Abstract: Copper (I) oxide microparticles with the morphology
of cubic and hollow sphere were synthesized with the assistance of
surfactant as the shape controller. Both particles were then subjected
to study the catalytic activity and observed the results of shape effects
of catalysts on rate of catalytic reaction. The decolorizing reaction of
crystal violet and sodium hydroxide was chosen and measured the
decreasing of reactant with respect to times using spectrophotometer.
The result revealed that morphology of crystal had no effect on the
catalytic activity for crystal violet reaction but contributed to total
surface area predominantly.
Abstract: Mammography is widely used technique for breast cancer
screening. There are various other techniques for breast cancer screening
but mammography is the most reliable and effective technique. The
images obtained through mammography are of low contrast which
causes problem for the radiologists to interpret. Hence, a high quality
image is mandatory for the processing of the image for extracting any
kind of information from it. Many contrast enhancement algorithms have
been developed over the years. In the present work, an efficient
morphology based technique is proposed for contrast enhancement of
masses in mammographic images. The proposed method is based on
Multiscale Morphology and it takes into consideration the scale of the
structuring element. The proposed method is compared with other stateof-
the-art techniques. The experimental results show that the proposed
method is better both qualitatively and quantitatively than the other
standard contrast enhancement techniques.
Abstract: Any variation in environmental characteristics of
geomorphosites would lead to destabilisation of their geotouristic
values all around the planet. The Urmia lake, with an area of
approximately 5,500 km2 and a catchment area of 51,876 km2, and to
which various reasons over time, especially in the last fifty years
have seen a sharp decline and have decreased by about 93 % in two
recent decades. These variations are not only driving significant
changes in the morphology and ecology of the present lake
landscape, but at the same time are shaping newly formed
morphologies, which vanished some valuable geomorphosites or
develop into smaller geomorphosites with significant value from a
scientific and cultural point of view. This paper analyses and
discusses features and evolution in several representative coastal and
island geomorphosites. For this purpose, a total of 23 geomorphosites
were studied in two data series (1963 and 2015) and the respective
data were compared and analysed. The results showed, the total loss
in geomorphosites area in a half century amounted to a loss of more
than 90% of the valuable geomorphosites. Moreover, the comparison
between the mean yearly value of coastal area lost over the entire
period and the yearly average calculated for the shorter period (1998-
2014) clearly indicates a pattern of acceleration. This acceleration in
the rate of reduction in lake area was seen in most of the southern
half of the lake. In the region as well, the general water-level falling
is not only causing the loss of a significant water resource, which is
followed by major impact on regional ecosystems, but is also driving
the most marked recent (last century) changes in the geotouristic
landscapes. In fact, the disappearance of geomorphosites means the
loss of tourism phenomenon. In this context attention must be paid to
the question of conservation. The action needed to safeguard
geomorphosites includes: 1) Preventive action, 2) Corrective action,
and 3) Sharing knowledge.
Abstract: Electrodeposition is a simple and economic technique
for precision coating of different shaped substrates with pure metal,
alloy or composite films. Dc electrodeposition was used to produce
Cr, Co-Cr and Co-Cr/TiO2 nano-composite coatings from Cr(III)
based electrolytes onto 316L SS substrates. The effects of TiO2 nanoparticles
concentration on co-deposition of these particles along with
Cr content and microhardness of the coatings were investigated.
Morphology of the Cr, Co-Cr and Co-Cr/TiO2 coatings besides their
tribological behavior were studied. The results showed that increment
of TiO2 nanoparticles concentration from 0 to 30 g L-1 in the bath
increased their co-deposition and Cr content of the coatings from 0 to
3.5 wt.% and from 23.7 to 31.2 wt.%, respectively. Microhardness of
Cr coating was about 920 Hv which was higher than Co-Cr and even
Co-Cr/TiO2 films. Microhardness of Co-Cr and Co-Cr/TiO2 coatings
were improved by increasing their Cr and TiO2 content. All the
coatings had nodular morphology and contained microcracks.
Nodules sizes and the number of microcracks in the alloy and
composite coatings were lower than the Cr film. Wear results
revealed that the Co-Cr/TiO2 coating had the lowest wear loss
between all the samples, while the Cr film had the worst wear
resistance.
