Abstract: The combination of the properties of graphene oxide
(OG) and PVDF homopolymer makes their combined composite
materials as multifunctional systems with great potential. Knowledge
of the molecular structure is essential for better use. In this work, the
degradation of PVDF polymer exposed to gamma irradiation in
oxygen atmosphere in high dose rate has been studied and compared
to degradation of PVDF/OG composites. The samples were irradiated
with a Co-60 source at constant dose rate, with doses ranging from
100 kGy to 1,000 kGy. In FTIR data shown that the formation of
oxidation products was at the both samples with formation of
carbonyl and hydroxyl groups amongst the most prevalent products
in the pure PVDF samples. In the other hand, the composites samples
exhibit less presence of degradation products with predominant
formation of carbonyl groups, these results also seen in the UV-Vis
analysis. The results show that the samples of composites may have
greater resistance to the irradiation process, since they have less
degradation products than pure PVDF samples seen by spectroscopic
techniques.
Abstract: Reinforced earth structures are generally subjected to cyclic loading generated from earthquakes. This paper presents a summary of the results and analyses of a testing program carried out in a large-scale multi-function geosynthetic testing apparatus that accommodates soil samples up to 1.0 m3. This apparatus performs different shear and pullout tests under both static and cyclic loading. The testing program was carried out to investigate the controlling factors affecting soil/geogrid interaction under cyclic loading. The extensibility of the geogrids, the applied normal stresses, the characteristics of the cyclic loading (frequency, and amplitude), and initial static load within the geogrid sheet were considered in the testing program. Based on the findings of the testing program, the effect of these parameters on the pullout resistance of geogrids, as well as the displacement mobility under cyclic loading were evaluated. Conclusions and recommendations for the design of reinforced earth walls under cyclic loading are presented.
Abstract: The study was meant to identify the impediments to
female sports management and participation in the selected colleges.
Seven colleges of education in the south west parts of the country
were selected for the study. A total of one hundred and five subjects
were sampled to supply data. Only one hundred adequately
completed and returned, copies of the questionnaire were used for
data analysis. The collected data were analysed descriptively. The
result of the study showed that inadequate fund, personnel, facilities
equipment, supplies, management of sports, supervision and coaching
were some of the impediments to female sports management and
participation. Athletes were not encouraged to participate. Based on
the findings, it was recommended that the government should come
to the aid of the colleges by providing fund and other needs that will
make sports attractive for enhanced participation.
Abstract: The layered structure LiNi1/3Co1/3Mn1/3-xAlxO2 (x = 0 ~
0.04) series cathode materials were synthesized by a carbonate
co-precipitation method, followed by a high temperature calcination
process. The influence of Al substitution on the microstructure and
electrochemical performances of the prepared materials was
investigated by X-Ray diffraction (XRD), scanning electron
microscopy (SEM), and galvanostatic charge/discharge test. The
results show that the LiNi1/3Co1/3Mn1/3-xAlxO2 has a well-ordered
hexagonal α-NaFeO2 structure. Although the discharge capacity of
Al-doped samples decreases as x increases,
LiNi1/3Co1/3Mn1/3-0.02Al0.02O2 exhibits superior capacity retention at
high voltage (4.6 V). Therefore, LiNi1/3Co1/3Mn1/3-0.02Al0.02O2 is a
promising material for “green” vehicles.
Abstract: The irradiation of polymeric materials has received
much attention because it can produce diverse changes in chemical
structure and physical properties. Thus, studying the chemical and
structural changes of polymers is important in practice to achieve
optimal conditions for the modification of polymers. The effect of
gamma irradiation on the crystalline structure of poly(vinylidene
fluoride) (PVDF) has been investigated using differential scanning
calorimetry (DSC) and X-ray diffraction techniques (XRD). Gamma
irradiation was carried out in atmosphere air with doses between 100
kGy at 3,000 kGy with a Co-60 source. In the melting thermogram of
the samples irradiated can be seen a bimodal melting endotherm is
detected with two melting temperature. The lower melting
temperature is attributed to melting of crystals originally present and
the higher melting peak due to melting of crystals reorganized upon
heat treatment. These results are consistent with those obtained by
XRD technique showing increasing crystallinity with increasing
irradiation dose, although the melting latent heat is decreasing.
