Abstract: In this study the adsorption of Cu (II) ions from aqueous solutions on synthetic zeolite NaA was evaluated. The effect of solution temperature and the determination of the kinetic parameters of adsorption of Cu(II) from aqueous solution on zeolite NaA is important in understanding the adsorption mechanism. Variables of the system include adsorption time, temperature (293- 328K), initial solution concentration and pH for the system. The sorption kinetics of the copper ions were found to be strongly dependent on pH (the optimum pH 3-5), solute ion concentration and temperature (293 – 328 K). It was found, the pseudo-second-order model was the best choice among all the kinetic models to describe the adsorption behavior of Cu(II) onto ziolite NaA, suggesting that the adsorption mechanism might be a chemisorptions process The activation energy of adsorption (Ea) was determined as Cu(II) 13.5 kJ mol-1. The low value of Ea shows that Cu(II) adsorption process by zeolite NaA may be an activated chemical adsorption. The thermodynamic parameters (ΔG0, ΔH0, and ΔS0) were also determined from the temperature dependence. The results show that the process of adsorption Cu(II) is spontaneous and endothermic process and rise in temperature favors the adsorption.
Abstract: This paper presents a new approach to tackle the problem of recognizing machine-printed Arabic texts. Because of the difficulty of recognizing cursive Arabic words, the text has to be normalized and segmented to be ready for the recognition stage. The new scheme for recognizing Arabic characters depends on multiple parallel neural networks classifier. The classifier has two phases. The first phase categories the input character into one of eight groups. The second phase classifies the character into one of the Arabic character classes in the group. The system achieved high recognition rate.
Abstract: Given that entrepreneurship is a very significant factor of regional development, it is necessary to approach systematically the development with measures of regional politics. According to international classification The Nomenclature of Territorial Units for Statistics (NUTS II), there are three regions in Croatia. The indicators of entrepreneurial activities on the national level of Croatia are analyzed in the paper, taking into consideration the results of referent research. The level of regional development is shown based on the analysis of entrepreneurs- operations. The results of the analysis show a very unfavorable situation in entrepreneurial activities on the national level of Croatia. The origin of this situation is to be found in the surroundings with an expressed inequality of regional development, which is caused by the non-existence of a strategically directed regional policy. In this paper recommendations which could contribute to the reduction of regional inequality in Croatia, have been made.
Abstract: In this paper we present the information life cycle and analyze the importance of managing the corporate application portfolio across this life cycle. The approach presented here corresponds not just to the extension of the traditional information system development life cycle. This approach is based in the generic life cycle. In this paper it is proposed a model of an information system life cycle, supported in the assumption that a system has a limited life. But, this limited life may be extended. This model is also applied in several cases; being reported here two examples of the framework application in a construction enterprise and in a manufacturing enterprise.
Abstract: When architecting an application, key nonfunctional requirements such as performance, scalability, availability and security, which influence the architecture of the system, are some times not adequately addressed. Performance of the application may not be looked at until there is a concern. There are several problems with this reactive approach. If the system does not meet its performance objectives, the application is unlikely to be accepted by the stakeholders. This paper suggests an approach for performance modeling for web based J2EE and .Net applications to address performance issues early in the development life cycle. It also includes a Performance Modeling Case Study, with Proof-of-Concept (PoC) and implementation details for .NET and J2EE platforms.
Abstract: In the present study, a procedure was developed to
determine the optimum reaction rate constants in generalized
Arrhenius form and optimized through the Nelder-Mead method. For
this purpose, a comprehensive mathematical model of a fixed bed
reactor for dehydrogenation of heavy paraffins over Pt–Sn/Al2O3
catalyst was developed. Utilizing appropriate kinetic rate expressions
for the main dehydrogenation reaction as well as side reactions and
catalyst deactivation, a detailed model for the radial flow reactor was
obtained. The reactor model composed of a set of partial differential
equations (PDE), ordinary differential equations (ODE) as well as
algebraic equations all of which were solved numerically to
determine variations in components- concentrations in term of mole
percents as a function of time and reactor radius. It was demonstrated
that most significant variations observed at the entrance of the bed
and the initial olefin production obtained was rather high. The
aforementioned method utilized a direct-search optimization
algorithm along with the numerical solution of the governing
differential equations. The usefulness and validity of the method was
demonstrated by comparing the predicted values of the kinetic
constants using the proposed method with a series of experimental
values reported in the literature for different systems.
