Abstract: In the process of recovering oil in weak sandstone formations, the strength of sandstones around the wellbore is weakened due to the increase of effective stress/load from the completion activities around the cavity. The weakened and de-bonded sandstone may be eroded away by the produced fluid, which is termed sand production. It is one of the major trending subjects in the petroleum industry because of its significant negative impacts, as well as some observed positive impacts. For efficient sand management therefore, there has been need for a reliable study tool to understand the mechanism of sanding. One method of studying sand production is the use of the widely recognized Discrete Element Method (DEM), Particle Flow Code (PFC3D) which represents sands as granular individual elements bonded together at contact points. However, there is limited knowledge of the particle-scale behavior of the weak sandstone, and the parameters that affect sanding. This paper aims to investigate the reliability of using PFC3D and a simple Darcy flow in understanding the sand production behavior of a weak sandstone. An isotropic tri-axial test on a weak oil sandstone sample was first simulated at a confining stress of 1MPa to calibrate and validate the parallel bond models of PFC3D using a 10m height and 10m diameter solid cylindrical model. The effect of the confining stress on the number of bonds failure was studied using this cylindrical model. With the calibrated data and sample material properties obtained from the tri-axial test, simulations without and with fluid flow were carried out to check on the effect of Darcy flow on bonds failure using the same model geometry. The fluid flow network comprised of every four particles connected with tetrahedral flow pipes with a central pore or flow domain. Parametric studies included the effects of confining stress, and fluid pressure; as well as validating flow rate – permeability relationship to verify Darcy’s fluid flow law. The effect of model size scaling on sanding was also investigated using 4m height, 2m diameter model. The parallel bond model successfully calibrated the sample’s strength of 4.4MPa, showing a sharp peak strength before strain-softening, similar to the behavior of real cemented sandstones. There seems to be an exponential increasing relationship for the bigger model, but a curvilinear shape for the smaller model. The presence of the Darcy flow induced tensile forces and increased the number of broken bonds. For the parametric studies, flow rate has a linear relationship with permeability at constant pressure head. The higher the fluid flow pressure, the higher the number of broken bonds/sanding. The DEM PFC3D is a promising tool to studying the micromechanical behavior of cemented sandstones.
Abstract: In many practical situations, bubbles are dispersed in a
liquid phase. Understanding these complex bubbly flows is therefore
a key issue for applications such as shell and tube heat exchangers,
mineral flotation and oxidation in water treatment. Although a large
body of work exists for bubbles rising in an unbounded medium,
that of bubbles rising in constricted geometries has received less
attention. The particular case of a bubble sliding underneath an
inclined surface is common to two-phase flow systems. The current
study intends to expand this knowledge by performing experiments
to quantify the streamwise flow structures associated with a single
sliding air bubble under an inclined surface in quiescent water. This
is achieved by means of two-dimensional, two-component particle
image velocimetry (PIV), performed with a continuous wave laser
and high-speed camera. PIV vorticity fields obtained in a plane
perpendicular to the sliding surface show that there is significant bulk
fluid motion away from the surface. The associated momentum of the
bubble means that this wake motion persists for a significant time
before viscous dissipation. The magnitude and direction of the flow
structures in the streamwise measurement plane are found to depend
on the point on its path through which the bubble enters the plane.
This entry point, represented by a phase angle, affects the nature and
strength of the vortical structures. This study reconstructs the vorticity
field in the wake of the bubble, converting the field at different
instances in time to slices of a large-scale wake structure. This is, in
essence, Taylor’s ”frozen turbulence” hypothesis. Applying this to the
vorticity fields provides a pseudo three-dimensional representation
from 2-D data, allowing for a more intuitive understanding of the
bubble wake. This study provides insights into the complex dynamics
of a situation common to many engineering applications, particularly
shell and tube heat exchangers in the nucleate boiling regime.
Abstract: Application of nanoscience in biomedical field has come across as a new era. This study involves the synthesis of nano drug carrier with antibiotic loading. Based on the founding that polydopamine (PDA) nanoparticles could be formed via self-polymerization of dopamine at alkaline pH, one-step synthesis of rifampicin coupled polydopamine (PDA-R) nanoparticles was achieved by adding rifampicin into the dopamine solution. The successful yield of PDA nanoparticles with or without the presence of rifampicin during the polymerization process was characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, and Raman spectroscopy. Drug loading was monitored by UV-vis spectroscopy and the loading efficiency of rifampicin was calculated to be 76%. Such highly capacious nano-reservoir was found very stable with little drug leakage at pH 3.