Abstract: The combination of multi–walled carbon nanotubes
(MWCNTs) with polymers offers an attractive route to reinforce the
macromolecular compounds as well as the introduction of new
properties based on morphological modifications or electronic
interactions between the two constituents. As they are only a few
nanometers in dimension, it offers ultra-large interfacial area per
volume between the nano-element and polymer matrix. Nevertheless,
the use of MWCNTs as a rough material in different applications has
been largely limited by their poor processability, insolubility, and
infusibility. Studies concerning the nanofiller reinforced polymer
composites are justified in an attempt to overcome these limitations.
This work presents one preliminary study of MWCNTs dispersion
into the PVDF homopolymer. For preparation, the composite
components were diluted in n,n-dimethylacetamide (DMAc) with
mechanical agitation assistance. After complete dilution, followed by
slow evaporation of the solvent at 60°C, the samples were dried.
Films of about 80 μm were obtained. FTIR and UV-Vis
spectroscopic techniques were used to characterize the
nanocomposites. The appearance of absorption bands in the FTIR
spectra of nanofilled samples, when compared to the spectrum of
pristine PVDF samples, are discussed and compared with the UV-Vis
measurements.
Abstract: Debts reconstruction under some of moratorium
projects is one of important method that highly benefits to both the
Banks and farmers. The method can reduce probabilities for nonprofits
loan. This paper discuss about debts reconstruction and career
development training for farmers in Thailand between 2011 and
2013. The research designed is mix-method between quantitative
survey and qualitative survey. Sample size for quantitative method is
1003 cases. Data gathering procedure is between October and
December 2013. Main results affirmed that debts reconstruction is
needed. And there are numerous benefits from farmers’ career
development training. Many of farmers who attend field school
activities able to bring knowledge learned to apply for the farms’
work. They can reduce production costs. Framers’ quality of life and
their household well-being also improve. This program should apply
in any countries where farmers have highly debts and highly risks for
not return the debts.
Abstract: This paper applies recursive cointegration analysis to
examine the dynamic changes in Feldstein-Horioka saving-investment
(S-I) coefficients across China and the ASEAN-5 countries over time.
To the extent that the S-I coefficients measure international capital
mobility, the main empirical results are as follows. The recursive trace
statistics show that the investment- savings nexus varies in these six
countries. There is no cointegration between investment and savings in
three countries (China, Malaysia, and Singapore), which means that
the mobility of the capital markets in the three is high and that
domestic investment in them will be financed by the global pool of
capital. As to the other three countries (Indonesia, Thailand, and
Philippines), there is cointegration between investment and savings for
part of the sample period in the three, including before 2002 for
Thailand, before 2001 for Indonesia, and before 2002 for Philippines.
This shows these three countries achieved highly mobile and open
capital markets later.
Abstract: This paper investigates the application of metallic
coatings on high fiber volume fraction carbon/epoxy polymer matrix
composites. For the grip of the metallic layer, a method of modifying
the surface of the composite by introducing a mixture of copper and
steel powder (filler powders) which can reduce the impact of thermal
spray particles. The powder was introduced to the surface at the time
of the forming. Arc spray was used to project the zinc coating layer.
The substrate was grit blasted to avoid poor adherence. The porosity, microstructure, and morphology of layers are
characterized by optical microscopy, SEM and image analysis. The
samples were studied also in terms of hardness and erosion resistance.
This investigation did not reveal any visible evidence damage to the
substrates. The hardness of zinc layer was about 25.94 MPa and the
porosity was around (∼6.70%). The erosion test showed that the zinc
coating improves the resistance to erosion. Based on the results
obtained, we can conclude that thermal spraying allows the production
of protective coating on PMC. Zinc coating has been identified as a
compatible material with the substrate. The filler powders layer
protects the substrate from the impact of hot particles and allows
avoiding the rupture of brittle carbon fibers.
