Abstract: The biosynthesis of nanoparticles by microorganisms,
on the contrary to chemical synthesis, is an environmentally-friendly
process which has low energy requirements. In this investigation, we
used the microorganism Geobacillus wiegelii, strain GWE1, an
aerobic thermophile belonging to genus Geobacillus, isolated from a
drying oven. This microorganism has the ability to reduce selenite
evidenced by the change of color from colorless to red in the culture.
Elemental analysis and composition of the particles were verified
using transmission electron microscopy and energy-dispersive X-ray
analysis. The nanoparticles have a defined spherical shape and a
selenium elemental state. Previous experiments showed that the
presence of the whole microorganism for the reduction of selenite
was not necessary. The results strongly suggested that an intracellular
NADPH/NADH-dependent reductase mediates selenium
nanoparticles synthesis under aerobic conditions. The enzyme was
purified and identified by mass spectroscopy MALDI-TOF TOF
technique. The enzyme is a 1-pyrroline-5-carboxylate dehydrogenase.
Histograms of nanoparticles sizes were obtained. Size distribution
ranged from 40-160 nm, where 70% of nanoparticles have less than
100 nm in size. Spectroscopic analysis showed that the nanoparticles
are composed of elemental selenium. To analyse the effect of pH in
size and morphology of nanoparticles, the synthesis of them was
carried out at different pHs (4.0, 5.0, 6.0, 7.0, 8.0). For
thermostability studies samples were incubated at different
temperatures (60, 80 and 100 ºC) for 1 h and 3 h. The size of all
nanoparticles was less than 100 nm at pH 4.0; over 50% of
nanoparticles have less than 100 nm at pH 5.0; at pH 6.0 and 8.0 over
90% of nanoparticles have less than 100 nm in size. At neutral pH
(7.0) nanoparticles reach a size around 120 nm and only 20% of them
were less than 100 nm. When looking at temperature effect,
nanoparticles did not show a significant difference in size when they
were incubated between 0 and 3 h at 60 ºC. Meanwhile at 80 °C the
nanoparticles suspension lost its homogeneity. A change in size was
observed from 0 h of incubation at 80ºC, observing a size range
between 40-160 nm, with 20% of them over 100 nm. Meanwhile
after 3 h of incubation at size range changed to 60-180 nm with 50%
of them over 100 nm. At 100 °C the nanoparticles aggregate forming
nanorod structures. In conclusion, these results indicate that is
possible to modulate size and shape of biologically synthesized
nanoparticles by modulating pH and temperature.
Abstract: The purpose of this study was to investigate
perceptions of climate change risk to forest ecosystems and forestbased
communities as well as perceived effectiveness of adaptation
strategies for climate change as well as challenges for adaptation.
Data was gathered using a pre-tested semi-structured questionnaire.
Simple random selection technique was applied. For the majority of
issues, the responses were obtained on multi-point likert scales, and
the scores provided were, in turn, used to estimate the means and
other useful estimates. A composite knowledge index developed
using correct responses to a set of self-rated statements were used to
evaluate the issues. The mean of the knowledge index was 0.64. Also
all respondents recorded values of the knowledge index above 0.25.
Increase forest fire was perceived by respondents as the greatest risk
to forest eco-system. Decrease access to water supplies was perceived
as the greatest risk to livelihoods of forest based communities. The
most effective adaptation strategy relevant to climate change risks to
forest eco-systems and forest based communities livelihoods in
Kathmandu valley in Nepal as perceived by the respondents was
reforestation and afforestation. As well, lack of public awareness was
perceived as the major limitation for climate change adaptation.
However, perceived risks as well as effective adaptation strategies
showed an inconsistent association with knowledge indicators and
social-cultural variables. The results provide useful information to
any party who involve with climate change issues in Nepal, since
such attempts would be more effective once the people’s perceptions
on these aspects are taken into account.
Abstract: In this paper it was examined the influence of margin
regulation on stock market volatility in EU 1993 – 2014. Regulating
margin requirements or haircuts for securities financing transactions
has for a long time been considered as a potential tool to limit the
build-up of leverage and dampen volatility in financial markets. The
margin requirement dictates how much investors can borrow against
these securities. Margin can be an important part of investment.
