Abstract: Slag sample from copper smelting operation in a
water jacket furnace from DRC plant was used. The study intends to
determine the effect of cooling in the extraction of base metals. The
cooling methods investigated were water quenching, air cooling and
furnace cooling. The latter cooling ways were compared to the
original as received slag. It was observed that, the cooling rate of the
slag affected the leaching of base metals as it changed the phase
distribution in the slag and the base metals distribution within the
phases. It was also found that fast cooling of slag prevented
crystallization and produced an amorphous phase that encloses the
base metals. The amorphous slags from the slag dumps were more
leachable in acidic medium (HNO3) which leached 46%Cu, 95% Co,
85% Zn, 92% Pb and 79% Fe with no selectivity at pH0, than in
basic medium (NH4OH). The leachability was vice versa for the
modified slags by quenching in water which leached 89%Cu with a
high selectivity as metal extractions are less than 1% for Co, Zn, Pb
and Fe at ambient temperature and pH12. For the crystallized slags,
leaching of base metals increased with the increase of temperature
from ambient temperature to 60°C and decreased at the higher
temperature of 80°C due to the evaporation of the ammonia solution
used for basic leaching, the total amounts of base metals that were
leached in slow cooled slags were very low compared to the
quenched slag samples.
Abstract: In modern day disaster recovery mission has become
one of the top priorities in any natural disaster management regime.
Smart autonomous robots may play a significant role in such
missions, including search for life under earth quake hit rubbles,
Tsunami hit islands, de-mining in war affected areas and many other
such situations. In this paper current state of many walking robots are
compared and advantages of hexapod systems against wheeled robots
are described. In our research we have selected a hexapod spider
robot; we are developing focusing mainly on efficient navigation
method in different terrain using apposite gait of locomotion, which
will make it faster and at the same time energy efficient to navigate
and negotiate difficult terrain. This paper describes the method of
terrain negotiation navigation in a hazardous field.
Abstract: One of the major parts of a jet engine is air intake,
which provides proper and required amount of air for the engine to
operate. There are several aerodynamic parameters which should be
considered in design, such as distortion, pressure recovery, etc. In
this research, the effects of lip ice accretion on pitot intake
performance are investigated. For ice accretion phenomenon, two
supervised multilayer neural networks (ANN) are designed, one for
ice shape prediction and another one for ice roughness estimation
based on experimental data. The Fourier coefficients of transformed
ice shape and parameters include velocity, liquid water content
(LWC), median volumetric diameter (MVD), spray time and
temperature are used in neural network training. Then, the subsonic
intake flow field is simulated numerically using 2D Navier-Stokes
equations and Finite Volume approach with Hybrid mesh includes
structured and unstructured meshes. The results are obtained in
different angles of attack and the variations of intake aerodynamic
parameters due to icing phenomenon are discussed. The results show
noticeable effects of ice accretion phenomenon on intake behavior.
Abstract: Because of the great advance in multimedia
technology, digital multimedia is vulnerable to malicious
manipulations. In this paper, a public key self-recovery block-based
video authentication technique is proposed which can not only
precisely localize the alteration detection but also recover the missing
data with high reliability. In the proposed block-based technique,
multiple description coding MDC is used to generate two codes (two
descriptions) for each block. Although one block code (one
description) is enough to rebuild the altered block, the altered block
is rebuilt with better quality by the two block descriptions. So using
MDC increases the ratability of recovering data. A block signature is
computed using a cryptographic hash function and a doubly linked
chain is utilized to embed the block signature copies and the block
descriptions into the LSBs of distant blocks and the block itself. The
doubly linked chain scheme gives the proposed technique the
capability to thwart vector quantization attacks. In our proposed
technique , anyone can check the authenticity of a given video using
the public key. The experimental results show that the proposed
technique is reliable for detecting, localizing and recovering the
alterations.
Abstract: Preparation of size controlled nano-particles of silver catalyst on carbon substrate from e-waste has been investigated. Chemical route was developed by extraction of the metals available in nitric acid followed by treatment with hydrofluoric acid. Silver metal particles deposited with an average size 4-10 nm. A stabilizer concentration of 10- 40 g/l was used. The average size of the prepared silver decreased with increase of the anode current density. Size uniformity of the silver nano-particles was improved distinctly at higher current density no more than 20mA... Grain size increased with EK time whereby aggregation of particles was observed after 6 h of reaction.. The chemical method involves adsorption of silver nitrate on the carbon substrate. Adsorbed silver ions were directly reduced to metal particles using hydrazine hydrate. Another alternative method is by treatment with ammonia followed by heating the carbon loaded-silver hydroxide at 980°C. The product was characterized with the help of XRD, XRF, ICP, SEM and TEM techniques.