Abstract: This paper investigates the thermo-electric effects
around the crack and notch tips under the electric current load. The
research methods include the finite element analysis and thermal
imaging experiment. The finite element solutions show that the electric
current density field concentrates at the crack tip. Due to the Joule
heating, this electric concentration causes the hot spot at the tip zone.
From numerical and experimental results, this hot spot is identified.
The temperature of the hot spot is affected by the electric load,
operation time and geometry of the sample.
Abstract: An analysis of the air tightness level is performed on a representative sample of school classrooms in Southern Spain, which allows knowing the infiltration level of these classrooms, mainly through its envelope, which can affect both energy demand and occupant's thermal comfort. By using a pressurization/depressurization equipment (Blower-Door test), a characterization of 45 multipurpose classrooms have been performed in nine non-university educational institutions of the main climate zones of Southern Spain. In spite of having two doors and a high ratio between glass surface and outer surface, it is possible to see in these classrooms that there is an adequate level of airtightness, since all the n50 values obtained are lower than 9.0 ACH, with an average value around 7.0 ACH.
Abstract: In this research, students’ scientific attitude, computer anxiety, educational use of the Internet, academic achievement, and problematic use of the Internet are analyzed based on different variables (gender, parents’ educational level and daily access to the Internet). The research group involves 361 students from two middle schools which are located in the center of Konya. The “general survey method” is adopted in the research. In accordance with the purpose of the study, percentage, mean, standard deviation, independent samples t--‐test, ANOVA (variance) are employed in the study. A total of four scales are implemented. These four scales include a total of 13 sub-dimensions. The scores from these scales and their subscales are studied in terms of various variables. In the research, students’ scientific attitude, computer anxiety, educational use of the Internet, the problematic Internet use and academic achievement (gender, parent educational level, and daily access to the Internet) are investigated based on various variables and some significant relations are found.
Abstract: Teaching methods include lectures, workshops and
tutorials for the presentation and discussion of ideas have become out
of date; were developed outside the discipline of architecture from
the college of engineering and do not satisfy the architectural
students’ needs and causes them many difficulties in integrating
structure into their design. In an attempt to improve structure
teaching methods, this paper focused upon proposing a supportive
teaching/learning tool using multi-media applications which seeks to
better meet the architecture student’s needs and capabilities and
improve the understanding and application of basic and intermediate
structural engineering and technology principles. Before introducing
the use of multi-media as a supportive teaching tool, a questionnaire
was distributed to third year students of a structural design course
who were selected as a sample to be surveyed forming a sample of 90
cases. The primary aim of the questionnaire was to identify the
students’ learning style and to investigate whether the selected
method of teaching could make the teaching and learning process
more efficient. Students’ reaction on the use of this method was
measured using three key elements indicating that this method is an
appropriate teaching method for the nature of the students and the
course as well.
Abstract: The aim of irrigation is to recharge the available water
in the soil. Quality of irrigation water is essential for the yield and
quality of crops produced, maintenance of soil productivity and
protection of the environment. The analysis of irrigation water arises
as a need to know the impact of irrigation water on the yield of crops,
the effect, and the necessary control measures to rectify the effect of
this for optimum production and yield of crops. This study was conducted to assess the quality of irrigation water
with its performance on crop planted, in Josepdam irrigation scheme
Bacita, Nigeria. Field visits were undertaken to identify and locate
water supply sources and collect water samples from these sources;
X1 Drain, Oshin, River Niger loop and Ndafa. Laboratory
experiments were then undertaken to determine the quality of raw
water from these sources. The analysis was carried for various parameters namely; physical
and chemical analyses after water samples have been taken from four
sources. The samples were tested in laboratory. Results showed that
the raw water sources shows no salinity tendencies with SAR values
less than 1me/l and Ecvaules at Zero while the pH were within the
recommended range by FAO, there are increase in potassium and
sulphate content contamination in three of the location. From this, it
is recommended that there should be proper monitoring of the
scheme by conducting analysis of water and soil in the environment,
preferable test should be carried out at least one year to cover the
impact of seasonal variations and to determine the physical and
chemical analysis of the water used for irrigation at the scheme.
