Abstract: Water, soil and sediment contaminated with
metolachlor poses a threat to the environment and human health.
We determined the effectiveness of nano-zerovalent iron (NZVI) to
dechlorinate metolachlor [2-chloro-n-(2-ethyl-6-methyl-phenyl)-n-
(1-methoxypropan-2-yl)acetamide] in pH solution and the presence
of aluminium salt. The optimum dosage of degradation of 100 mlL-1
metolachlor was 1% (w/v) NZVI. The degradation kinetic rate (kobs)
was 0.218×10-3 min-1 and specific first-order rates (kSA) was
8.72×10-7 L m-2min-1. By treating aqueous solutions of metolachlor
with NZVI, metolachlor destruction rate were increased as the pH
decrease from 10 to 4. Lowering solution pH removes Fe (III)
passivating layers from the NZVI and makes it free for reductive
transformations. Destruction kinetic rates were 20.8×10-3 min-1 for
pH4, 18.9×10-3 min-1 for pH7, 13.8×10-3 min-1 for pH10. In addition,
destruction kinetic of metolachlor by NZVI was enhanced when
aluminium sulfate was added. The destruction kinetic rate were
20.4×10-3 min-1 for 0.05% Al(SO4)3 and 60×10-3 min-1 for 0.1%
Al(SO4)3.