Abstract: Aerospace vehicles are subjected to non-uniform
thermal loading that may cause thermal buckling. A study was
conducted on the thermal post-buckling of shape memory alloy
composite plates subjected to the non-uniform tent-like temperature
field. The shape memory alloy wires were embedded within the
laminated composite plates to add recovery stress to the plates. The
non-linear finite element model that considered the recovery stress of
the shape memory alloy and temperature dependent properties of the
shape memory alloy and composite matrix along with its source
codes were developed. It was found that the post-buckling paths of
the shape memory alloy composite plates subjected to various tentlike
temperature fields were stable within the studied temperature
range. The addition of shape memory alloy wires to the composite
plates was found to significantly improve the post-buckling behavior
of laminated composite plates under non-uniform temperature
distribution.
Abstract: This paper highlights some interesting facts on South African-s waste situation and management strategies, in particular the Integrated Waste Management. South Africa supports a waste hierarchy by promoting cleaner production, waste minimisation, reuse, recycling and waste treatment with disposal and remediation as the last preferred options in waste management. The drivers for waste management techniques are identified as increased demand for waste service provision; increased demand for waste minimisation; recycling and recovery; land use, physical and environmental limitations; and socio-economic and demographic factors. The South African government recognizes the importance of scientific research as outlined on the white paper on Integrated Pollution and Waste Management (IP and WM) (DEAT, 2000).
Abstract: Due to adverse pressure gradient along the diverging
walls of wide-angled diffusers, the attached flow separates from
one wall and remains attached permanently to the other wall in a
process called stalling. Stalled diffusers render the whole fluid flow
system, in which they are part of, very inefficient. There is then an
engineering need to try to understand the whole process of diffuser
stall if any meaningful attempts to improve on diffuser efficiency
are to be made. In this regard, this paper provides a data bank
contribution for the mean flow-field in wide-angled diffusers where
the complete velocity and static pressure fields, and pressure recovery
data for diffusers in the fully stalled flow regime are experimentally
measured. The measurements were carried out at Reynolds numbers
between 1.07×105 and 2.14×105 based on inlet hydraulic diameter
and centreline velocity for diffusers whose divergence angles were
between 30Ôùª and 50Ôùª. Variation of Reynolds number did not significantly
affect the velocity and static pressure profiles. The wall static
pressure recovery was found to be more sensitive to changes in the
Reynolds number. By increasing the velocity from 10 m/s to 20 m/s,
the wall static pressure recovery increased by 8.31%. However, as the
divergence angle was increased, a similar increase in the Reynolds
number resulted in a higher percentage increase in pressure recovery.
Experimental results showed that regardless of the wall to which
the flow was attached, both the velocity and pressure fields were
replicated with discrepancies below 2%.
Abstract: Use of microemulsion in enhanced oil recovery has become more attractive in recent years because of its high level of extraction efficiency. Experimental investigations have been made on characterization of microemulsions of oil-brinesurfactant/ cosurfactant system for its use in enhanced oil recovery (EOR). Sodium dodecyl sulfate, propan-1-ol and heptane were selected as surfactant, cosurfactant and oil respectively for preparation of microemulsion. The effects of salinity on the relative phase volumes and solubilization parameters have also been studied. As salinity changes from low to high value, phase transition takes place from Winsor I to Winsor II via Winsor III. Suitable microemulsion composition has been selected based on its stability and ability to reduce interfacial tension. A series of flooding experiments have been performed using the selected microemulsion. The flooding experiments were performed in a core flooding apparatus using uniform sand pack. The core holder was tightly packed with uniform sands (60-100 mesh) and saturated with brines of different salinities. It was flooded with the brine at 25 psig and the absolute permeability was calculated from the flow rate of the through sand pack. The sand pack was then flooded with the crude oil at 800 psig to irreducible water saturation. The initial water saturation was determined on the basis of mass balance. Waterflooding was conducted by placing the coreholder horizontally at a constant injection pressure at 200 pisg. After water flooding, when water-cut reached above 95%, around 0.5 pore volume (PV) of the above microemulsion slug was injected followed by chasing water. The experiments were repeated using different composition of microemulsion slug. The additional recoveries were calculated by material balance. Encouraging results with additional recovery more than 20% of original oil in place above the conventional water flooding have been observed.
Abstract: A process flowsheet was developed in ChemCad 6.4
to study the effect of feed moisture contents on the pre-esterification
of waste oils. Waste oils were modelled as a mixture of triolein
(90%), oleic acid (5%) and water (5%). The process mainly consisted
of feed drying, pre-esterification reaction and methanol recovery. The
results showed that the process energy requirements would be
minimized when higher degrees of feed drying and higher preesterification
reaction temperatures are used.