Abstract: In more complex systems, such as automotive
gearbox, a rigorous treatment of the data is necessary because there
are several moving parts (gears, bearings, shafts, etc.), and in this
way, there are several possible sources of errors and also noise. The
basic objective of this work is the detection of damage in automotive
gearbox. The detection methods used are the wavelet method, the
bispectrum; advanced filtering techniques (selective filtering) of
vibrational signals and mathematical morphology. Gearbox vibration
tests were performed (gearboxes in good condition and with defects)
of a production line of a large vehicle assembler. The vibration
signals are obtained using five accelerometers in different positions
of the sample. The results obtained using the kurtosis, bispectrum,
wavelet and mathematical morphology showed that it is possible to
identify the existence of defects in automotive gearboxes.
Abstract: In this paper we propose a novel methodology for
extracting a road network and its nodes from satellite images of
Algeria country.
This developed technique is a progress of our previous research
works. It is founded on the information theory and the mathematical
morphology; the information theory and the mathematical
morphology are combined together to extract and link the road
segments to form a road network and its nodes.
We therefore have to define objects as sets of pixels and to study
the shape of these objects and the relations that exist between them.
In this approach, geometric and radiometric features of roads are
integrated by a cost function and a set of selected points of a crossing
road. Its performances were tested on satellite images of Algeria
country.
Abstract: This paper presents the development of a robot car
that can track the motion of an object by detecting its color through
an Android device. The employed computer vision algorithm uses the
OpenCV library, which is embedded into an Android application of a
smartphone, for manipulating the captured image of the object. The
captured image of the object is subjected to color conversion and is
transformed to a binary image for further processing after color
filtering. The desired object is clearly determined after removing
pixel noise by applying image morphology operations and contour
definition. Finally, the area and the center of the object are
determined so that object’s motion to be tracked. The smartphone
application has been placed on a robot car and transmits by Bluetooth
to an Arduino assembly the motion directives so that to follow
objects of a specified color. The experimental evaluation of the
proposed algorithm shows reliable color detection and smooth
tracking characteristics.
Abstract: In this study, ultrasonic assisted machining (UAM) technique is applied in side-surface milling experiment for glass-ceramic workpiece material. The tungsten carbide cutting-tool with diamond coating is used in conjunction with two kinds of cooling/lubrication mediums such as water-soluble (WS) cutting fluid and minimum quantity lubricant (MQL). Full factorial process parameter combinations on the milling experiments are planned to investigate the effect of process parameters on cutting performance. From the experimental results, it tries to search for the better process parameter combination which the edge-indentation and the surface roughness are acceptable. In the machining experiments, ultrasonic oscillator was used to excite a cutting-tool along the radial direction producing a very small amplitude of vibration frequency of 20KHz to assist the machining process. After processing, toolmaker microscope was used to detect the side-surface morphology, edge-indentation and cutting tool wear under different combination of cutting parameters, and analysis and discussion were also conducted for experimental results. The results show that the main leading parameters to edge-indentation of glass ceramic are cutting depth and feed rate. In order to reduce edge-indentation, it needs to use lower cutting depth and feed rate. Water-soluble cutting fluid provides a better cooling effect in the primary cutting area; it may effectively reduce the edge-indentation and improve the surface morphology of the glass ceramic. The use of ultrasonic assisted technique can effectively enhance the surface finish cleanness and reduce cutting tool wear and edge-indentation.
Abstract: In this study, polycaprolactone (PCL) was dissolved
in chloroform:ethanol solvent system at a concentration of 18 w/v %.
1, 2, 4, and 6 droplets of formic acid were added to the prepared 10ml
PCL-chloroform:ethanol solutions separately. Fibrous webs were
produced by electrospinning technique based on the horizontal
working principle. Morphology of the webs was investigated by
using scanning electron microscopy (SEM) whereas fiber diameters
were measured by Image J Software System. The effect of formic
acid addition to the mostly used chloroform solvent on fiber
morphology was examined.
Results indicate that there is a distinct fall in fiber diameter with
the addition of formic acid drops. The average fiber diameter was
measured as 2.22μm in PCL /chloroform:ethanol solution system. On
the other hand, 328nm and 256 nm average fiber diameters were
measured for the samples of 4 drops and 6 drops formic acid added.
This study offers alternative solvent systems to produce nanoscaled,
nontoxic PCL fibrous webs by electrospinning technique.
