Abstract: In our recent study, we have used ZnO nanoparticles assisted with UV light irradiation to investigate the photocatalytic degradation of Phenol Red (PR). The ZnO photocatalyst was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), specific surface area analysis (BET) and UVvisible spectroscopy. X-ray diffractometry result for the ZnO nanoparticles exhibit normal crystalline phase features. All observed peaks can be indexed to the pure hexagonal wurtzite crystal structures, with the space group of P63mc. There are no other impurities in the diffraction peak. In addition, TEM measurement shows that most of the nanoparticles are rod-like and spherical in shape and fairly monodispersed. A significant degradation of the PR was observed when the catalyst was added into the solution even without the UV light exposure. In addition, the photodegradation increases with the photocatalyst loading. The surface area of the ZnO nanomaterials from the BET measurement was 11.9 m2/g. Besides the photocatalyst loading, the effect of some parameters on the photodegradation efficiency such as initial PR concentration and pH were also studied.
Abstract: Transport and logistics are the lifeblood of societies.
There is a strong correlation between overall growth in economic
activity and growth of transport. The movement of people and goods
has the potential for creating wealth and prosperity, therefore the
state of transportation infrastructure and especially the condition of
road networks is often a governmental priority. The design, building
and maintenance of national roads constitute a substantial share of
government budgets. Taking into account the magnitude and
importance of these investments, the expedience, efficiency and
sustainability of these projects are of great public interest. This paper
provides an overview of supply chain management principles applied
to road construction. In addition, road construction performance
measurement systems and ICT solutions are discussed. Road
construction in Estonia is analyzed. The authors propose the
development of a national performance measurement system for road
construction.
Abstract: This study presents an active vibration control
technique to reduce the earthquake responses of a retained structural
system. The proposed technique is a synthesis of the adaptive input
estimation method (AIEM) and linear quadratic Gaussian (LQG)
controller. The AIEM can estimate an unknown system input online.
The LQG controller offers optimal control forces to suppress
wall-structural system vibration. The numerical results show robust
performance in the active vibration control technique.
Abstract: Due to heightened concerns over environmental and economic issues the growing important of air pollution, and the importance of conserving fossil fuel resources in the world, the automotive industry is now forced to produce more fuel efficient, low emission vehicles and new drive system technologies. One of the most promising technologies to receive attention is the hybrid electric vehicle (HEV), which consists of two or more energy sources that supply energy to electric traction motors that in turn drive the wheels. This paper presents the various structures of HEV systems, the basic theoretical knowledge for describing their operation and the general behaviour of the HEV in acceleration, cruise and deceleration phases. The conventional design and sizing of a series HEV is studied. A conventional bus and its series configuration are defined and evaluated using the ADVISOR. In this section the simulation of a standard driving cycle and prediction of its fuel consumption and emissions of the HEV are discussed. Finally the bus performance is investigated to establish whether it can satisfy the performance, fuel consumption and emissions requested. The validity of the simulation has been established by the close conformity between the fuel consumption of the conventional bus reported by the manufacturer to what has achieved from the simulation.
Abstract: In this paper, the detection of a fault in the Global Positioning System (GPS) measurement is addressed. The class of faults considered is a bias in the GPS pseudorange measurements. This bias is modeled as an unknown constant. The fault could be the result of a receiver fault or signal fault such as multipath error. A bias bank is constructed based on set of possible fault hypotheses. Initially, there is equal probability of occurrence for any of the biases in the bank. Subsequently, as the measurements are processed, the probability of occurrence for each of the biases is sequentially updated. The fault with a probability approaching unity will be declared as the current fault in the GPS measurement. The residual formed from the GPS and Inertial Measurement Unit (IMU) measurements is used to update the probability of each fault. Results will be presented to show the performance of the presented algorithm.
Abstract: Wet chemistry methods are used to prepare the
SiO2/Au nanoshells. The purpose of this research was to synthesize
gold coated SiO2 nanoshells for biomedical applications. Tunable
nanoshells were prepared by using different colloidal concentrations.
The nanoshells are characterized by FTIR, XRD, UV-Vis
spectroscopy and atomic force microscopy (AFM). The FTIR results
confirmed the functionalization of the surfaces of silica nanoparticles
with NH2 terminal groups. A tunable absorption was observed
between 470-600 nm with a maximum range of 530-560 nm. Based
on the XRD results three main peaks of Au (111), (200) and (220)
were identified. Also AFM results showed that the silica core
diameter was about 100 nm and the thickness of gold shell about 10
nm.