Abstract: In this work, we propose an algorithm developed under Python language for the modeling of ordinary scalar Bessel beams and their discrete superpositions and subsequent calculation of optical forces exerted over dielectric spherical particles. The mathematical formalism, based on the generalized Lorenz-Mie theory, is implemented in Python for its large number of free mathematical (as SciPy and NumPy), data visualization (Matplotlib and PyJamas) and multiprocessing libraries. We also propose an approach, provided by a synchronized Software as Service (SaaS) in cloud computing, to develop a user interface embedded on a mobile application, thus providing users with the necessary means to easily introduce desired unknowns and parameters and see the graphical outcomes of the simulations right at their mobile devices. Initially proposed as a free Android-based application, such an App enables data post-processing in cloud-based architectures and visualization of results, figures and numerical tables.
Abstract: Water suspensions of in-organic (metals and oxides)
and organic nano-objects (chitozan and collagen) were subjected to
the treatment of direct and alternative electrical fields. In addition to
quasi-periodical spatial patterning resonance-like performance of
spatial distributions of these suspensions has been found at low
frequencies of alternating electrical field. These resonances are
explained as the result of creation of equilibrium states of groups of
charged nano-objects with opposite signs of charges at the interparticle
distances where the forces of Coulomb attraction are
compensated by the repulsion forces induced by relatively negative
polarization of hydrated regions surrounding the nanoparticles with
respect to pure water. The low frequencies of these resonances are
explained by comparatively big distances between the particles and
their big masses with t\respect to masses of atoms constituting
molecules with high resonance frequencies. These new resonances
open a new approach to detailed modeling and understanding of
mechanisms of the influence of electrical fields on the functioning of
internal organs of living organisms at the level of cells and neurons.
Abstract: The effect of upstream surface roughness over a
smooth forward facing step in an open channel was investigated
using a particle image velocimetry technique. Three different
upstream surface topographies consisting of hydraulically smooth
wall, sandpaper 36 grit and sand grains were examined. Besides the
wall roughness conditions, all other upstream flow characteristics
were kept constant. It was also observed that upstream roughness
decreased the approach velocity by 2% and 10% but increased the
turbulence intensity by 14% and 35% at the wall-normal distance
corresponding to the top plane of the step compared to smooth
upstream. The results showed that roughness decreased the
reattachment lengths by 14% and 30% compared to smooth upstream.
Although the magnitudes of maximum positive and negative
Reynolds shear stress in separated and reattached region were 0.02Ue
for all the cases, the physical size of both the maximum and
minimum contour levels were decreased by increasing upstream
roughness.
Abstract: By using an adequate thermal barrier coating in
buildings the energy saving will be happened. In this study, a range
of wall paints with different absorption coefficient in different
climates has been investigated. In order to study these effects, heating
and cooling loads of a common building with different ordinary
paints and paint with mineral coating have been calculated. The
effect of building paint in different climatic condition was studied
and comparison was done between ordinary paints and paint with
mineral insulators in temperate climate to obtain optimized energy
consumption. The results have been shown that coatings with
inorganic micro particles as insulation reduce the energy
consumption of buildings around 14%.
Abstract: Flue gas desulfurization gypsum (FGD) is a waste
material arouse from coal power plants. Hydroxyapatite (HAP) is a
biomaterial with porous structure. In this study, FGD gypsum which
retrieved from coal power plant in Turkey was characterized and
HAP particles which can be used as an adsorbent in wastewater
treatment application were synthesized from the FGD gypsum. The
raw materials are characterized by using X Ray Diffraction (XRD)
and Fourier transform infrared spectroscopy (FT-IR) techniques and
produced HAP are characterized by using XRD. As a result, HAP
particles were synthesized at the molar ratio of 5:10, 5:15, 5:20, 5:24,
at room temperature, in alkaline medium (pH=11) and in 1 hour-reaction
time. Among these conditions, 5:20 had the best result.
Abstract: The tribological test with Pin-On-Disc configuration
measures friction and wear properties in dry or lubricated sliding
surfaces of a variety of materials and coatings. Polymeric matrix
composites loaded with mineral filler were used, 1%, 3%, 10%, 30%,
and 50% mass percentage of filler, to reduce the material cost by
using mineral tailings. Using a pin-on-disc tribometer to quantify
coefficient of friction and wear resistance of the specimens. The
parameters known to performing the test were 300 rpm rotation,
normal load of 16N and duration of 33.5 minutes. The composite
with 10% mineral filler performed better, considering that the wear
resistance was good when compared to the other compositions and an
average low coefficient of friction, in the order of μ ≤ 0.15.