Abstract: The objective of this work is to study the effect of two
key factors - external magnetic field and applied current density
during template-based electrodeposition of nickel nanowires using an
electrode distance of 20 mm. Morphology, length, crystallite size and
crystallographic characterization of the grown nickel nanowires at an
electrode distance of 20mm are presented. For this electrode distance
of 20 mm, these two key electrodeposition factors when coupled was
found to reduce crystallite size with a higher growth length and
preferred orientation of Ni crystals. These observed changes can be
inferred to be due to coupled interaction forces induced by the
intensity of applied electric field (current density) and external
magnetic field known as magnetohydrodynamic (MHD) effect during
the electrodeposition process.
Abstract: Rice husk and kenaf filled with calcium carbonate
(CaCO3) and high density polyethylene (HDPE) composite were
prepared separately using twin-screw extruder at 50rpm. Different
filler loading up to 30 parts of rice husk particulate and kenaf fiber
were mixed with the fixed 30% amount of CaCO3 mineral filler to
produce rice husk/CaCO3/HDPE and kenaf/CaCO3/HDPE hybrid
composites. In this study, the effects of natural fiber for both rice
husk and kenaf in CaCO3/HDPE composite on physical, mechanical
and morphology properties were investigated. Field Emission
Scanning Microscope (FeSEM) was used to investigate the impact
fracture surfaces of the hybrid composite. The property analyses
showed that water absorption increased with the presence of kenaf
and rice husk fillers. Natural fibers in composite significantly
influence water absorption properties due to natural characters of
fibers which contain cellulose, hemicellulose and lignin structures.
The result showed that 10% of additional natural fibers into hybrid
composite had caused decreased flexural strength, however additional
of high natural fiber (>10%) filler loading has proved to increase its
flexural strength.
Abstract: Today, the pollution due to non-degradable material
such as plastics, has led to studies about the development of
environmental-friendly material. Because of biodegradability
obtained from natural sources, polylactid acid (PLA) and ijuk fiber
are interesting to modify into a composite. This material is also
expected to reduce the impact of environmental pollution. Surface
modification of ijuk fiber through alkalinization with 0.25 M NaOH
solution for 30 minutes was aimed to enhance its compatibility to
PLA, in order to improve properties of the composite such as the
mechanical properties. Alkalinization of the ijuk fibers annihilates
some surface components such as lignin, wax and hemicelloluse, so
the pore on the surface clearly appeared, decreasing of the density
and diameter of the ijuk fibers. The change of the ijuk fiber properties
leads to increase the mechanical properties of PLA composites
reinforced the ijuk fibers through strengthening of the mechanical
interlocking with the PLA matrix. An addition to enhance the
distribution of the fibers in the PLA matrix, the stirring during DCM
solvent evaporation from the mixture of the ijuk fibers and the
dissolved-PLA can reduce amount of the trapped-voids and fibers
pull-out phenomena, which can decrease the mechanical properties of
the composite.
Abstract: Composite material based on Fe3Si micro-particles
and Mn-Zn nano-ferrite was prepared using powder metallurgy
technology. The sol-gel followed by autocombustion process was
used for synthesis of Mn0.8Zn0.2Fe2O4 ferrite. 3 wt.% of mechanically
milled ferrite was mixed with Fe3Si powder alloy. Mixed micro-nano
powder system was homogenized by the Resonant Acoustic Mixing
using ResodynLabRAM Mixer. This non-invasive homogenization
technique was used to preserve spherical morphology of Fe3Si
powder particles. Uniaxial cold pressing in the closed die at pressure
600 MPa was applied to obtain a compact sample. Microwave
sintering of green compact was realized at 800°C, 20 minutes, in air.
Density of the powders and composite was measured by
Hepycnometry. Impulse excitation method was used to measure
elastic properties of sintered composite. Mechanical properties were
evaluated by measurement of transverse rupture strength (TRS) and
Vickers hardness (HV). Resistivity was measured by 4 point probe
method. Ferrite phase distribution in volume of the composite was
documented by metallographic analysis.
It has been found that nano-ferrite particle distributed among
micro- particles of Fe3Si powder alloy led to high relative density
(~93%) and suitable mechanical properties (TRS >100 MPa, HV
~1GPa, E-modulus ~140 GPa) of the composite. High electric
resistivity (R~6.7 ohm.cm) of prepared composite indicate their
potential application as soft magnetic material at medium and high
frequencies.