Abstract: Many real-world optimization problems involve multiple conflicting objectives and the use of evolutionary algorithms to solve the problems has attracted much attention recently. This paper investigates the application of multi-objective optimization technique for the design of a Thyristor Controlled Series Compensator (TCSC)-based controller to enhance the performance of a power system. The design objective is to improve both rotor angle stability and system voltage profile. A Genetic Algorithm (GA) based solution technique is applied to generate a Pareto set of global optimal solutions to the given multi-objective optimisation problem. Further, a fuzzy-based membership value assignment method is employed to choose the best compromise solution from the obtained Pareto solution set. Simulation results are presented to show the effectiveness and robustness of the proposed approach.
Abstract: In literature, there are metrics for identifying the
quality of reusable components but the framework that makes use of
these metrics to precisely predict reusability of software components
is still need to be worked out. These reusability metrics if identified
in the design phase or even in the coding phase can help us to reduce
the rework by improving quality of reuse of the software component
and hence improve the productivity due to probabilistic increase in
the reuse level. As CK metric suit is most widely used metrics for
extraction of structural features of an object oriented (OO) software;
So, in this study, tuned CK metric suit i.e. WMC, DIT, NOC, CBO
and LCOM, is used to obtain the structural analysis of OO-based
software components. An algorithm has been proposed in which the
inputs can be given to K-Means Clustering system in form of
tuned values of the OO software component and decision tree is
formed for the 10-fold cross validation of data to evaluate the in
terms of linguistic reusability value of the component. The developed
reusability model has produced high precision results as desired.
Abstract: Requirements that should be met when determining the regimes of circuits with variable elements are formulated. The interpretation of the variations in the regimes, based on projective geometry, enables adequate expressions for determining and comparing the regimes to be derived. It is proposed to use as the parameters of a generalized equivalent generator of an active two-pole with changeable resistor such load current and voltage which provide the current through this resistor equal to zero.
Abstract: The main purpose of the study was to determine whether students- interpretation achievement differed with the use of various multimedia presentation types. Four groups of students, text only (T), audio only (A), text and audio (TA), text and image (TI), were arranged and they were presented the same story via different types of multimedia presentations. Inference achievement was measured by a critical thinking inference test. Higher mean scores for the TA group compared to the other three groups were found. Also when compared pairwise, interpretation achievement of the TA group differed significantly from scores of the T and TI groups. These differences were interpreted with the increased cognitive load. Increased cognitive load for the TA group may have invited students to put more effort into comprehending the text, thus resulting in better test scores. Findings of the study can be seen as a sign of the importance of learning situations and learning outcomes in multimedia-supported learning environments and may have practical benefits for instructional designers.
Abstract: Protective coatings that resist oxide scale growth and
decrease chromium evaporation are necessary to make stainless steel
interconnect materials for long-term durable operation of solid oxide
fuel cells (SOFCs). In this study a layer of cobalt was electroplated
on the surface of AISI 441 ferritic stainless steel which is used in
solid oxide fuel cells for interconnect applications. The oxidation
behavior of coated substrates was studied as a function of time at
operating conditions of SOFCs. Cyclic oxidation has been also tested
at 800ºC for 100 cycles. Cobalt coating during isothermal oxidation
caused to the oxide growth resistance by limiting the outward
diffusion of Cr cation and the inward diffusion of oxygen anion.
Results of cyclic oxidation exhibited that coated substrates
demonstrate an excellent resistance against the spallation and
cracking.
Abstract: A measurement system for pH array sensors is
introduced to increase accuracy, and decrease non-ideal effects
successfully. An array readout circuit reads eight potentiometric
signals at the same time, and obtains an average value. The deviation
value or the extreme value is counteracted and the output voltage is a
relatively stable value. The errors of measuring pH buffer solutions are
decreased obviously with this measurement system, and the non-ideal
effects, drift and hysteresis, are lowered to 1.638mV/hr and 1.118mV,
respectively. The efficiency and stability are better than single sensor.
The whole sensing characteristics are improved.