Abstract: The purpose of this research was to analyze and compare the instability of a contact surface between Copper and Nickel an alloy cathode in vacuum, the different ratio of Copper and Copper were conducted at 1%, 2% and 4% by using the cathode spot model. The transient recovery voltage is predicted. The cathode spot region is recognized as the collisionless space charge sheath connected with singly ionized collisional plasma. It was found that the transient voltage is decreased with increasing the percentage of an amount of Nickel in cathode materials.
Abstract: The aim of the present study was to develop and
validate an inexpensive and simple high performance liquid
chromatographic (HPLC) method for the determination of colistin
sulfate. Separation of colistin sulfate was achieved on a ZORBAX
Eclipse XDB-C18 column using UV detection at λ=215 nm. The
mobile phase was 30 mM sulfate buffer (pH 2.5):acetonitrile(76:24).
An excellent linearity (r2=0.998) was found in the concentration
range of 25 - 400 μg/mL. Intra- day and inter-day precisions of
method (%RSD, n=3) were less than 7.9%.The developed and
validated method was applied to determination of the content of
colistin sulfate in medicated premix and animal feed sample.The
recovery of colistin from animal feed was satisfactorily ranged from
90.92 to 93.77%. The results demonstrated that the HPLC method
developed in this work is appropriate for direct determination of
colistin sulfate in commercial medicated premixes and animal feed.
Abstract: One of the important applications of gas turbines is
their utilization for heat recovery steam generator in combine-cycle technology. Exhaust flow and energy are two key parameters for
determining heat recovery steam generator performance which are mainly determined by the main gas turbine components performance
data. For this reason a method was developed for determining the
exhaust energy in the new edition of ASME PTC22. The result of this investigation shows that the method of standard has considerable
error. Therefore in this paper a new method is presented for modifying of the performance calculation. The modified method is
based on exhaust gas constituent analysis and combustion calculations. The case study presented here by two kind of General
Electric gas turbine design data for validation of methodologies. The
result shows that the modified method is more precise than the ASME PTC22 method. The exhaust flow calculation deviation from
design data is 1.5-2 % by ASME PTC22 method so that the deviation regarding with modified method is 0.3-0.5%. Based on precision of
analyzer instruments, the method can be suitable alternative for gas
turbine standard performance test. In advance two methods are
proposed based on known and unknown fuel in modified method procedure. The result of this paper shows that the difference between
the two methods is below than %0.02. In according to reasonable esult of the second procedure (unknown fuel composition), the
method can be applied to performance evaluation of gas turbine, so that the measuring cost and data gathering should be reduced.
Abstract: CO2 miscible displacement is not feasible in many oil fields due to high reservoir temperature as higher pressure is required to achieve miscibility. The miscibility pressure is far higher than the formation fracture pressure making it impossible to have CO2 miscible displacement. However, by using oleophilic chemicals, minimum miscibility pressure (MMP) could be lowered. The main objective of this research is to find the best oleophilic chemical in MMP reduction using slim-tube test and Vanishing Interfacial Tension (VIT) The chemicals are selected based on the characteristics that it must be oil soluble, low water solubility, have 4 – 8 carbons, semi polar, economical, and safe for human operation. The families of chemicals chosen are carboxylic acid, alcohol, and ketone. The whole experiment would be conducted at 100°C and the best chemical is said to be effective when it is able to lower CO2-crude oil MMP the most. Findings of this research would have great impact to the oil and gas industry in reduction of operation cost for CO2EOR which is applicable to both onshore and offshore operation.
Abstract: The aim of this studywas toinvestigate the effect
ofrunning classification (sprint, middle, and long distance)and two
distances on blood lactate (BLa), heart rate (HR), and rating of
perceived exertion (RPE) Borg scale ratings in collegiate athletes. On
different days, runners (n = 15) ran 400m and 1600m at a five min
mile pace, followed by a two min 6mph jog, and a two min 3mph
walk as part of the cool down. BLa, HR, and RPE were taken at
baseline, post-run, plus 2 and 4 min recovery times. The middle and
long distance runners exhibited lower BLa concentrations than sprint
runners after two min of recovery post 400 m runs, immediately after,
and two and four min recovery periods post 1600 m runs. When
compared to sprint runners, distance runners may have exhibited the
ability to clear BLa more quickly, particularly after running 1600 m.
Abstract: This paper proposes a Wavelength Division
Multiplexing (WDM) technology based Storage Area Network
(SAN) for all type of Disaster recovery operation. It considers
recovery when all paths failure in the network as well as the main
SAN site failure also the all backup sites failure by the effect of
natural disasters such as earthquakes, fires and floods, power outage,
and terrorist attacks, as initially SAN were designed to work within
distance limited environments[2]. Paper also presents a NEW PATH
algorithm when path failure occurs. The simulation result and
analysis is presented for the proposed architecture with performance
consideration.
