Abstract: In this research, effect of combustion reaction
mechanism on direct initiation of detonation has been studied
numerically. For this purpose, reaction mechanism has been
simulated by using a three-step chemical kinetics model. The reaction
scheme consists sequentially of a chain-initiation and chainbranching
step, followed by a temperature -independent chaintermination.
In a previous research, the effect of chain-branching on
the direct initiation of detonation is studied. In this research effect of
chain-initiation on direct initiation of detonation is investigated. For
the investigation, first a characteristic time (τ) for each step of
mechanism, which includes effect of different kinetics parameters, is
defined. Then the effect of characteristic time of chain-initiation (τI)
on critical initiation energy is studied. It is seen that increasing τI,
causes critical initiation energy to be increased. Drawing detonation's
shock pressure diagrams for different cases, shows that in small value
of τI , kinetics has more important effect on the behavior of the wave.