Abstract: Acid rain occurs when sulphur dioxide (SO2) and
nitrogen oxides (Nox) gases react in the atmosphere with water,
oxygen, and other chemicals to form various acidic compounds. The
result is a mild solution of sulfuric acid and nitric acid. Soil has a
greater buffering capacity than aquatic systems. However excessive
amount of acids introduced by acid rains may disturb the entire soil
chemistry. Acidity and harmful action of toxic elements damage
vegetation while susceptible microbial species are eliminated. In
present study, the effects of simulated sulphuric acid and nitric acid
rains were investigated on crop Glycine max. The effect of acid rain
on change in soil fertility was detected in which pH of control sample
was 6.5 and pH of 1%H2SO4 and 1%HNO3 were 3.5. Nitrogen nitrate
in soil was high in 1% HNO3 treated soil & Control sample.
Ammonium nitrogen in soil was low in 1% HNO3 & H2SO4 treated
soil. Ammonium nitrogen was medium in control and other samples.
The effect of acid rain on seed germination on 3rd day of germination
control sample growth was 7 cm, 0.1% HNO3 was 8cm, and 0.001%
HNO3 & 0.001% H2SO4 was 6cm each. On 10th day fungal growth
was observed in 1% and 0.1%H2SO4 concentrations, when all plants
were dead. The effect of acid rain on crop productivity was
investigated on 3rd day roots were developed in plants. On12th day
Glycine max showed more growth in 0.1% HNO3, 0.001% HNO3 and
0.001% H2SO4 treated plants growth were same as compare to control
plants. On 20th day development of discoloration of plant pigments
were observed on acid treated plants leaves. On 38th day, 0.1, 0.001%
HNO3 and 0.1, 0.001% H2SO4 treated plants and control plants were
showing flower growth. On 42th day, acid treated Glycine max variety
and control plants were showed seeds on plants. In Glycine max
variety 0.1, 0.001% H2SO4, 0.1, 0.001% HNO3 treated plants were
dead on 46th day and fungal growth was observed. The toxicological
study was carried out on Glycine max plants exposed to 1% HNO3
cells were damaged more than 1% H2SO4. Leaf sections exposed to
0.001% HNO3 & H2SO4 showed less damaged of cells and
pigmentation observed in entire slide when compare with control
plant. The soil analysis was done to find microorganisms in HNO3 &
H2SO4 treated Glycine max and control plants. No microorganism
growth was observed in 1% HNO3 & H2SO4 but control plant showed
microbial growth.
Abstract: Eukaryotic protein-coding genes are interrupted by spliceosomal introns, which are removed from the RNA transcripts before translation into a protein. The exon-intron structures of different eukaryotic species are quite different from each other, and the evolution of such structures raises many questions. We try to address some of these questions using statistical analysis of whole genomes. We go through all the protein-coding genes in a genome and study correlations between the net length of all the exons in a gene, the number of the exons, and the average length of an exon. We also take average values of these features for each chromosome and study correlations between those averages on the chromosomal level. Our data show universal features of exon-intron structures common to animals, plants, and protists (specifically, Arabidopsis thaliana, Caenorhabditis elegans, Drosophila melanogaster, Cryptococcus neoformans, Homo sapiens, Mus musculus, Oryza sativa, and Plasmodium falciparum). We have verified linear correlation between the number of exons in a gene and the length of a protein coded by the gene, while the protein length increases in proportion to the number of exons. On the other hand, the average length of an exon always decreases with the number of exons. Finally, chromosome clustering based on average chromosome properties and parameters of linear regression between the number of exons in a gene and the net length of those exons demonstrates that these average chromosome properties are genome-specific features.
Abstract: The present work was conducted to find out the effect
of biofertilizer formulated with four species of bacteria (two species
of Azotobacter and two species of Lysobacter) and zinc sulphate.
Field experiments with mustard plant were conducted to study the
effectiveness of soil application of zinc sulphate and biofertilizer at
0, 10, 20, 30, 40, 50 days after sowing. Plant height and condition of
plant was found to be increased significantly using a mixture of
biofertilizer and zinc sulphate than other treatments after 40 days
sowing. Three treatments were also used in this field experiment such
as bacteria only, zinc sulphate only and mixture of biofertilizer and
zinc sulphate. The treatment using a mixture of zinc sulphate and
biofertilizer had the best yield (4688.008 kg/ha) within 50 days of
sowing and performed better than other treatments. Field experiment
using zinc sulphate only was second best yield (3380.75Kg/ha) and
biofertilizer only treatment gave (2639.04kg/ha).