Abstract: Elastic scattering of α-particles from 9Be and 11B
nuclei at different alpha energies have been analyzed. Optical model
parameters (OMPs) of α-particles elastic scattering by these nuclei at
different energies have been obtained. In the present calculations, the
real part of the optical potential are derived by folding of nucleonnucleon
(NN) interaction into nuclear matter density distribution of
the projectile and target nuclei using computer code FRESCO. A
density-dependent version of the M3Y interaction (CDM3Y6), which
is based on the G-matrix elements of the Paris NN potential, has been
used. Volumetric integrals of the real and imaginary potential depth
(JR, JW) have been calculated and found to be energy dependent.
Good agreement between the experimental data and the theoretical
predictions in the whole angular range. In double folding (DF)
calculations, the obtained normalization coefficient Nr is in the range
0.70–1.32.
Abstract: The exploitation of flow pulsation in micro- and
mini-channels is a potentially useful technique for enhancing cooling
of high-end photonics and electronics systems. It is thought that
pulsation alters the thickness of the hydrodynamic and thermal
boundary layers, and hence affects the overall thermal resistance
of the heat sink. Although the fluid mechanics and heat transfer
are inextricably linked, it can be useful to decouple the parameters
to better understand the mechanisms underlying any heat transfer
enhancement. Using two-dimensional, two-component particle image
velocimetry, the current work intends to characterize the heat transfer
mechanisms in pulsating flow with a mean Reynolds number of
48 by experimentally quantifying the hydrodynamics of a generic
liquid-cooled channel geometry. Flows circulated through the test
section by a gear pump are modulated using a controller to achieve
sinusoidal flow pulsations with Womersley numbers of 7.45 and
2.36 and an amplitude ratio of 0.75. It is found that the transient
characteristics of the measured velocity profiles are dependent on the
speed of oscillation, in accordance with the analytical solution for
flow in a rectangular channel. A large velocity overshoot is observed
close to the wall at high frequencies, resulting from the interaction
of near-wall viscous stresses and inertial effects of the main fluid
body. The steep velocity gradients at the wall are indicative of
augmented heat transfer, although the local flow reversal may reduce
the upstream temperature difference in heat transfer applications.
While unsteady effects remain evident at the lower frequency, the
annular effect subsides and retreats from the wall. The shear rate at
the wall is increased during the accelerating half-cycle and decreased
during deceleration compared to steady flow, suggesting that the flow
may experience both enhanced and diminished heat transfer during
a single period. Hence, the thickness of the hydrodynamic boundary
layer is reduced for positively moving flow during one half of the
pulsation cycle at the investigated frequencies. It is expected that the
size of the thermal boundary layer is similarly reduced during the
cycle, leading to intervals of heat transfer enhancement.
Abstract: Surface characteristics of Bacillus megaterium strain
were investigated; zeta potential, FTIR and contact angle were
measured. Surface energy components including Lifshitz-van der
Waals, Hamaker constant, and acid/base components (Lewis
acid/Lewis base) were calculated from the contact angle data. The
results showed that the microbial cells were negatively charged over
all pH regions with high values at alkaline region. A hydrophilic
nature for the strain was confirmed by contact angle and free energy
of adhesion between microbial cells. Adsorption affinity of the strain
toward dolomite was studied at different pH values. The results
showed that the cells had a high affinity to dolomite at acid pH
comparing to neutral and alkaline pH. Extended DLVO theory was
applied to calculate interaction energy between B. megaterium cells
and dolomite particles. The adsorption results were in agreement with
the results of Extended DLVO approach. Surface changes occurred
on dolomite surface after the bio-treatment were monitored; contact
angle decreased from 69° to 38° and the mineral’s floatability
decreased from 95% to 25% after the treatment.
Abstract: This paper investigates the application of metallic
coatings on high fiber volume fraction carbon/epoxy polymer matrix
composites. For the grip of the metallic layer, a method of modifying
the surface of the composite by introducing a mixture of copper and
steel powder (filler powders) which can reduce the impact of thermal
spray particles. The powder was introduced to the surface at the time
of the forming. Arc spray was used to project the zinc coating layer.
The substrate was grit blasted to avoid poor adherence. The porosity, microstructure, and morphology of layers are
characterized by optical microscopy, SEM and image analysis. The
samples were studied also in terms of hardness and erosion resistance.
This investigation did not reveal any visible evidence damage to the
substrates. The hardness of zinc layer was about 25.94 MPa and the
porosity was around (∼6.70%). The erosion test showed that the zinc
coating improves the resistance to erosion. Based on the results
obtained, we can conclude that thermal spraying allows the production
of protective coating on PMC. Zinc coating has been identified as a
compatible material with the substrate. The filler powders layer
protects the substrate from the impact of hot particles and allows
avoiding the rupture of brittle carbon fibers.