Abstract: This paper explores the features of political economy in the dynamics of representative politics in India. Politics is seen as enhancing economic benefits through acquiring and maintenance of power in the realm of democratic set up. The system of representation is riddled with competitive populism. Emerging leaders and parties are forced to accommodate their ideologies in coping with competitive politics. Electoral politics and voting behaviour reflect series of influences mooted by the politicians. Voters are accustomed to expect benefits outs of state exchequer. The electoral competitors show a changing phase of investment and return policy. Every elector has to spend and realize his costs in his tenure. In the case of defeated electors, even the cost recovery is not possible directly; there are indirect means to recover their costs. The series of case studies show the method of party funding, campaign financing, electoral expenditure, and cost recovery. Regulations could not restrict the level of spending. Several cases of disproportionate accumulation of wealth by the politicians reveal that money played a major part in electoral process. The political economy of representative politics hitherto ignores how a politician spends and recovers his cost and multiples his wealth. To be sure, the acquiring and maintenance of power is to enhance the wealth of the electors.
Abstract: Nowadays due to globalization of economy and
competition environment, innovation and technology plays key role
at creation of wealth and economic growth of countries. In fact
prompt growth of practical and technologic knowledge may results in
social benefits for countries when changes into effective innovation.
Considering the importance of innovation for the development of
countries, this study addresses the radical technological innovation
introduced by nanopapers at different stages of producing paper
including stock preparation, using authorized additives, fillers and
pigments, using retention, calender, stages of producing conductive
paper, porous nanopaper and Layer by layer self-assembly. Research
results show that in coming years the jungle related products will lose
considerable portion of their market share, unless embracing radical
innovation. Although incremental innovations can make this industry
still competitive in mid-term, but to have economic growth and
competitive advantage in long term, radical innovations are
necessary. Radical innovations can lead to new products and
materials which their applications in packaging industry can produce
value added. However application of nanotechnology in this industry
can be costly, it can be done in cooperation with other industries to
make the maximum use of nanotechnology possible. Therefore this
technology can be used in all the production process resulting in the
mass production of simple and flexible papers with low cost and
special properties such as facility at shape, form, easy transportation,
light weight, recovery and recycle marketing abilities, and sealing.
Improving the resistance of the packaging materials without reducing
the performance of packaging materials enhances the quality and the
value added of packaging. Improving the cellulose at nano scale can
have considerable electron optical and magnetic effects leading to
improvement in packaging and value added. Comparing to the
specifications of thermoplastic products and ordinary papers,
nanopapers show much better performance in terms of effective
mechanical indexes such as the modulus of elasticity, tensile strength,
and strain-stress. In densities lower than 640 kgm -3, due to the
network structure of nanofibers and the balanced and randomized
distribution of NFC in flat space, these specifications will even
improve more. For nanopapers, strains are 1,4Gpa, 84Mpa and 17%,
13,3 Gpa, 214Mpa and 10% respectively. In layer by layer self
assembly method (LbL) the tensile strength of nanopaper with Tio3
particles and Sio2 and halloysite clay nanotube are 30,4 ±7.6Nm/g
and 13,6 ±0.8Nm/g and 14±0.3,3Nm/g respectively that fall within
acceptable range of similar samples with virgin fiber. The usage of
improved brightness and porosity index in nanopapers can create
more competitive advantages at packaging industry.
Abstract: Trace element speciation of an integrated soil
amendment matrix was studied with a modified BCR sequential
extraction procedure. The analysis included pseudo-total
concentration determinations according to USEPA 3051A and
relevant physicochemical properties by standardized methods. Based
on the results, the soil amendment matrix possessed neutralization
capacity comparable to commercial fertilizers. Additionally, the
pseudo-total concentrations of all trace elements included in the
Finnish regulation for agricultural fertilizers were lower than the
respective statutory limit values. According to chemical speciation,
the lability of trace elements increased in the following order: Hg <
Cr < Co < Cu < As < Zn < Ni < Pb < Cd < V < Mo < Ba. The
validity of the BCR approach as a tool for chemical speciation was
confirmed by the additional acid digestion phase. Recovery of trace
elements during the procedure assured the validity of the approach
and indicated good quality of the analytical work.
Abstract: This paper made an attempt to investigate the problem associated with enhancement of emulsions of light crude oil-water recovery in an oil field of Algerian Sahara. Measurements were taken through experiments using RheoStress (RS600). Factors such as shear rate, temperature and light oil concentration on the viscosity behavior were considered. Experimental measurements were performed in terms of shear stress–shear rate, yield stress and flow index on mixture of light crude oil–water. The rheological behavior of emulsion showed Non-Newtonian shear thinning behavior (Herschel-Bulkley). The experiments done in the laboratory showed the stability of some water in light crude oil emulsions form during consolidate oil recovery process. To break the emulsion using additives may involve higher cost and could be very expensive. Therefore, further research should be directed to find solution of these problems that have been encountered.