Abstract: The problem on the conservation programme of the Royal Thai Navy Sea Turtle Nursery, Phang-nga Province, Thailand is high mortality rate of juvenile green sea turtle (Cheloniamydas) on nursing period. So, during May to October 2012, postmortem examinations of juvenile green sea turtle were performed to determine the causes of dead. Fresh tissues of postmortem of 15 juvenile green sea turtles (1-3 months old) were investigated using paraffin section technique. The results showed normal ultrastructure of all tissue organs. These instances reviewed the health and stability of the environments in which juvenile green sea turtles live and concern for the survival rate. The present article also provides guidance for a review of the biology, guidelines for appropriate postmortem tissue, normal histology and sampling collection and procedures. The data also provides information for conservation of this endangered species in term of acknowledging and encouraging people to protect the animals and their habitats in nature.
Abstract: In this study, a 3D combustion chamber was simulated
using FLUENT 6.32. Aims to obtain accurate information about the
profile of the combustion in the furnace and also check the effect of
oxygen enrichment on the combustion process. Oxygen enrichment is
an effective way to reduce combustion pollutant. The flow rate of air
to fuel ratio is varied as 1.3, 3.2 and 5.1 and the oxygen enriched
flow rates are 28, 54 and 68 lit/min. Combustion simulations
typically involve the solution of the turbulent flows with heat
transfer, species transport and chemical reactions. It is common to
use the Reynolds-averaged form of the governing equation in
conjunction with a suitable turbulence model. The 3D Reynolds
Averaged Navier Stokes (RANS) equations with standard k-ε
turbulence model are solved together by Fluent 6.3 software. First
order upwind scheme is used to model governing equations and the
SIMPLE algorithm is used as pressure velocity coupling. Species
mass fractions at the wall are assumed to have zero normal
gradients.Results show that minimum mole fraction of CO2 happens
when the flow rate ratio of air to fuel is 5.1. Additionally, in a fixed
oxygen enrichment condition, increasing the air to fuel ratio will
increase the temperature peak. As a result, oxygen-enrichment can
reduce the CO2 emission at this kind of furnace in high air to fuel
rates.
Abstract: Lake Nasser is one of the largest reservoirs in the
world. Over 120 million metric tons of sediments are deposited in its
dead storage zone every year. The main objective of the present work
was to determine the physical and chemical characteristics of Lake
Nasser sediments. The sample had a relatively low surface area of 2.9
m2/g which increased more than 3-fold upon chemical activation. The
main chemical elements of the raw sediments were C, O and Si with
some traces of Al, Fe and Ca. The organic functional groups for the
tested sample included O-H, C=C, C-H and C-O, with indications of
Si-O and other metal-C and/or metal-O bonds normally associated
with clayey materials. Potentiometric titration of the sample in
different ionic strength backgrounds revealed an alkaline material with
very strong positive surface charge at pH values just a little less than
the pH of zero charge which is ~9. Surface interactions of the
sediments with the background electrolyte were significant. An
advanced surface complexation model was able to capture these
effects, employing a single-site approach to represent protolysis
reactions in aqueous solution, and to determine the significant surface
species in the pH range of environmental interest.
Abstract: Understanding of how and where NOx formation
occurs in industrial burner is very important for efficient and clean
operation of utility burners. Also the importance of this problem is
mainly due to its relation to the pollutants produced by more burners
used widely of gas turbine in thermal power plants and glass and steel
industry.
In this article, a numerical model of an industrial burner operating
in MILD combustion is validated with experimental data.. Then
influence of air flow rate and air temperature on combustor
temperature profiles and NOX product are investigated. In order to
modification this study reports on the effects of fuel and air dilution
(with inert gases H2O, CO2, N2), and also influence of lean-premixed
of fuel, on the temperature profiles and NOX emission.
Conservation equations of mass, momentum and energy, and
transport equations of species concentrations, turbulence, combustion
and radiation modeling in addition to NO modeling equations were
solved together to present temperature and NO distribution inside the
burner.