Abstract: Magnetic Resonance Imaging Contrast Agents
(MRI-CM) are significant in the clinical and biological imaging as
they have the ability to alter the normal tissue contrast, thereby
affecting the signal intensity to enhance the visibility and detectability
of images. Superparamagnetic Iron Oxide (SPIO) nanoparticles,
coated with dextran or carboxydextran are currently available for
clinical MR imaging of the liver. Most SPIO contrast agents are
T2 shortening agents and Resovist (Ferucarbotran) is one of a
clinically tested, organ-specific, SPIO agent which has a low
molecular carboxydextran coating. The enhancement effect of
Resovist depends on its relaxivity which in turn depends on factors
like magnetic field strength, concentrations, nanoparticle properties,
pH and temperature. Therefore, this study was conducted to
investigate the impact of field strength and different contrast
concentrations on enhancement effects of Resovist. The study
explored the MRI signal intensity of Resovist in the physiological
range of plasma from T2-weighted spin echo sequence at three
magnetic field strengths: 0.47 T (r1=15, r2=101), 1.5 T (r1=7.4,
r2=95), and 3 T (r1=3.3, r2=160) and the range of contrast
concentrations by a mathematical simulation. Relaxivities of r1 and r2
(L mmol-1 Sec-1) were obtained from a previous study and the selected
concentrations were 0.05, 0.06, 0.07, 0.08, 0.09, 0.1, 0.2, 0.3, 0.4, 0.5,
0.6, 0.7, 0.8, 0.9, 1.0, 2.0, and 3.0 mmol/L. T2-weighted images were
simulated using TR/TE ratio as 2000 ms /100 ms. According to the
reference literature, with increasing magnetic field strengths, the
r1 relaxivity tends to decrease while the r2 did not show any
systematic relationship with the selected field strengths. In parallel,
this study results revealed that the signal intensity of Resovist at lower
concentrations tends to increase than the higher concentrations. The
highest reported signal intensity was observed in the low field strength
of 0.47 T. The maximum signal intensities for 0.47 T, 1.5 T and 3 T
were found at the concentration levels of 0.05, 0.06 and 0.05 mmol/L,
respectively. Furthermore, it was revealed that, the concentrations
higher than the above, the signal intensity was decreased
exponentially. An inverse relationship can be found between the field
strength and T2 relaxation time, whereas, the field strength was
increased, T2 relaxation time was decreased accordingly. However,
resulted T2 relaxation time was not significantly different between
0.47 T and 1.5 T in this study. Moreover, a linear correlation of
transverse relaxation rates (1/T2, s–1) with the concentrations of
Resovist can be observed. According to these results, it can conclude
that the concentration of SPIO nanoparticle contrast agents and the
field strengths of MRI are two important parameters which can affect the signal intensity of T2-weighted SE sequence. Therefore, when MR
imaging those two parameters should be considered prudently.
Abstract: For several hundred years, the design of railway tracks
has practically remained unchanged. Traditionally, rail tracks are
placed on a ballast layer due to several reasons, including economy,
rapid drainage, and high load bearing capacity. The primary function
of ballast is to distributing dynamic track loads to sub-ballast and
subgrade layers, while also providing lateral resistance and allowing
for rapid drainage. Upon repeated trainloads, the ballast becomes
fouled due to ballast degradation and the intrusion of fines which
adversely affects the strength and deformation behaviour of ballast.
This paper presents the use of three-dimensional discrete element
method (DEM) in studying the shear behaviour of the fouled ballast
subjected to direct shear loading. Irregularly shaped particles of
ballast were modelled by grouping many spherical balls together in
appropriate sizes to simulate representative ballast aggregates. Fouled
ballast was modelled by injecting a specified number of miniature
spherical particles into the void spaces. The DEM simulation
highlights that the peak shear stress of the ballast assembly decreases
and the dilation of fouled ballast increases with an increase level of
fouling. Additionally, the distributions of contact force chain and
particle displacement vectors were captured during shearing progress,
explaining the formation of shear band and the evolutions of
volumetric change of fouled ballast.
Abstract: This paper outlines the development of an
experimental technique in quantifying supersonic jet flows, in an
attempt to avoid seeding particle problems frequently associated with
particle-image velocimetry (PIV) techniques at high Mach numbers.