Abstract: Microbial fuel cells (MFCs) represent a promising
technology for simultaneous bioelectricity generation and wastewater
treatment. Catalysts are significant portions of the cost of microbial
fuel cell cathodes. Many materials have been tested as aqueous
cathodes, but air-cathodes are needed to avoid energy demands for
water aeration. The sluggish oxygen reduction reaction (ORR) rate at
air cathode necessitates efficient electrocatalyst such as carbon
supported platinum catalyst (Pt/C) which is very costly. Manganese
oxide (MnO2) was a representative metal oxide which has been
studied as a promising alternative electrocatalyst for ORR and has
been tested in air-cathode MFCs. However the single MnO2 has poor
electric conductivity and low stability. In the present work, the MnO2
catalyst has been modified by doping Pt nanoparticle. The goal of the
work was to improve the performance of the MFC with minimum Pt
loading. MnO2 and Pt nanoparticles were prepared by hydrothermal
and sol gel methods, respectively. Wet impregnation method was
used to synthesize Pt/MnO2 catalyst. The catalysts were further used
as cathode catalysts in air-cathode cubic MFCs, in which anaerobic
sludge was inoculated as biocatalysts and palm oil mill effluent
(POME) was used as the substrate in the anode chamber. The asprepared
Pt/MnO2 was characterized comprehensively through field
emission scanning electron microscope (FESEM), X-Ray diffraction
(XRD), X-ray photoelectron spectroscopy (XPS), and cyclic
voltammetry (CV) where its surface morphology, crystallinity,
oxidation state and electrochemical activity were examined,
respectively. XPS revealed Mn (IV) oxidation state and Pt (0)
nanoparticle metal, indicating the presence of MnO2 and Pt.
Morphology of Pt/MnO2 observed from FESEM shows that the
doping of Pt did not cause change in needle-like shape of MnO2
which provides large contacting surface area. The electrochemical
active area of the Pt/MnO2 catalysts has been increased from 276 to
617 m2/g with the increase in Pt loading from 0.2 to 0.8 wt%. The
CV results in O2 saturated neutral Na2SO4 solution showed that
MnO2 and Pt/MnO2 catalysts could catalyze ORR with different
catalytic activities. MFC with Pt/MnO2 (0.4 wt% Pt) as air cathode
catalyst generates a maximum power density of 165 mW/m3, which
is higher than that of MFC with MnO2 catalyst (95 mW/m3). The
open circuit voltage (OCV) of the MFC operated with MnO2 cathode
gradually decreased during 14 days of operation, whereas the MFC
with Pt/MnO2 cathode remained almost constant throughout the
operation suggesting the higher stability of the Pt/MnO2 catalyst.
Therefore, Pt/MnO2 with 0.4 wt% Pt successfully demonstrated as an
efficient and low cost electrocatalyst for ORR in air cathode MFC with higher electrochemical activity, stability and hence enhanced
performance.
Abstract: This work reports the potential of using Palm Kernel
(PK) ash and shell as a partial substitute for Portland Cement (PC)
and coarse aggregate in the development of mortar and concrete. PK
ash and shell are agro-waste materials from palm oil mills, the
disposal of PK ash and shell is an environmental problem of concern.
The PK ash has pozzolanic properties that enables it as a partial
replacement for cement and also plays an important role in the
strength and durability of concrete, its use in concrete will alleviate
the increasing challenges of scarcity and high cost of cement. In order
to investigate the PC replacement potential of PK ash, three types of
PK ash were produced at varying temperature (350-750C) and they
were used to replace up to 50% PC. The PK shell was used to replace
up to 100% coarse aggregate in order to study its aggregate
replacement potential. The testing programme included material
characterisation, the determination of compressive strength, tensile
splitting strength and chemical durability in aggressive sulfatebearing
exposure conditions. The 90 day compressive results showed
a significant strength gain (up to 26.2 N/mm2). The Portland cement
and conventional coarse aggregate has significantly higher influence
in the strength gain compared to the equivalent PK ash and PK shell.
The chemical durability results demonstrated that after a prolonged
period of exposure, significant strength losses in all the concretes
were observed. This phenomenon is explained, due to lower change
in concrete morphology and inhibition of reaction species and the
final disruption of the aggregate cement paste matrix.