The results shows that dilution, cause to a reduction in value of
temperature and NOX emission, and suppresses any flame
propagation inside the furnace and made the flame inside the furnace
invisible. Dilution with H2O rather than N2 and CO2 decreases further
the value of the NOX. Also with raise of lean-premix level, local
temperature of burner and the value of NOX product are decreases
because of premixing prevents local “hot spots" within the combustor
volume that can lead to significant NOx formation. Also leanpremixing
of fuel with air cause to amount of air in reaction zone is
reach more than amount that supplied as is actually needed to burn
the fuel and this act lead to limiting NOx formation
Abstract: A model of a system concerning one species of demersal
(inshore) fish and one of pelagic (offshore) fish undergoing fishing
restricted by marine protected areas is proposed in this paper. This
setup was based on the FISH-BE model applied to the Tabina fishery
in Zamboanga del Sur, Philippines. The components of the model
equations have been adapted from widely-accepted mechanisms in
population dynamics. The model employs Gompertz-s law of growth
and interaction on each type of protected and unprotected subpopulation.
Exchange coefficients between protected and unprotected
areas were assumed to be proportional to the relative area of the
entry region. Fishing harvests were assumed to be proportional to
both the number of fishers and the number of unprotected fish. An
extra term was included for the pelagic population to allow for the
exchange between the unprotected area and the outside environment.
The systems were found to be bounded for all parameter values. The
equations for the steady state were unsolvable analytically but the
existence and uniqueness of non-zero steady states can be proven.
Plots also show that an MPA size yielding the maximum steady state
of the unprotected population can be found. All steady states were
found to be globally asymptotically stable for the entire range of
parameter values.
Abstract: In this study, solid phase micro-extraction (SPME)
was optimized to improve the sensitivity and accuracy in
formaldehyde determination for plywood panels. Further work has
been carried out to compare the newly developed technique with
existing method which reacts formaldehyde collected in desiccators
with acetyl acetone reagent (DC-AA). In SPME, formaldehyde was
first derivatized with O-(2,3,4,5,6 pentafluorobenzyl)-hydroxylamine
hydrochloride (PFBHA) and analysis was then performed by gas
chromatography in combination with mass spectrometry (GC-MS).
SPME data subjected to various wood species gave satisfactory
results, with relative standard deviations (RSDs) obtained in the
range of 3.1-10.3%. It was also well correlated with DC values,
giving a correlation coefficient, RSQ, of 0.959. The quantitative
analysis of formaldehyde by SPME was an alternative in wood
industry with great potential
Abstract: The full length mitochondrial small subunit ribosomal
(mt-rns) gene has been characterized for Ophiostoma novo-ulmi
subspecies americana. The gene was also characterized for
Ophiostoma ulmi and a group II intron was noted in the mt-rns gene
of O. ulmi. The insertion in the mt-rns gene is at position S952 and it
is a group IIB1 intron that encodes a double motif LAGLIDADG
homing endonuclease from an open reading frame located within a
loop of domain III. Secondary structure models for the mt-rns RNA
of O. novo-ulmi subsp. americana and O. ulmi were generated to
place the intron within the context of the ribosomal RNA. The in vivo
splicing of the O.ul-mS952 group II intron was confirmed with
reverse transcription-PCR. A survey of 182 strains of Dutch Elm
Diseases causing agents showed that the mS952 intron was absent in
what is considered to be the more aggressive species O. novo-ulmi
but present in strains of the less aggressive O. ulmi. This observation
suggests that the O.ul-mS952 intron can be used as a PCR-based
molecular marker to discriminate between O. ulmi and O. novo-ulmi
subsp. americana.
Abstract: The study was carried out to gather and identify
medicinal plants their curative effects and the part of them which is
used from the reservation area of Miankaleh. The region under study
has an area of 68800 hectares situated 12 kilometers north of the city
of Behshahr and northwest of the city of Gorgan. Results obtained
showed that out of a total of 43 families, 125 genera, and 155 species
found in the region, 33 families, 52 genera and 61 species (39% of all
the species) belonged to medicinal plants, among which the class
Asteraceae with 6 species and the class Chenopodiaceae with 5
species had the most medicinal species. The most used parts of the
plants were the leaves with 31%, the whole plants with 19%, and the
roots with 15%.
