Abstract: Carbon fibers are fabricated from different materials,
such as special polyacrylonitrile (PAN) fibers, rayon fibers and pitch.
Among these three groups of materials, PAN fibers are the most
widely used precursor for the manufacture of carbon fibers. The
process of fabrication carbon fibers from special PAN fibers includes
two steps; oxidative stabilization at low temperature and
carbonization at high temperatures in an inert atmosphere. Due to the
high price of raw materials (special PAN fibers), carbon fibers are
still expensive.
In the present work the main goal is making carbon fibers from
low price commercial PAN fibers with modified chemical
compositions. The results show that in case of conducting completes
stabilization process, it is possible to produce carbon fibers with
desirable tensile strength from this type of PAN fibers. To this
matter, thermal characteristics of commercial PAN fibers were
investigated and based upon the obtained results, with some changes
in conventional procedure of stabilization in terms of temperature
and time variables; the desirable conditions of complete stabilization
is achieved.
Abstract: A structural study of an aqueous electrolyte whose
experimental results are available. It is a solution of LiCl-6H2O type
at glassy state (120K) contrasted with pure water at room temperature
by means of Partial Distribution Functions (PDF) issue from neutron
scattering technique. Based on these partial functions, the Reverse
Monte Carlo method (RMC) computes radial and angular correlation
functions which allow exploring a number of structural features of
the system. The obtained curves include some artifacts. To remedy
this, we propose to introduce a screened potential as an additional
constraint. Obtained results show a good matching between
experimental and computed functions and a significant improvement
in PDFs curves with potential constraint. It suggests an efficient fit of
pair distribution functions curves.
Abstract: EPA (Ethernet for Plant Automation) resolves the nondeterministic problem of standard Ethernet and accomplishes real-time communication by means of micro-segment topology and deterministic scheduling mechanism. This paper studies the real-time performance of EPA periodic data transmission from theoretical and experimental perspective. By analyzing information transmission characteristics and EPA deterministic scheduling mechanism, 5 indicators including delivery time, time synchronization accuracy, data-sending time offset accuracy, utilization percentage of configured timeslice and non-RTE bandwidth that can be used to specify the real-time performance of EPA periodic data transmission are presented and investigated. On this basis, the test principles and test methods of the indicators are respectively studied and some formulas for real-time performance of EPA system are derived. Furthermore, an experiment platform is developed to test the indicators of EPA periodic data transmission in a micro-segment. According to the analysis and the experiment, the methods to improve the real-time performance of EPA periodic data transmission including optimizing network structure, studying self-adaptive adjustment method of timeslice and providing data-sending time offset accuracy for configuration are proposed.
Abstract: The aim of this study was to synthesize the single
walled carbon nanotubes (SWCNTs) and determine their hydrogen
storage capacities. SWCNTs were firstly synthesized by chemical
vapor deposition (CVD) of acetylene (C2H2) on a magnesium oxide
(MgO) powder impregnated with an iron nitrate (Fe(NO3)3·9H2O)
solution. The synthesis parameters were selected as: the synthesis
temperature of 800°C, the iron content in the precursor of 5% and the
synthesis time of 30 min. Purification process of SWCNTs was
fulfilled by microwave digestion at three different temperatures (120,
150 and 200 °C), three different acid concentrations (0.5, 1 and 1.5
M) and for three different time intervals (15, 30 and 60 min). Nitric
acid (HNO3) was used in the removal of the metal catalysts. The
hydrogen storage capacities of the purified materials were measured
using volumetric method at the liquid nitrogen temperature and gas
pressure up to 100 bar. The effects of the purification conditions such
as temperature, time and acid concentration on hydrogen adsorption
were investigated.
Abstract: The selection of parents and breeding strategies for
the successful maize hybrid production will be facilitated by
heterotic groupings of parental lines and determination of combining
abilities of them. Fourteen maize inbred lines, used in maize breeding
programs in Iran, were crossed in a diallel mating design. The 91 F1
hybrids and the 14 parental lines were studied during two years at
four locations of Iran for investigation of combining ability of
gentypes for grain yield and to determine heterotic patterns among
germplasm sources, using both, the Griffing-s method and the biplot
approach for diallel analysis. The graphical representation offered by
biplot analysis allowed a rapid and effective overview of general
combining ability (GCA) and specific combining ability (SCA)
effects of the inbred lines, their performance in crosses, as well as
grouping patterns of similar genotypes. GCA and SCA effects were
significant for grain yield (GY). Based on significant positive GCA
effects, the lines derived from LSC could be used as parent in crosses
to increase GY. The maximum best- parent heterosis values and
highest SCA effects resulted from crosses B73 × MO17 and A679 ×
MO17 for GY. The best heterotic patterns were LSC × RYD, which
would be potentially useful in maize breeding programs to obtain
high-yielding hybrids in the same climate of Iran.
Abstract: A catastrophic earthquake measuring 6.3 on the
Richter scale struck the Christchurch, New Zealand Central Business
District on February 22, 2012, abruptly disrupting the business of
teaching and learning at Christchurch Polytechnic Institute of
Technology. This paper presents the findings from a study
undertaken about the complexity of delivering an educational
programme in the face of this traumatic natural event. Nine
interconnected themes emerged from this multiple method study:
communication, decision making, leader- and follower-ship,
balancing personal and professional responsibilities, taking action,
preparedness and thinking ahead, all within a disruptive and uncertain
context. Sustainable responses that maximise business continuity, and
provide solutions to practical challenges, are among the study-s
recommendations.
Abstract: In this investigation, types of commercial and special
polyacrylonitrile (PAN) fibers contain sodium 2-methyl-2-
acrylamidopropane sulfonate (SAMPS) and itaconic acid (IA)
comonomers were studied by fourier transform infrared (FT-IR)
spectroscopy. The study of FT-IR spectra of PAN fibers samples
with different comonomers shows that during stabilization of PAN
fibers, the peaks related to C≡N bonds and CH2 are reduced sharply.
These reductions are related to cyclization of nitrile groups and
stabilization procedure. This reduction in PAN fibers contain IA
comonomer is very intense in comparison with PAN fibers contain
SAMPS comonomer. This fact indicates the cycling and stabilization
for sample contain IA comonomer have been conducted more
completely. Therefore the carbon fibers produced from this material
have higher tensile strength due to suitable stabilization.
Abstract: Over a million tonnes of cigarette butts (CBs) are produced worldwide annually. These CBs accumulate in the environment due to the poor biodegradability of the cellulose acetate filters and pose a serious environmental risk. This paper presents some of the results from a continuing study on recycling CBs into fired clay bricks. Properties including compressive strength, flexural strength, density, water absorption and thermal conductivity of fired clay bricks are reported and discussed. Furthermore, leaching of heavy metals from the manufactured clay bricks was tested. The results show that the density of fired bricks was reduced by about 8 – 30 %, depending on the percentage of CBs incorporated into the raw materials. The compressive strength of bricks tested was 12.57, 5.22 and 3.00 MPa for 2.5, 5.0 and 10 % CB content respectively. Water absorption and initial rate of absorption values increased as density, and hence porosity, of bricks decreased with increasing CB volume. The leaching test results revealed trace amounts of heavy metals.