Abstract: Water contamination by toxic compound is one of the serious environmental problems today. These toxic compounds mostly originated from industrial effluents, agriculture, natural sources and human waste. These studies focus on modification of multiwalled carbon nanotube (MWCNTs) with nanoparticle of calixarene and explore the possibility of using this modification for the remediation of cadmium in water. The nanocomposites were prepared by dissolving calixarene in chloroform solution as solvent, followed by additional multiwalled carbon nanotube (MWCNTs) then sonication process for 3 hour and fabricated the nanocomposites on substrate by spin coating method. Finally, the nanocomposites were tested on cadmium ion (10 mg/ml). The morphology of nanocomposites was investigated by FESEM showing the formation of calixarene on the outer walls of carbon nanotube and cadmium ion also clearly seen from the micrograph. This formation was supported by using energy dispersive x-ray (EDX). The presence of cadmium ions in the films, leads to some changes in the surface potential and Fourier Transform Infrared spectroscopy (FTIR).The nanocomposites MWCNTs-calixarene have potential for development of sensor for pollutant monitoring and nanoelectronics devices applications.
Abstract: The present work aims to throw light on the effects of
arcing in air on the surface state of contact pastilles made of silvernickel
Ag-Ni (60/40). Also, the photoelectric emission from these
electrical contacts has been investigated in the spectral range of 196-
256 nm. In order to study the effects of arcing on the EWF, the
metallic samples were subjected to electrical arcs in air, at
atmospheric pressure and room temperature, after that, they have
been introduced into the vacuum chamber of an experimental UHV
set-up for EWF measurements. Both Fowler method of isothermal
curves and linearized Fowler plots were used for the measurement of
the EWF by the photoelectric effect.
It has been found that the EWF varies with the number of applied
arcs. Thus, after 500 arcs in air, the observed EWF increasing is
probably due to progressive inclusion of oxide on alloy surface.
Microscopic examination is necessary to get better understandings on
EWF of silver alloys, for both virgin and arced electrical contacts.
Abstract: Compositions of different molar ratios of
polymethylmethacrylate-co-methacrylic acid (PMMA-co-MAA)
were synthesized via free-radical polymerization. Polymer coated
surfaces have been produced on silicon wafers. Coated samples were
analyzed by atomic force microscopy (AFM). The results have shown
that the roughness of the surfaces have increased by increasing the
molar ratio of monomer methacrylic acid (MAA). This study reveals
that the gradual increase in surface roughness is due to the fact that
carboxylic functional groups have been generated by MAA segments.
Such surfaces can be desirable platforms for fabrication of the
biosensors for detection of the viruses and diseases.
Abstract: Karst term is the determiner of a variety of areas or
landforms and unique perspectives that have been formed in result of
the of the ingredients dissolution of rocks constituter by natural
waters. Shiraz area with an area of 5322km2 is located in the simple
folded belt in the southern part of Zagros Mountain of Fars, and is
surrounded with Limestone Mountains (Asmari formation). Shiraz
area is located in Calcareous areas. The infrastructure of this city is
lime and absorbing wells that the city can influence the Limestone
dissolution and those accelerate its rate and increase the cavitation
below the surface. Dasht-e Arjan is a graben, which has been created
as the result of activity of two normal faults in its east and west sides.
It is a complete sample of Karst plains (Polje) which has been created
with the help of tectonic forces (fault) and dissolution process of
water in Asmari limestone formation. It is located 60km. off south
west of Shiraz (on Kazeroon-Shiraz road). In 1971, UNESCO has
recognized this plain as a reserve of biosphere. It is considered as one
of the world’s most beautiful geological phenomena, so that most of
the world’s geologists are interested in visiting this place. The
purpose of this paper is to identify and introduce landscapes of Karst
features shiraz city and Dasht-e Arjan including Karst dissolution
features (Lapiez, Karst springs, dolines, caves, underground caves,
ponors, and Karst valleys), anticlines and synclines, and Arjan Lake.
Abstract: To develop AZ91D magnesium alloys with improved
properties, we have applied TiN and VN/TiN multilayer coatings
using DC magnetron sputter technique. Coating structure, surface
morphology, chemical bonding and corrosion resistance of coatings
were analyzed by x-ray diffraction (XRD), scanning electron
microscope (SEM), x-ray photoelectron spectroscopy (XPS), and
tafel extrapolation method, respectively. XPS analysis reveal that VN
overlayer reacts with oxygen at the VN/TiN interface and forms more
stable TiN layer. Morphological investigations and the corrosion
results show that VN/TiN multilayer thin film coatings are quite
effective to optimize the corrosion resistance of Mg alloys.