Abstract: There are few studies on eggshell of leatherback turtle
which is endangered species in Thailand. This study was focusing on
the ultrastructure and elemental composition of leatherback turtle
eggshells collected from Andaman Sea Shore, Thailand during the
nesting season using scanning electron microscope (SEM). Three
eggshell layers of leatherback turtle; the outer cuticle layer or
calcareous layer, the middle layer or middle multistrata layer and the
inner fibrous layer were recognized. The outer calcareous layer was
thick and porosity which consisted of loose nodular units of various
crystal shapes and sizes. The loose attachment between these units
resulted in numerous spaces and openings. The middle layer was
compact thick with several multistrata and contained numerous
openings connecting to both outer cuticle layer and inner fibrous
layer. The inner fibrous layer was compact and thin, and composed of
numerous reticular fibers. Energy dispersive X-ray microanalysis
detector revealed energy spectrum of X-rays character emitted from
all elements on each layer. The percentages of all elements were
found in the following order: carbon (C) > oxygen (O) > calcium
(Ca) > sulfur (S) > potassium (K) > aluminum (Al) > iodine (I) >
silicon (Si) > chlorine (Cl) > sodium (Na) > fluorine (F) >
phosphorus (P) > magnesium (Mg). Each layer consisted of high
percentage of CaCO3 (approximately 98%) implying that it was
essential for turtle embryonic development. A significant difference
was found in the percentages of Ca and Mo in the 3layers. Moreover,
transition metal, metal and toxic non-metal contaminations were
found in leatherback turtle eggshell samples. These were palladium
(Pd), molybdenum (Mo), copper (Cu), aluminum (Al), lead (Pb), and
bromine (Br). The contamination elements were seen in the outer
layers except for Mo. All elements were readily observed and
mapped using Smiling program. X-ray images which mapped the
location of all elements were showed. Calcium containing in the
eggshell appeared in high contents and was widely distributing in
clusters of the outer cuticle layer to form CaCO3 structure. Moreover,
the accumulation of Na and Cl was observed to form NaCl which was
widely distributing in 3 eggshell layers. The results from this study
would be valuable on assessing the emergent success in this
endangered species.
Abstract: Variations in the growth rate constant of the Listeria
monocytogenes bacterial species were determined at 37°C in
irradiated environments and compared to the situation of a nonirradiated
environment. The bacteria cells, contained in a suspension
made of a nutrient solution of Brain Heart Infusion, were made to
grow at different frequency (2.30e2.60 GHz) and power (0e400
mW) values, in a plug flow reactor positioned in the irradiated
environment. Then the reacting suspension was made to pass into a
cylindrical cuvette where its optical density was read every 2.5
minutes at a wavelength of 600 nm. The obtained experimental data
of optical density vs. time allowed the bacterial growth rate constant
to be derived; this was found to be slightly influenced by microwave
power, but not by microwave frequency; in particular, a minimum
value was found for powers in the 50e150 mW field.
Abstract: Phylogenetic tree is a graphical representation of the
evolutionary relationship among three or more genes or organisms.
These trees show relatedness of data sets, species or genes
divergence time and nature of their common ancestors. Quality of a
phylogenetic tree requires parsimony criterion. Various approaches
have been proposed for constructing most parsimonious trees. This
paper is concerned about calculating and optimizing the changes of
state that are needed called Small Parsimony Algorithms. This paper
has proposed enhanced small parsimony algorithm to give better
score based on number of evolutionary changes needed to produce
the observed sequence changes tree and also give the ancestor of the
given input.
Abstract: The habitat where the present study has been carried
out is productive in relation to nutrient quality and they may perform
several useful functions, but are also threatened for their existence.
Hence, the proposed work, will add much new information about
biodiversity of macrophytes in drains and their embankment. All the
species were identified with their different stages of growth which
encountered on the three selected sites (I, II and III). The number of
species occurring at each site is grouped seasonally, i.e. summer,
rainy and winter season and the species were further recorded for the
study of phytosociology. Phytosociological characters such as
frequency, density and abundance were influenced by the climatic,
anthropogenic and biotic stresses prevailing at the three study sites.
All the species present at the study sites have shown maximum
values of frequency, density and abundance in rainy season in
comparison to that of summer and winter seasons.
Abstract: An ultrasound-assisted activation method for
electroless silver plating is presented in this study. When the
ultrasound was applied during the activation step, the amount of the Pd
species adsorbed on substrate surfaces was higher than that of sample
pretreated with a conventional activation process without ultrasound
irradiation. With this activation method, it was also shown that the
adsorbed Pd species with a size of about 5 nm were uniformly
distributed on the surfaces, thus a smooth and uniform coating on the
surfaces was obtained by subsequent electroless silver plating. The
samples after each step were characterized by AFM, XPS, FIB, and
SEM.