Abstract: This paper aims to link together the concepts of job
satisfaction, work engagement, trust, job meaningfulness and loyalty
to the organisation focusing on specific type of employment –
academic jobs. The research investigates the relationships between
job satisfaction, work engagement and loyalty as well as the impact
of trust and job meaningfulness on the work engagement and loyalty.
The survey was conducted in one of the largest Latvian higher
education institutions and the sample was drawn from academic staff
(n=326). Structured questionnaire with 44 reflective type questions
was developed to measure the constructs. Data was analysed using
SPSS and Smart-PLS software. Variance based structural equation
modelling (PLS-SEM) technique was used to test the model and to
predict the most important factors relevant to employee engagement
and loyalty. The first order model included two endogenous
constructs (loyalty and intention to stay and recommend to work in
this organisation, and employee engagement), as well as six
exogenous constructs (feeling of fair treatment and trust in
management; career growth opportunities; compensation, pay and
benefits; management; colleagues and teamwork; and finally job
meaningfulness). Job satisfaction was developed as second order
construct and both: first and second order models were designed for
data analysis. It was found that academics are more engaged than
satisfied with their work and main reason for that was found to be job
meaningfulness, which is significant predictor for work engagement,
but not for job satisfaction. Compensation is not significantly related
to work engagement, but only to job satisfaction. Trust was not
significantly related neither to engagement, nor to satisfaction,
however, it appeared to be significant predictor of loyalty and
intentions to stay with the University. Paper revealed academic jobs
as specific kind of employment where employees can be more
engaged than satisfied and highlighted the specific role of job
meaningfulness in the University settings.
Abstract: In language learning, second language learners as well
as Native speakers commit errors in their attempt to achieve
competence in the target language. The realm of collocation has to do
with meaning relation between lexical items. In all human language,
there is a kind of ‘natural order’ in which words are arranged or relate
to one another in sentences so much so that when a word occurs in a
given context, the related or naturally co-occurring word will
automatically come to the mind. It becomes an error, therefore, if
students inappropriately pair or arrange such ‘naturally’ co–occurring
lexical items in a text. It has been observed that most of the second
language learners in this research group commit collocation errors. A
study of this kind is very significant as it gives insight into the kinds
of errors committed by learners. This will help the language teacher
to be able to identify the sources and causes of such errors as well as
correct them thereby guiding, helping and leading the learners
towards achieving some level of competence in the language. The
aim of the study is to understand the nature of these errors as
stumbling blocks to effective essay writing. The objective of the
study is to identify the errors, analyze their structural compositions so
as to determine whether there are similarities between students in this
regard and to find out whether there are patterns to these kinds of
errors which will enable the researcher to understand their sources
and causes. As a descriptive research, the researcher samples some
nine hundred essays collected from three hundred undergraduate
learners of English as a second language in the Federal College of
Education, Kano, North- West Nigeria, i.e. three essays per each
student. The essays which were given on three different lecture times
were of similar thematic preoccupations (i.e. same topics) and length
(i.e. same number of words). The essays were written during the
lecture hour at three different lecture occasions. The errors were
identified in a systematic manner whereby errors so identified were
recorded only once even if they occur severally in students’ essays.
The data was collated using percentages in which the identified
numbers of occurrences were converted accordingly in percentages.
The findings from the study indicate that there are similarities as well
as regular and repeated errors which provided a pattern. Based on the
pattern identified, the conclusion is that students’ collocation errors
are attributable to poor teaching and learning which resulted in wrong
generalization of rules.
Abstract: Multiple Sclerosis (MS) is a disease which affects the
central nervous system and causes balance problem. In clinical, this
disorder is usually evaluated using static posturography. Some linear
or nonlinear measures, extracted from the posturographic data (i.e.
center of pressure, COP) recorded during a balance test, has been
used to analyze postural control of MS patients. In this study, the
trend (TREND) and the sample entropy (SampEn), two nonlinear
parameters were chosen to investigate their relationships with the
expanded disability status scale (EDSS) score. 40 volunteers with
different EDSS scores participated in our experiments with eyes open
(EO) and closed (EC). TREND and 2 types of SampEn (SampEn1
and SampEn2) were calculated for each combined COP’s position
signal. The results have shown that TREND had a weak negative
correlation to EDSS while SampEn2 had a strong positive correlation
to EDSS. Compared to TREND and SampEn1, SampEn2 showed a
better significant correlation to EDSS and an ability to discriminate
the MS patients in the EC case. In addition, the outcome of the study
suggests that the multi-dimensional nonlinear analysis could provide
some information about the impact of disability progression in MS on
dynamics of the COP data.