Based on optical flow algorithms, the idea behind the technique
involves using high speed cameras to capture Schlieren images of the
supersonic jet shear layers, before they are subjected to an adapted
optical flow algorithm based on the Horn-Schnuck method to
determine the associated flow fields. The proposed method is capable
of offering full-field unsteady flow information with potentially
higher accuracy and resolution than existing point-measurements or
PIV techniques. Preliminary study via numerical simulations of a
circular de Laval jet nozzle successfully reveals flow and shock
structures typically associated with supersonic jet flows, which serve
as useful data for subsequent validation of the optical flow based
experimental results. For experimental technique, a Z-type Schlieren
setup is proposed with supersonic jet operated in cold mode,
stagnation pressure of 4 bar and exit Mach of 1.5. High-speed singleframe
or double-frame cameras are used to capture successive
Schlieren images. As implementation of optical flow technique to
supersonic flows remains rare, the current focus revolves around
methodology validation through synthetic images. The results of
validation test offers valuable insight into how the optical flow
algorithm can be further improved to improve robustness and
accuracy. Despite these challenges however, this supersonic flow
measurement technique may potentially offer a simpler way to
identify and quantify the fine spatial structures within the shock shear
layer.
Abstract: We have aimed to produce a self-cleaning transparent
polymer coating with polyurethane (PU) matrix as the latter is highly
solvent, chemical and weather resistant having good mechanical
properties. Nano-silica modified by 1H, 1H, 2H, 2Hperflurooctyltriethoxysilane
was incorporated into the PU matrix for
attaining self-cleaning ability through hydrophobicity. The
modification was confirmed by particle size analysis and scanning
electron microscopy (SEM). Thermo-gravimetric (TGA) studies were
carried to ascertain the grafting of silane onto the silica. Several
coating formulations were prepared by varying the silica loading
content and compared to a commercial equivalent. The effect of
dispersion and the morphology of the coated films were assessed by
SEM analysis. All coating standardized tests like solvent resistance,
adhesion, flexibility, acid, alkali, gloss etc. have been performed as
per ASTM standards. Water contact angle studies were conducted to
analyze the hydrophobic character of the coating. In addition, the
coatings were also subjected to salt spray and accelerated weather
testing to analyze the durability of the coating.
Abstract: In the present study, a numerical approach to describe the pyrolysis of a single solid particle of wood is used to study the influence of various conditions such as particle size, heat transfer coefficient, reactor temperature and heating rate. The influence of these parameters in the change of the duration of the pyrolysis cycle was studied. Mathematical modeling was employed to simulate the heat, mass transfer, and kinetic processes inside the reactor. The evolutions of the mass loss as well as the evolution of temperature inside the thick piece are investigated numerically. The elaborated model was also employed to study the effect of the reactor temperature and the rate of heating on the change of the temperature and the local loss of the mass inside the piece of wood. The obtained results are in good agreement with the experimental data available in the literature.
Abstract: The simulation in wind tunnel is used thoroughly to model real situations of drainages of air. Besides the automotive industry, a great number of applications can be numbered: dispersion of pollutant, studies of pedestrians’ comfort, and dispersion of particles. This work had the objective of visualizing the characteristics aerodynamics of two automobiles in different ways. To accomplish that drainage of air a fan that generated a speed exists (measured with anemometer of hot thread) of 4,1m/s and 4,95m/s. To visualize the path of the air through the cars, in the wind tunnel, smoke was used, obtained with it burns of vegetable oil. For “to do smoke” vegetable oil was used, that was burned for a tension of 20V generated by a thread of 2,5mm. The cars were placed inside of the wind tunnel with the drainage of “air-smoke” and photographed, registering like this the path lines around them, in the 3 different speeds.
Abstract: Nanofibers are defined as fibers with diameters less
than 100 nanometers. In this study, behaviours of activated carbon
nanofiber (ACNF), carbon nanofiber (CNF), polyacrylonitrile/ carbon
nanotube (PAN/CNT), polyvinyl alcohol/nanosilver (PVA/Ag) in
proton exchange membrane (PEM) fuel cells are investigated
experimentally. This material was used as gas diffusion layer (GDL)
in PEM fuel cells. In this study, the electrical conductivities of
nanofiber and nanofiber/nanoparticles have been studied to
understand their effects on PEM fuel cell performance. According to
the experimental results, the maximum electrical conductivity
performance of the fuel cell with nanofiber was found to be at
PVA/Ag (at UConn condition). The electrical conductivities of CNF,
ACNF, PAN/CNT are lower for PEM. The resistance of cell with
PVA/Ag is lower than the resistance of cell with PAN/CNT, ACNF,
CNF.