Using daily and monthly stock returns and there is no convincing
evidence that EU Regulation margin requirements have served to
dampen stock market volatility. In this paper was detected the
expected negative relation between margin requirements and the
amount of margin credit outstanding. Also, it confirmed that changes
in margin requirements by the EU regulation have tended to follow
than lead changes in market volatility. For the analysis have been
used the modified Levene statistics to test whether the standard
deviation of stock returns in the 25, 50 and 100 days preceding
margin changes is the same as that in the succeeding 25, 50 and 100
days. The analysis started in May 1993 when it was first empowered
to set the initial margin requirement and the last sample was in May
2014. To test whether margin requirements influence stock market
volatility over the long term, the sample of stock returns was divided
into 14 periods, according to the 14 changes in margin requirements.
Abstract: This paper contains 2 main parts. In the first part of paper we simulated and studied three types of electrode patterns used in various industries for suspension and handling of the semiconductor and glass and we selected the best pattern by evaluating the electrostatic force, which was comb pattern electrode.
In the second part we investigated the parameters affecting the amount of electrostatic force such as the gap between surface and electrode (g), the electrode width (w), the gap between electrodes (t), the surface permittivity and electrode length and methods of improvement of adhesion force by changing these values.
Abstract: Composites depending on the nature of their
constituents and mode of production are regarded as one of the
advanced materials that drive today’s technology. This paper
attempts a short review of the subject matter with a general aim of
pushing to the next level the frontier of knowledge as it impacts the
technology of nano-particles manufacturing. The objectives entail an
effort to; aggregate recent research efforts in this field, analyse
research findings and observations, streamline research efforts and
support industry in taking decision on areas of fund deployment. It is
envisaged that this work will serve as a quick hand-on compendium
material for researchers in this field and a guide to relevant
government departments wishing to fund a research whose outcomes
have the potential of improving the nation’s GDP.
Abstract: Magnetic powder of Sr-ferrite was prepared by
conventional and sol-gel auto-combustion methods. In conventional
method, strontium carbonate and ferric oxide powders were mixed
together and then mixture was calcined. In sol-gel auto-combustion
method, a solution containing strontium nitrate, ferric nitrate and
citric acid was heated until the combustion took place automatically;
then, as-burnt powder was calcined. Thermal behavior, phase
identification, morphology and magnetic properties of powders
obtained by these two methods were compared by DTA, XRD, SEM
and VSM techniques. According to the results of DTA analysis,
formation temperature of Sr-ferrite obtained by conventional and solgel
auto-combustion methods were 1300°C and 1000°C, respectively.
XRD results confirmed the formation of pure Sr-ferrite at the
mentioned temperatures. Plate and hexagonal-shape particles of Srferrite
were observed using SEM. The Sr-ferrite powder obtained by
sol-gel auto-combustion method had saturation magnetization of
66.03 emu/g and coercivity of 5731 Oe in comparison with values of
58.20 emu/g and 4378 Oe obtained by conventional method.
Abstract: A series of polystyrene (PS) nanoparticles were
prepared by grafting polystyrene from both aggregated silica and
colloidally dispersed silica nanoparticles using atom-transfer radical
polymerisation (ATRP). Cross-linking and macroscopic gelation
were minimised by using a miniemulsion system. The thermal and
mechanical behaviour of the nanocomposites have been examined by
differential scanning calorimetry (DSC) and dynamic mechanical
thermal analysis (DMTA).
Abstract: In an urban area the location allocation of emergency
services mobile units, such as ambulances, police patrol cars must be
designed so as to achieve a prompt response to demand locations.
In this paper the partition of a given urban network into distinct
sub-networks is performed such that the vertices in each component
are close and simultaneously the sums of the corresponding
population in the sub-networks are almost uniform. The objective
here is to position appropriately in each sub-network a mobile
emergency unit in order to reduce the response time to the demands.
A mathematical model in framework of graph theory is developed.
In order to clarify the corresponding method a relevant numerical
example is presented on a small network.
Abstract: Series of laboratory tests were carried out to study the
extent of scour caused by a three-dimensional wall jets exiting from a
square cross-section nozzle and into a non-cohesive sand beds.
Previous observations have indicated that the effect of the tail water
depth was significant for densimetric Froude number greater than ten.
However, the present results indicate that the cut off value could be
lower depending on the value of grain size-to-nozzle width ratio.
Numbers of equations are drawn out for a better scaling of numerous
scour parameters. Also suggested the empirical prediction of scour to
predict the scour centre line profile and plan view of scour profile at
any particular time.