Abstract: This paper presents the experimental results of 11 kV
and 33 kV silicon composite insulators under artificial salt and urea
polluted conditions. The tests were carried out under different
seasons like summer, winter, and monsoon. The artificial pollution is
prepared by properly dissolving the salt and urea in the water. The
prepared salt and urea pollutions are sprayed on the insulators and
dried up for sufficiently large time. The process is continued until a
uniform layer is formed on the surface of insulator. For each insulator
rating, four samples were tested. The maximum leakage current and
breakdown voltage were measured. From experimental data,
performance of test specimen is evaluated by comparing breakdown
voltage and leakage current during different seasons when exposed to
salt and urea polluted conditions. From these results the performance
of the insulators can be predicted when they are installed in
industrial, agricultural, and coastal areas. The experimental tests were
carried out in the High Voltage laboratory using two stage cascade
transformer having the rating of 1000 kVA, 500 kV.
Abstract: The study assessed the effectiveness of Pawpaw
(Carica papaya) wood in reducing the concentrations of heavy
metals in wastewater acting as a bio-sorbent. The following heavy
metals were considered; Zinc, Cadmium, Lead, Copper, Iron,
Selenium, Nickel and Manganese. The physiochemical properties of
Carica papaya stem were studied. The experimental sample was
sourced from the trunk of a felled matured pawpaw tree. Wastewater
for experimental use was prepared by dissolving soil samples
collected from a dump site at Owerri, Imo state of Nigeria in water.
The concentration of each metal remaining in solution as residual
metal after bio-sorption was determined using Atomic absorption
Spectrometer. The effects of pH and initial heavy metal concentration
were studied in a batch reactor. The results of Spectrometer test
showed that there were different functional groups detected in the
Carica papaya stem biomass. There was increase in metal removal as
the pH increased for all the metals considered except for Nickel and
Manganese. Optimum bio-sorption occurred at pH 5.9 with 5g/100ml
solution of bio-sorbent. The results of the study showed that the
treated wastewater is fit for irrigation purpose based on Canada
wastewater quality guideline for the protection of Agricultural
standard. This approach thus provides a cost effective and
environmentally friendly option for treating wastewater.
Abstract: The research aims to investigate the occurrence of
multidrug-resistant Acinetobacter, in carrot and estimate the role of
carrot in its transmission in a rapidly growing urban population.
Thus, 50 carrot samples were collected from Jakara wastewater
irrigation farms and are analyzed on MacConkey agar and screened
by Microbact 24E (Oxoid) and susceptibility of isolates is tested
against 10 commonly used antibiotics. Acinetobacter baumannii and
A. lwoffii were isolated in 22.00% and 16% of samples respectively.
Resistance to ceporex and penicillin of 36.36% and 27.27% in A.
baumannii, and sensitivity to ofloxacin, pefloxacin, gentimycin and
co-trimoxazole were observed. However, for A. lwoffii apart from
37.50% resistance to ceporex, it was also resistant to all other drugs
tested. There were similarities in the resistances shown by A.
baumannii and A. lwoffii to fluoroquinolones and β- lactame drug
families in addition to between sulfonamide and animoglycoside
demonstrated by A. lwoffii. Significant correlation in similarities were
observed at P < 0.05 to CPX to NA (46.2%), and SXT to AU (52.6%)
A. baumannii and A. lwoffii respectively and high multi drug
resistance (MDR) of 27.27% and 62.50% by A. baumannii and A.
lwoffii respectively. The occurrence of multidrug-resistance pathogen
in carrot is a serious challenge to public health care, especially in a
rapidly growing urban population where subsistence agriculture
contributes greatly to urban livelihood and source of vegetables.