Abstract: Recently, bianisotropic media again received
increasing importance in electromagnetic theory because of advances
in material science which enable the manufacturing of complex
bianisotropic materials. By using Maxwell's equations and
corresponding boundary conditions, the electromagnetic field
distribution in bianisotropic solenoid coils is determined and the
influence of the bianisotropic behaviour of coil to the impedance and
Q-factor is considered. Bianisotropic media are the largest class of
linear media which is able to describe the macroscopic material
properties of artificial dielectrics, artificial magnetics, artificial chiral
materials, left-handed materials, metamaterials, and other composite
materials. Several special cases of coils, filled with complex
substance, have been analyzed. Results obtained by using the
analytical approach are compared with values calculated by
numerical methods, especially by our new hybrid EEM/BEM method
and FEM.
Abstract: Guaranteeing the availability of the required parts at
the scheduled time represents a key logistical challenge. This is
especially important when several parts are required together. This
article describes a tool that supports the positioning in the area of
conflict between low stock costs and a high service level for a
consumer.
Abstract: The purpose of this study is to identify the critical success factors (CSFs) for the effective implementation of Six Sigma in non-formal service Sectors.
Based on the survey of literature, the critical success factors (CSFs) for Six Sigma have been identified and are assessed for their importance in Non-formal service sector using Delphi Technique. These selected CSFs were put forth to the panel of expert to cluster them and prepare cognitive map to establish their relationship.
All the critical success factors examined and obtained from the review of literature have been assessed for their importance with respect to their contribution to Six Sigma effectiveness in non formal service sector.
The study is limited to the non-formal service sectors involved in the organization of religious festival only. However, the similar exercise can be conducted for broader sample of other non-formal service sectors like temple/ashram management, religious tours management etc.
The research suggests an approach to identify CSFs of Six Sigma for Non-formal service sector. All the CSFs of the formal service sector will not be applicable to Non-formal services, hence opinion of experts was sought to add or delete the CSFs. In the first round of Delphi, the panel of experts has suggested, two new CSFs-“competitive benchmarking (F19) and resident’s involvement (F28)”, which were added for assessment in the next round of Delphi. One of the CSFs-“fulltime six sigma personnel (F15)” has been omitted in proposed clusters of CSFs for non-formal organization, as it is practically impossible to deploy full time trained Six Sigma recruits.
Abstract: Static synchronous compensator (STATCOM) is a shunt connected voltage source converter (VSC), which can affect rapid control of reactive flow in the transmission line by controlling the generated a.c. voltage. The main aim of the paper is to design a power system installed with a Static synchronous compensator (STATCOM) and demonstrates the application of the linearised Phillips-heffron model in analyzing the damping effect of the STATCOM to improve power system oscillation stability. The proposed PI controller is designed to coordinate two control inputs: Voltage of the injection bus and capacitor voltage of the STATCOM, to improve the Dynamic stability of a SMIB system .The power oscillations damping (POD) control and power system stabilizer (PSS) and their coordinated action with proposed controllers are tested. The simulation result shows that the proposed damping controllers provide satisfactory performance in terms of improvements of dynamic stability of the system.