Abstract: Collapsible soils go through radical rearrangement of
their particles when triggered by water, stress or/and vibration,
causing loss of volume. This loss of volume in soil as seen in
foundation failures has caused millions of dollars’ worth of damages
to public facilities and infrastructure and so has an adverse effect on
the society and people. Despite these consequences and the several
studies that are available, more research is still required in the study
of soil collapsibility. Discerning the pedogenesis (formation) of soils
and investigating the combined effects of the different geological soil
properties is key to elucidating and quantifying soils collapsibility.
This study presents a novel laboratory testing regime that would be
undertaken on soil samples where the effects of soil type, compactive
variables (moisture content, density, void ratio, degree of saturation)
and loading are analyzed. It is anticipated that results obtained would
be useful in mapping the trend of the combined effect thus the basis
for evaluating soil collapsibility or collapse potentials encountered in
construction with volume loss problems attributed to collapse.
Abstract: South Africa has some regions which are susceptible
to moderate seismic activity. A peak ground acceleration of between
0.1g and 0.15g can be expected in the southern parts of the Western
Cape. Unreinforced Masonry (URM) is commonly used as a
construction material for 2 to 5 storey buildings in underprivileged
areas in and around Cape Town. URM is typically regarded as the
material most vulnerable to damage when subjected to earthquake
excitation. In this study, a three-storey URM building was analysed
by applying seven earthquake time-histories, which can be expected
to occur in South Africa using a finite element approach.
Experimental data was used to calibrate the in- and out-of-plane
stiffness of the URM. The results indicated that tensile cracking of
the in-plane piers was the dominant failure mode. It is concluded that
URM buildings of this type are at risk of failure especially if
sufficient ductility is not provided. The results also showed that
connection failure must be investigated further.
Abstract: Preparation of nanoparticles of cerium oxide and
adsorption of bovine serum albumin on them were studied. Particle
size distribution and influence of pH on zeta potential of prepared
CeO2 were determined. Average size of prepared cerium oxide
nanoparticles was 9 nm. The simultaneous measurements of the
bovine serum albumin adsorption and zeta potential determination of
the (adsorption) suspensions were carried out. The adsorption
isotherms were found to be of typical Langmuir type; values of the
bovine serum albumin adsorption capacities were calculated.
Increasing of pH led to decrease of zeta potential and decrease of
adsorption capacity of cerium oxide nanoparticles. The maximum
adsorption capacity was found for strongly acid suspension (am =
118 mg/g). The samples of nanoceria with positive zeta potential
adsorbed more bovine serum albumin on the other hand, the samples
with negative zeta potential showed little or no protein adsorption.
Surface charge or better say zeta potential of CeO2 nanoparticles
plays the key role in adsorption of proteins on such type of materials.
Abstract: The bean (Phaseolus vulgaris L.) is one of the best
known of the legumes, and it has a long cultivation tradition in Italy.
The territory of “Subappennino Dauno” (southern Italy) is at around
700 m a.s.l. and is predominantly grown with cereals, olive trees and
grapevines. Ecotypes of white beans to eat dry (such as cannellini
beans) are also grown, which are sought for their palatability, high
digestibility, and ease of cooking. However, these are not easy to find
on the market due to their low production in relatively small areas
and on small family farms that use seeds handed down from
generation to generation. The introduction of these ecotypes in plain
areas of the Puglia region would provide an opportunity to promote
the diffusion of this type of bean. To investigate the adaptability of
these ecotypes in plain environments (Cerignola, in southern Italy) a
comparative trial was carried out between three ‘Monti Dauni’
ecotypes (E1, E2, E3) that are native to mountain areas and the
similar commercial variety, ‘Cannellini’. The data provide useful
information about the quantitative and qualitative characteristics of
these ecotypes when grown in lowland environments. Ecotype E3
provided the greatest bean production (2.34 t ha-1) compared to
‘Cannellini’ (1.28 t ha-1) and the other ecotypes (0.55 and 0.40 t ha-1,
for E1 and E2, respectively), due to its greater plant growth and the
larger size of the seed (and thickness, in particular). Finally, ecotype
E2 provided the greatest protein content (31.2%), although not
significantly different from the commercial cultivar ‘Cannellini’
(32.1%).
Abstract: There are pending discussions over the mapping of
country export potential in order to refocus export strategy of firms
and its evidence-based promotion by the Export Credit Agencies
(ECAs) and other permitted vehicles of governments.
In this paper we develop our version of an applied model that
offers “stepwise” elimination of unattractive markets. We modify and
calibrate the model for the particular features of the Czech Republic
and specific pilot cases where we apply an individual approach to
each sector.