Abstract: The adsorption properties of CO and H2 on iron-based
catalyst with addition of Zr and Ni were investigated using
temperature programmed desorption process. It was found that on the
carburized iron-based catalysts, molecular state and dissociative state
CO existed together. The addition of Zr was preferential for the
molecular state adsorption of CO on iron-based catalyst and the
presence of Ni was beneficial to the dissociative adsorption of CO. On
H2 reduced catalysts, hydrogen mainly adsorbs on the surface iron
sites and surface oxide sites. On CO reduced catalysts, hydrogen
probably existed as the most stable CH and OH species. The addition
of Zr was not benefit to the dissociative adsorption of hydrogen on
iron-based catalyst and the presence of Ni was preferential for the
dissociative adsorption of hydrogen.
Abstract: This paper unifies power optimization approaches in
various energy converters, such as: thermal, solar, chemical, and
electrochemical engines, in particular fuel cells. Thermodynamics
leads to converter-s efficiency and limiting power. Efficiency
equations serve to solve problems of upgrading and downgrading of
resources. While optimization of steady systems applies the
differential calculus and Lagrange multipliers, dynamic optimization
involves variational calculus and dynamic programming. In reacting
systems chemical affinity constitutes a prevailing component of an
overall efficiency, thus the power is analyzed in terms of an active
part of chemical affinity. The main novelty of the present paper in the
energy yield context consists in showing that the generalized heat
flux Q (involving the traditional heat flux q plus the product of
temperature and the sum products of partial entropies and fluxes of
species) plays in complex cases (solar, chemical and electrochemical)
the same role as the traditional heat q in pure heat engines.
The presented methodology is also applied to power limits in fuel
cells as to systems which are electrochemical flow engines propelled
by chemical reactions. The performance of fuel cells is determined by
magnitudes and directions of participating streams and mechanism of
electric current generation. Voltage lowering below the reversible
voltage is a proper measure of cells imperfection. The voltage losses,
called polarization, include the contributions of three main sources:
activation, ohmic and concentration. Examples show power maxima
in fuel cells and prove the relevance of the extension of the thermal
machine theory to chemical and electrochemical systems. The main
novelty of the present paper in the FC context consists in introducing
an effective or reduced Gibbs free energy change between products p
and reactants s which take into account the decrease of voltage and
power caused by the incomplete conversion of the overall reaction.
Abstract: Cameron Highlands is known for upland tourism area
with vast natural wealth, mountainous landscape endowed with rich
diverse species as well as people traditions and cultures. With these
various resources, CH possesses an interesting visual and panorama
that can be offered to the tourist. However this benefit may not be
utilized without obtaining the understanding of existing landscape
structure and visual. Given a limited data, this paper attempts to
classify landscape visual of Cameron Highlands using land use and
contour data. Visual points of view were determined from the given
tourist attraction points in the CH Local Plan 2003-2015. The result
shows landscape visual and structure categories offered in the study
area. The result can be used for further analysis to determine the best
alternative tourist trails for tourism planning and decision making
using readily available data.
Abstract: Snake bite cases in Malaysia most often involve the
species Naja-naja and Calloselasma rhodostoma. In keeping with the
need for a rapid snake venom detection kit in a clinical setting, plate
and dot-ELISA test for the venoms of Naja-naja sumatrana,
Calloselasma rhodostoma and the cobra venom fraction V antigen
was developed. Polyclonal antibodies were raised and further used to
prepare the reagents for the dot-ELISA test kit which was tested in
mice, rabbit and virtual human models. The newly developed dot-
ELISA kit was able to detect a minimum venom concentration of
244ng/ml with cross reactivity of one antibody type. The dot-ELISA
system was sensitive and specific for all three snake venom types in
all tested animal models. The lowest minimum venom concentration
detectable was in the rabbit model, 244ng/ml of the cobra venom
fraction V antigen. The highest minimum venom concentration was
in mice, 1953ng/ml against a multitude of venoms. The developed
dot-ELISA system for the detection of three snake venom types was
successful with a sensitivity of 95.8% and specificity of 97.9%.