Abstract: Cryptographic algorithms play a crucial role in the
information society by providing protection from unauthorized
access to sensitive data. It is clear that information technology will
become increasingly pervasive, Hence we can expect the emergence
of ubiquitous or pervasive computing, ambient intelligence. These
new environments and applications will present new security
challenges, and there is no doubt that cryptographic algorithms and
protocols will form a part of the solution. The efficiency of a public
key cryptosystem is mainly measured in computational overheads,
key size and bandwidth. In particular the RSA algorithm is used in
many applications for providing the security. Although the security
of RSA is beyond doubt, the evolution in computing power has
caused a growth in the necessary key length. The fact that most chips
on smart cards can-t process key extending 1024 bit shows that there
is need for alternative. NTRU is such an alternative and it is a
collection of mathematical algorithm based on manipulating lists of
very small integers and polynomials. This allows NTRU to high
speeds with the use of minimal computing power. NTRU (Nth degree
Truncated Polynomial Ring Unit) is the first secure public key
cryptosystem not based on factorization or discrete logarithm
problem. This means that given sufficient computational resources
and time, an adversary, should not be able to break the key. The
multi-party communication and requirement of optimal resource
utilization necessitated the need for the present day demand of
applications that need security enforcement technique .and can be
enhanced with high-end computing. This has promoted us to develop
high-performance NTRU schemes using approaches such as the use
of high-end computing hardware. Peer-to-peer (P2P) or enterprise
grids are proven as one of the approaches for developing high-end
computing systems. By utilizing them one can improve the
performance of NTRU through parallel execution. In this paper we
propose and develop an application for NTRU using enterprise grid
middleware called Alchemi. An analysis and comparison of its
performance for various text files is presented.
Abstract: In this paper, the notion of Hyperbolic Klingenberg
plane is introduced via a set of axioms like as Affine Klingenberg
planes and Projective Klingenberg planes. Models of such planes are
constructed by deleting a certain number m of equivalence classes
of lines from a Projective Klingenberg plane. In the finite case, an
upper bound for m is established and some combinatoric properties
are investigated.
Abstract: In this study the regional stability of a rotor system which is supported on rolling bearings with radial clearance is studied. The rotor is assumed to be rigid. Due to radial clearance of bearings and dynamic configuration of system, each rolling elements of bearings has the possibility to be in contact with both of the races (under compression) or lose its contact. As a result, this change in dynamic of the system makes it to be known as switching system which is a type of Hybrid systems. In this investigation by adopting Multiple Lyapunov Function theorem and using Hamiltonian function as a candidate Lyapunov function, the stability of the system is studied. The purpose of this study is to inspect the regional stability of rotor-roller bearing and rotor-ball bearing systems.
Abstract: Employees commonly encounter unpredictable and
unavoidable work related stressors. Exposure to such stressors can
evoke negative appraisals and associated adverse mental, physical,
and behavioral responses. Because Acceptance and Commitment
Therapy (ACT) emphasizes acceptance of unavoidable stressors and
diffusion from negative appraisals, it may be particularly beneficial
for work stress. Forty-five workers were randomly assigned to an
ACT intervention for work stress (n = 21) or a waitlist control group
(n = 24). The intervention consisted of two 3-hour sessions spaced
one week apart. An examination of group process and outcomes was
conducted using the Revised Sessions Rating Scale. Results indicated
that the ACT participants reported that they perceived the
intervention to be supportive, task focused, and without adverse
therapist behaviors (e.g., feelings of being criticized or discounted).
Additionally, the second session (values clarification and
commitment to action) was perceived to be more supportive and task
focused than the first session (mindfulness, defusion). Process ratings
were correlated with outcomes. Results indicated that perceptions of
therapy supportiveness and task focus were associated with reduced
psychological distress and improved perceived physical health.
Abstract: The aim of present study was to assess the effect of
glucogenic (G) and lipogenic (L) diets on blood metabolites in
Baloochi lambs. Three rumen cannulated Baloochi sheep were used
as a 3×3 Latin square design with 3 periods (28 days). Experimental
diets were a glucogenic, a lipogenic and a mixture of G and L diets
(50:50). The animals were fed diets consisted of 50% chopped alfalfa
hay and 50% concentrate. Diets were fed once daily ad libitum.
Blood samples were taken from jugular vein before the feeding, 2, 4
and 6 hour post feeding at day 27. Results indicated that β-
hydroxybutyrate (BHBA), glucose, insulin and aspartate
aminotransferase (AST) were not affected by treatments (P > 0.05).
However, lipogenic diet increased significantly activity of Alanine
aminotransferase (ALT) and concentration of non-esterified fatty acid
(NEFA) in blood plasma (P < 0.05)
Abstract: Hemodialysis patients might suffer from unhealthy
care behaviors or long-term dialysis treatments. Ultimately they need
to be hospitalized. If the hospitalization rate of a hemodialysis center
is high, its quality of service would be low. Therefore, how to decrease
hospitalization rate is a crucial problem for health care. In this study
we combined temporal abstraction with data mining techniques for
analyzing the dialysis patients' biochemical data to develop a decision
support system. The mined temporal patterns are helpful for clinicians
to predict hospitalization of hemodialysis patients and to suggest them
some treatments immediately to avoid hospitalization.