Abstract: The connection between past travel experience and
tourists’ revisit behavioral intentions has not been widely explored
but the existing studies suggest a close relationship between them.
Destination image can equally be construed as having effects on the
attitudes of the tourists at the end of their actual visitation and the
satisfaction of a tourist with his or her travel experiences contributes
to a revisit intention towards a particular destination. With strong
marketing efforts, UAE is not only considered to be successful in
attracting foreign investors, but is becoming the most popular tourism
destination in the Arab region. UAE is seriously developing its
tourism image and taking serious initiatives to attract new or repeat
visitations from the international tourists. This study empirically
investigates the causal relationships between tourism destination
image, tourist satisfaction and revisit intention using UAE as a
contextual study setting. A very clear picture emerged which
provides a host country with potential implications for its tourism
industry practitioners, Department of Tourism and Commerce
Marketing and the travel agencies who act as the intermediaries
between the potential tourists and the hotel operators.
Abstract: This study offers a comprehensive review of the
research papers published in the field of cooling towers and gives an
insight into the latest developments of the natural draught cooling
towers. Different modeling, analysis and design techniques are
summarized and the challenges are discussed. The 118 references
included in this paper are mostly concentrated on the review of the
published papers after 2005. The present paper represents a complete
collection of the studies done for cooling towers and would give an
updated material for the researchers and design engineers in the field
of hyperbolic cooling towers.
Abstract: The handwriting is a physical demonstration of a
complex cognitive process learnt by man since his childhood. People
with disabilities or suffering from various neurological diseases are
facing so many difficulties resulting from problems located at the
muscle stimuli (EMG) or signals from the brain (EEG) and which
arise at the stage of writing. The handwriting velocity of the same
writer or different writers varies according to different criteria: age,
attitude, mood, writing surface, etc. Therefore, it is interesting to
reconstruct an experimental basis records taking, as primary
reference, the writing speed for different writers which would allow
studying the global system during handwriting process. This paper
deals with a new approach of the handwriting system modeling based
on the velocity criterion through the concepts of artificial neural
networks, precisely the Radial Basis Functions (RBF) neural
networks. The obtained simulation results show a satisfactory
agreement between responses of the developed neural model and the
experimental data for various letters and forms then the efficiency of
the proposed approaches.
Abstract: An investigation into the effect of countersunk depth,
plate thickness, countersunk angle and plate width on the stress
concentration around countersunk hole is carried out with the help of
finite element analysis. The variation of stress concentration with
respect to these parameters is studied for three types of loading viz.
uniformly distributed load, uniformly varying load and functionally
distributed load. The results of the finite element analysis are
interpreted and some conclusions are drawn. The distribution of
stress concentration around countersunk hole in isotropic plates
simply supported at all the edges is found similar and is independent
of loading. The maximum stress concentration also occurs at a
particular point irrespective of the loading conditions.
Abstract: Present study is aimed on the cutting process of circular
cross-section rods where the fracture is used to separate one rod
into two pieces. Incorporating the phenomenological ductile fracture
model into the explicit formulation of finite element method, the
process can be analyzed without the necessity of realizing too many
real experiments which could be expensive in case of repetitive
testing in different conditions. In the present paper, the steel AISI
1045 was examined and the tensile tests of smooth and notched
cylindrical bars were conducted together with biaxial testing of the
notched tube specimens to calibrate material constants of selected
phenomenological ductile fracture models. These were implemented
into the Abaqus/Explicit through user subroutine VUMAT and used
for cutting process simulation. As the calibration process is based
on variables which cannot be obtained directly from experiments,
numerical simulations of fracture tests are inevitable part of the
calibration. Finally, experiments regarding the cutting process were
carried out and predictive capability of selected fracture models is
discussed. Concluding remarks then make the summary of gained
experience both with the calibration and application of particular
ductile fracture criteria.
Abstract: This paper deals with the problem of automatic rule
generation for fuzzy systems design. The proposed approach is based
on hybrid artificial bee colony (ABC) optimization and weighted least
squares (LS) method and aims to find the structure and parameters of
fuzzy systems simultaneously. More precisely, two ABC based fuzzy
modeling strategies are presented and compared. The first strategy
uses global optimization to learn fuzzy models, the second one
hybridizes ABC and weighted least squares estimate method. The
performances of the proposed ABC and ABC-LS fuzzy modeling
strategies are evaluated on complex modeling problems and compared
to other advanced modeling methods.