Abstract: In this paper, the construction of a detailed spine
model is presented using the LifeMOD Biomechanics Modeler. The
detailed spine model is obtained by refining spine segments in
cervical, thoracic and lumbar regions into individual vertebra
segments, using bushing elements representing the intervertebral
discs, and building various ligamentous soft tissues between
vertebrae. In the sagittal plane of the spine, constant force will be
applied from the posterior to anterior during simulation to determine
dynamic characteristics of the spine. The force magnitude is
gradually increased in subsequent simulations. Based on these
recorded dynamic properties, graphs of displacement-force
relationships will be established in terms of polynomial functions by
using the least-squares method and imported into a haptic integrated
graphic environment. A thoracolumbar spine model with complex
geometry of vertebrae, which is digitized from a resin spine
prototype, will be utilized in this environment. By using the haptic
technique, surgeons can touch as well as apply forces to the spine
model through haptic devices to observe the locomotion of the spine
which is computed from the displacement-force relationship graphs.
This current study provides a preliminary picture of our ongoing
work towards building and simulating bio-fidelity scoliotic spine
models in a haptic integrated graphic environment whose dynamic
properties are obtained from LifeMOD. These models can be helpful
for surgeons to examine kinematic behaviors of scoliotic spines and
to propose possible surgical plans before spine correction operations.
Abstract: This paper presents a procedure of forming the
mathematical model of radial electric power systems for simulation
of both transient and steady-state conditions. The research idea has
been based on nodal voltages technique and on differentiation of
Kirchhoff's current law (KCL) applied to each non-reference node of
the radial system, the result of which the nodal voltages has been
calculated by solving a system of algebraic equations. Currents of the
electric power system components have been determined by solving
their respective differential equations. Transforming the three-phase
coordinate system into Cartesian coordinate system in the model
decreased the overall number of equations by one third. The use of
Cartesian coordinate system does not ignore the DC component
during transient conditions, but restricts the model's implementation
for symmetrical modes of operation only. An example of the input
data for a four-bus radial electric power system has been calculated.
Abstract: Absorptive characteristics of polyaniline synthesized
in mixture of water and acetonitrile in 50/50 volume ratio was
studied. Synthesized polyaniline in powder shape is used as an
adsorbent to remove toxic hexavalent chromium from aqueous
solutions. Experiments were conducted in batch mode with different
variables such as agitation time, solution pH and initial concentration
of hexavalent chromium. Removal mechanism is the combination of
surface adsorption and reduction. The equilibrium time for removal
of Cr(T) and Cr(VI) was about 2 and 10 minutes respectively. The
optimum pH for total chromium removal occurred at pH 7 and
maximum hexavalent chromium removal took place under acidic
condition at pH 3. Investigating the isothermal characteristics showed
that the equilibrium adsorption data fitted both Freundlich-s and
Langmuir-s isotherms. The maximum adsorption of chromium was
calculated 36.1 mg/g for polyaniline
Abstract: The agriculture lignocellulosic by-products are receiving increased attention, namely in the search for filter materials that retain contaminants from water. These by-products, specifically almond and hazelnut shells are abundant in Portugal once almond and hazelnuts production is a local important activity. Hazelnut and almond shells have as main constituents lignin, cellulose and hemicelluloses, water soluble extractives and tannins. Along the adsorption of heavy metals from contaminated waters, water soluble compounds can leach from shells and have a negative impact in the environment. Usually, the chemical characterization of treated water by itself may not show environmental impact caused by the discharges when parameters obey to legal quality standards for water. Only biological systems can detect the toxic effects of the water constituents. Therefore, the evaluation of toxicity by biological tests is very important when deciding the suitability for safe water discharge or for irrigation applications.
The main purpose of the present work was to assess the potential impacts of waters after been treated for heavy metal removal by hazelnut and almond shells adsorption systems, with short term acute toxicity tests.
To conduct the study, water at pH 6 with 25 mg.L-1 of lead, was treated with 10 g of shell per litre of wastewater, for 24 hours. This procedure was followed for each bark. Afterwards the water was collected for toxicological assays; namely bacterial resistance, seed germination, Lemna minor L. test and plant grow. The effect in isolated bacteria strains was determined by disc diffusion method and the germination index of seed was evaluated using lettuce, with temperature and humidity germination control for 7 days. For aquatic higher organism, Lemnas were used with 4 days contact time with shell solutions, in controlled light and temperature. For terrestrial higher plants, biomass production was evaluated after 14 days of tomato germination had occurred in soil, with controlled humidity, light and temperature.
Toxicity tests of water treated with shells revealed in some extent effects in the tested organisms, with the test assays showing a close behaviour as the control, leading to the conclusion that its further utilization may not be considered to create a serious risk to the environment.
