Abstract: Magnesium alloys have gained increased attention in recent years in automotive, electronics, and medical industry. This because of magnesium alloys have better properties than aluminum alloys and steels in respects of their low density and high strength to weight ratio. However, the main problems of magnesium alloy welding are the crack formation and the appearance of porosity during the solidification. This paper proposes a unique technique to weld two thin sheets of AZ31B magnesium alloy using a paste containing Ag nanoparticles. The paste containing Ag nanoparticles of 5 nm in average diameter and an organic solvent was used to coat the surface of AZ31B thin sheet. The coated sheet was heated at 100 °C for 60 s to evaporate the solvent. The dried sheet was set as a lower AZ31B sheet on the jig, and then lap fillet welding was carried out by using a pulsed Nd:YAG laser in a closed box filled with argon gas. The characteristics of the microstructure and the corrosion behavior of the joints were analyzed by opticalmicroscopy (OM), energy dispersive spectrometry (EDS), electron probe micro-analyzer (EPMA), scanning electron microscopy (SEM), and immersion corrosion test. The experimental results show that the wrought AZ31B magnesium alloy can be joined successfully using Ag nanoparticles. Ag nanoparticles insert promote grain refinement, narrower the HAZ width and wider bond width compared to weld without and insert. Corrosion rate of welded AZ31B with Ag nanoparticles reduced up to 44 % compared to base metal. The improvement of corrosion resistance of welded AZ31B with Ag nanoparticles due to finer grains and large grain boundaries area which consist of high Al content. β-phase Mg17Al12 could serve as effective barrier and suppressed further propagation of corrosion. Furthermore, Ag distribution in fusion zone provide much more finer grains and may stabilize the magnesium solid solution making it less soluble or less anodic in aqueous
Abstract: Steel made pipelines with different diameters are used
for transmitting oil and gas which in many cases are buried in soil
under the sea bed or immersed in sea water. External corrosion of
pipes is an important form of deterioration due to the aggressive
environment of sea water. Corrosion normally results in pits. Hence,
using the finite element method, namely ABAQUS software, this
paper estimates the amount of pressure capacity reduction of a pipecontaining
a semi-elliptical pitting corrosion and the rate of corrosion
during the pipeline life of 25 years.
Abstract: Natural gas is the most popular fossil fuel in the
current era and future as well. Natural gas is existed in underground
reservoirs so it may contain many of non-hydrocarbon components
for instance, hydrogen sulfide, nitrogen and water vapor. These
impurities are undesirable compounds and cause several technical
problems for example, corrosion and environment pollution.
Therefore, these impurities should be reduce or removed from natural
gas stream. Khurmala dome is located in southwest Erbil-Kurdistan
region. The Kurdistan region government has paid great attention for
this dome to provide the fuel for Kurdistan region. However, the
Khurmala associated natural gas is currently flaring at the field.
Moreover, nowadays there is a plan to recover and trade this gas and
to use it either as feedstock to power station or to sell it in global
market. However, the laboratory analysis has showed that the
Khurmala sour gas has huge quantities of H2S about (5.3%) and CO2
about (4.4%). Indeed, Khurmala gas sweetening process has been
removed in previous study by using Aspen HYSYS. However,
Khurmala sweet gas still contents some quintets of water about 23
ppm in sweet gas stream. This amount of water should be removed or
reduced. Indeed, water content in natural gas cause several technical
problems such as hydrates and corrosion. Therefore, this study aims
to simulate the prospective Khurmala gas dehydration process by
using Aspen HYSYS V. 7.3 program. Moreover, the simulation
process succeeded in reducing the water content to less than 0.1ppm.
In addition, the simulation work is also achieved process
optimization by using several desiccant types for example, TEG and
DEG and it also study the relationship between absorbents type and
its circulation rate with HCs losses from glycol regenerator tower.