Abstract: Groundwater is an essential and vital component of our life support system. The groundwater resources are being utilized for drinking, irrigation and industrial purposes. There is growing concern on deterioration of groundwater quality due to geogenic and anthropogenic activities. Groundwater, being a fragile must be carefully managed to maintain its purity within standard limits. So, quality assessment and management are to be carried out hand-in-hand to have a pollution free environment and for a sustainable use. In order to assess the quality for consumption by human beings and for use in agriculture, the groundwater from the shallow aquifers (dug well) in the Palakkad and Chittur taluks of Bharathapuzha river basin - a paddy dominated agricultural basin (order=8th; L= 209 Km; Area = 6186 Km2), Kerala, India, has been selected. The water samples (n= 120) collected for various seasons, viz., monsoon-MON (August, 2005), postmonsoon-POM (December, 2005) and premonsoon-PRM (April, 2006), were analyzed for important physico-chemical attributes. Spatial and temporal variation of attributes do exist in the study area, and based on major cations and anions, different hydrochemical facies have been identified. Using Gibbs'diagram, rock dominance has been identified as the mechanism controlling groundwater chemistry. Further, the suitability of water for irrigation was determined by analyzing salinity hazard indicated by sodium adsorption ratio (SAR), residual sodium carbonate (RSC) and sodium percent (%Na). Finally, stress zones in the study area were delineated using Arc GIS spatial analysis and various management options were recommended to restore the ecosystem.
Abstract: The article deals with the relation between rainfall in selected months and subsequent weed infestation of spring barley. The field experiment was performed at Mendel University agricultural enterprise in Žabčice, Czech Republic. Weed infestation was measured in spring barley vegetation in years 2004 to 2012. Barley was grown in three tillage variants: conventional tillage technology (CT), minimization tillage technology (MT), and no tillage (NT). Precipitation was recorded in one-day intervals. Monthly precipitation was calculated from the measured values in the months of October through to April. The technique of canonical correspondence analysis was applied for further statistical processing. 41 different species of weeds were found in the course of the 9-year monitoring period. The results clearly show that precipitation affects the incidence of most weed species in the selected months, but acts differently in the monitored variants of tillage technologies.
Abstract: In this study, production possibilities of hydrogen and/or methane via SCWG from black grape residues have been investigated. For this aim, grape residues which remain as a byproduct of the wine making process have been used. Since utilization from grape residues is limited due to the high moisture content, supercritical water gasification is the most convenient method. The effect of the gasification temperature and type of catalyst on supercritical water gasification have been investigated. Gasification experiments were performed in a batch autoclave at four different temperatures 300, 400, 500 and 600°C. K2CO3 and Trona (NaHCO3.Na2CO3·2H2O) were used as catalyst. Real biomass types of black grape residues have been successfully gasified and the product gas (hydrogen, methane, carbon dioxide, carbon monoxide and a small amount of ethane and ethylene) were identified by using gas chromatography. A TOC analyzer was used to determine total organic carbon (TOC) content of aqueous phase. The amounts of carboxylic acids, aldehydes, ketones, furfurals and phenols present in the aqueous solutions were analyzed by high performance liquid chromatography. When the temperature increased from 300°C to 600°C, mol% of H2 in gas products increased. The presence of catalysts improves the hydrogen yield. Trona showed gasification activity to be similar to that of K2CO3. It may be concluded that the use of Trona instead of commercially produced catalysts, can be preferably used in the gasification of biomass in supercritical water.
Abstract: Burnishing is a method of finishing and hardening
machined parts by plastic deformation of the surface. Experimental
work based on central composite second order rotatable design has
been carried out on a lathe machine to establish the effects of ball
burnishing parameters on the surface roughness of brass material.
Analysis of the results by the analysis of variance technique and the
F-test show that the parameters considered, have significant effects
on the surface roughness.