage we propose a mel-cepstral based approach. Our feature vector classification method uses a special nonlinear metric, derived from the Hausdorff distance for sets, and a minimum mean distance classifier.
Abstract: This paper discusses a new, systematic approach to
the synthesis of a NP-hard class of non-regenerative Boolean
networks, described by FON[FOFF]={mi}[{Mi}], where for every
mj[Mj]∈{mi}[{Mi}], there exists another mk[Mk]∈{mi}[{Mi}], such
that their Hamming distance HD(mj, mk)=HD(Mj, Mk)=O(n), (where
'n' represents the number of distinct primary inputs). The method
automatically ensures exact minimization for certain important selfdual
functions with 2n-1 points in its one-set. The elements meant for
grouping are determined from a newly proposed weighted incidence
matrix. Then the binary value corresponding to the candidate pair is
correlated with the proposed binary value matrix to enable direct
synthesis. We recommend algebraic factorization operations as a post
processing step to enable reduction in literal count. The algorithm
can be implemented in any high level language and achieves best
cost optimization for the problem dealt with, irrespective of the
number of inputs. For other cases, the method is iterated to
subsequently reduce it to a problem of O(n-1), O(n-2),.... and then
solved. In addition, it leads to optimal results for problems exhibiting
higher degree of adjacency, with a different interpretation of the
heuristic, and the results are comparable with other methods.
In terms of literal cost, at the technology independent stage, the
circuits synthesized using our algorithm enabled net savings over
AOI (AND-OR-Invert) logic, AND-EXOR logic (EXOR Sum-of-
Products or ESOP forms) and AND-OR-EXOR logic by 45.57%,
41.78% and 41.78% respectively for the various problems.
Circuit level simulations were performed for a wide variety of
case studies at 3.3V and 2.5V supply to validate the performance of
the proposed method and the quality of the resulting synthesized
circuits at two different voltage corners. Power estimation was
carried out for a 0.35micron TSMC CMOS process technology. In
comparison with AOI logic, the proposed method enabled mean
savings in power by 42.46%. With respect to AND-EXOR logic, the
proposed method yielded power savings to the tune of 31.88%, while
in comparison with AND-OR-EXOR level networks; average power
savings of 33.23% was obtained.
Abstract: In the present research, a finite element model is
presented to study the geometrical and material nonlinear behavior of
reinforced concrete plane frames considering soil-structure
interaction. The nonlinear behaviors of concrete and reinforcing steel
are considered both in compression and tension up to failure. The
model takes account also for the number, diameter, and distribution
of rebar along every cross section. Soil behavior is taken into
consideration using four different models; namely: linear-, nonlinear
Winkler's model, and linear-, nonlinear continuum model. A
computer program (NARC) is specially developed in order to
perform the analysis. The results achieved by the present model show
good agreement with both theoretical and experimental published
literature. The nonlinear behavior of a rectangular frame resting on
soft soil up to failure using the proposed model is introduced for
demonstration.
Abstract: Median filters with larger windows offer greater smoothing and are more robust than the median filters of smaller windows. However, the larger median smoothers (the median filters with the larger windows) fail to track low order polynomial trends in the signals. Due to this, constant regions are produced at the signal corners, leading to the loss of fine details. In this paper, an algorithm, which combines the ability of the 3-point median smoother in preserving the low order polynomial trends and the superior noise filtering characteristics of the larger median smoother, is introduced. The proposed algorithm (called the combiner algorithm in this paper) is evaluated for its performance on a test image corrupted with different types of noise and the results obtained are included.
Abstract: Automatic Vehicle Identification (AVI) has many
applications in traffic systems (highway electronic toll collection, red
light violation enforcement, border and customs checkpoints, etc.).
License Plate Recognition is an effective form of AVI systems. In
this study, a smart and simple algorithm is presented for vehicle-s
license plate recognition system. The proposed algorithm consists of
three major parts: Extraction of plate region, segmentation of
characters and recognition of plate characters. For extracting the
plate region, edge detection algorithms and smearing algorithms are
used. In segmentation part, smearing algorithms, filtering and some
morphological algorithms are used. And finally statistical based
template matching is used for recognition of plate characters. The
performance of the proposed algorithm has been tested on real
images. Based on the experimental results, we noted that our
algorithm shows superior performance in car license plate
recognition.
Abstract: We propose a reduced-ordermodel for the instantaneous
hydrodynamic force on a cylinder. The model consists of a system of
two ordinary differential equations (ODEs), which can be integrated
in time to yield very accurate histories of the resultant force and
its direction. In contrast to several existing models, the proposed
model considers the actual (total) hydrodynamic force rather than its
perpendicular or parallel projection (the lift and drag), and captures
the complete force rather than the oscillatory part only. We study
and provide descriptions of the relationship between the model
parameters, evaluated utilizing results from numerical simulations,
and the Reynolds number so that the model can be used at any
arbitrary value within the considered range of 100 to 500 to provide
accurate representation of the force without the need to perform timeconsuming
simulations and solving the partial differential equations
(PDEs) governing the flow field.
Abstract: To deal with random delays in Networked Control System (NCS), Modified Fuzzy PID Controller is introduced in this paper to implement real-time control adaptively. Via adjusting the control signal dynamically, the system performance is improved. In this paper, the design process and the ultimate simulation results are represented. Finally, examples and corresponding comparisons prove the significance of this method.
Abstract: Assessment of IEP (Individual Education Plan) is an
important stage in the area of special education. This paper deals
with this problem by introducing computer software which process
the data gathered from application of IEP. The software is intended
to be used by special education institution in Turkey and allows
assessment of school and family trainings. The software has a user
friendly interface and its design includes graphical developer tools.
Abstract: Heating is inevitable in any bearing operation. This
leads to not only the thinning of the lubricant but also could lead to a
thermal deformation of the bearing. The present work is an attempt to
analyze the influence of thermal deformation on the thermohydrodynamic
lubrication of infinitely long tilted pad slider rough
bearings. As a consequence of heating the slider is deformed and is
assumed to take a parabolic shape. Also the asperities expand leading
to smaller effective film thickness. Two different types of surface
roughness are considered: longitudinal roughness and transverse
roughness. Christensen-s stochastic approach is used to derive the
Reynolds-type equations. Density and viscosity are considered to be
temperature dependent. The modified Reynolds equation, momentum
equation, continuity equation and energy equation are decoupled and
solved using finite difference method to yield various bearing
characteristics. From the numerical simulations it is observed that the
performance of the bearing is significantly affected by the thermal
distortion of the slider and asperities and even the parallel sliders
seem to carry some load.