Abstract: The work presented in this paper focus on Knowledge Management services enabling CSCW (Computer Supported Cooperative Work) applications to provide an appropriate adaptation to the user and the situation in which the user is working. In this paper, we explain how a knowledge management system can be designed to support users in different situations exploiting contextual data, users' preferences, and profiles of involved artifacts (e.g., documents, multimedia files, mockups...). The presented work roots in the experience we had in the MILK project and early steps made in the MAIS project.
Abstract: Two-interconnected fluidized bed systems are widely used in various processes such as Fisher-Tropsch, hot gas desulfurization, CO2 capture-regeneration with dry sorbent, chemical-looping combustion, sorption enhanced steam methane reforming, chemical-looping hydrogen generation system, and so on. However, most of two-interconnected fluidized beds systems require riser and/or pneumatic transport line for solid conveying and loopseals or seal-pots for gas sealing, recirculation of solids to the riser, and maintaining of pressure balance. The riser (transport bed) is operated at the high velocity fluidization condition and residence times of gas and solid in the riser are very short. If the reaction rate of catalyst or sorbent is slow, the riser can not ensure sufficient contact time between gas and solid and we have to use two bubbling beds for each reaction to ensure sufficient contact time. In this case, additional riser must be installed for solid circulation. Consequently, conventional two-interconnected fluidized bed systems are very complex, large, and difficult to operate. To solve these problems, a novel two-interconnected fluidized bed system has been developed. This system has two bubbling beds, solid injection nozzles, solid conveying lines, and downcomers. In this study, effects of operating variables on solid circulation rate, gas leakage between two beds have been investigated in a cold mode two-interconnected fluidized bed system. Moreover, long-term operation of continuous solid circulation up to 60 hours has been performed to check feasibility of stable operation.
Abstract: This paper presents the design, fabrication and
evaluation of magneto-rheological damper. Semi-active control
devices have received significant attention in recent years because
they offer the adaptability of active control devices without requiring
the associated large power sources. Magneto-Rheological (MR)
dampers are semi- active control devices that use MR fluids to
produce controllable dampers. They potentially offer highly reliable
operation and can be viewed as fail-safe in that they become passive
dampers if the control hardware malfunction. The advantage of MR
dampers over conventional dampers are that they are simple in
construction, compromise between high frequency isolation and
natural frequency isolation, they offer semi-active control, use very
little power, have very quick response, has few moving parts, have a
relax tolerances and direct interfacing with electronics. Magneto-
Rheological (MR) fluids are Controllable fluids belonging to the
class of active materials that have the unique ability to change
dynamic yield stress when acted upon by an electric or magnetic
field, while maintaining viscosity relatively constant. This property
can be utilized in MR damper where the damping force is changed by
changing the rheological properties of the fluid magnetically. MR
fluids have a dynamic yield stress over Electro-Rheological fluids
(ER) and a broader operational temperature range. The objective of
this papert was to study the application of an MR damper to vibration
control, design the vibration damper using MR fluids, test and
evaluate its performance. In this paper the Rheology and the theory
behind MR fluids and their use on vibration control were studied.
Then a MR vibration damper suitable for vehicle suspension was
designed and fabricated using the MR fluid. The MR damper was
tested using a dynamic test rig and the results were obtained in the
form of force vs velocity and the force vs displacement plots. The
results were encouraging and greatly inspire further research on the
topic.
Abstract: The composite materials were prepared by sawdust, cassava starch and natural rubber latex (NR). The mixtures of 15%w/v gelatinized cassava starch and 15%w/v PVOH were used as the binder of these composite materials. The concentrated rubber latex was added to the mixtures. They were mixed rigorously to the treated sawdust in the ratio of 70:30 until achive uniform dispersion. The batters were subjected to the hot compression moulding at the temperature of 160°C and 3,000 psi pressure for 5 min. The experimental results showed that the mechanical properties of composite materials, which contained the gelatinized cassava starch and PVOH in the ratio of 2:1, 20% NR latex by weight of the dry starch and treated sawdust with 5%NaOH or 1% BPO, were the best. It contributed the maximal compression strength (341.10 + 26.11 N), puncture resistance (8.79 + 0.98 N/mm2) and flexural strength (3.99 + 0.72N/mm2). It is also found that the physicochemical and mechanical properties of composites strongly depends on the interface quality of sawdust, cassava starch and NR latex.