Abstract: This work concerns the topological optimization
problem for determining the optimal petroleum refinery
configuration. We are interested in further investigating and
hopefully advancing the existing optimization approaches and
strategies employing logic propositions to conceptual process
synthesis problems. In particular, we seek to contribute to this
increasingly exciting area of chemical process modeling by
addressing the following potentially important issues: (a) how the
formulation of design specifications in a mixed-logical-and-integer
optimization model can be employed in a synthesis problem to enrich
the problem representation by incorporating past design experience,
engineering knowledge, and heuristics; and (b) how structural
specifications on the interconnectivity relationships by space (states)
and by function (tasks) in a superstructure should be properly
formulated within a mixed-integer linear programming (MILP)
model. The proposed modeling technique is illustrated on a case
study involving the alternative processing routes of naphtha, in which
significant improvement in the solution quality is obtained.