Abstract: Coal tar is a liquid by-product of coal pyrolysis
processes. This liquid oil mixture contains various kinds of useful
compounds such as benzoic aromatic compounds and phenolic
compounds. These compounds are widely used as raw material for
insecticides, dyes, medicines, perfumes, coloring matters, and many
others. The coal tar was collected by pyrolysis process of coal
obtained from PT Kaltim Prima Coal and Arutmin-Kalimantan. The
experiments typically occurred at the atmospheric pressure in a
laboratory furnace at temperatures ranging from 300 to 550oC with a
heating rate of 10oC/min and a holding time of 1 hour at the pyrolysis
temperature. The Gas Chromatography-Mass Spectroscopy (GC-MS)
was used to analyze the coal tar components. The obtained coal tar
has the viscosity of 3.12 cp, the density of 2.78 g/cm3, the calorific
value of 11,048.44 cal/g, and the molecular weight of 222.67. The
analysis result showed that the coal tar contained more than 78
chemical compounds such as benzene, cresol, phenol, xylene,
naphtalene, etc. The total phenolic compounds contained in coal tar
are 33.25% (PT KPC) and 17.58% (Arutmin-Kalimantan). The total
naphtalene compounds contained in coal tar is 14.15% (PT KPC) and
17.13% (Arutmin-Kalimantan).
Abstract: In this study, a multi objective optimization for end
milling of Al 6061 alloy has been presented to provide better
surface quality and higher Material Removal Rate (MRR). The input
parameters considered for the analysis are spindle speed, depth of cut
and feed. The experiments were planned as per Taguchis design of
experiment, with L27 orthogonal array. The Grey Relational Analysis
(GRA) has been used for transforming multiple quality responses
into a single response and the weights of the each performance
characteristics are determined by employing the Principal Component
Analysis (PCA), so that their relative importance can be properly and
objectively described. The results reveal that Taguchi based G-PCA
can effectively acquire the optimal combination of cutting parameters.
Abstract: Life cycle assessment is a technique to assess the
environmental aspects and potential impacts associated with a
product, process, or service, by compiling an inventory of relevant
energy and material inputs and environmental releases; evaluating the
potential environmental impacts associated with identified inputs and
releases; and interpreting the results to help you make a more
informed decision. In this paper, the life cycle assessment of
aluminum and beech wood as two commonly used materials in Egypt
for window frames are heading, highlighting their benefits and
weaknesses. Window frames of the two materials have been assessed
on the basis of their production, energy consumption and
environmental impacts. It has been found that the climate change of
the windows made of aluminum and beech wood window, for a
reference window (1.2m×1.2m), are 81.7 mPt and -52.5 mPt impacts
respectively. Among the most important results are: fossil fuel
consumption, potential contributions to the green building effect and
quantities of solid waste tend to be minor for wood products
compared to aluminum products; incineration of wood products can
cause higher impacts of acidification and eutrophication than
aluminum, whereas thermal energy can be recovered.
Abstract: Drying is a phenomenon that accompanies the
hardening of hydraulic materials. This study is concerned the
modelling of drying shrinkage of the hydraulic materials and the
prediction of the rate of spontaneous deformations of hydraulic
materials during hardening. The model developed takes consideration
of the main factors affecting drying shrinkage. There was agreement
between drying shrinkage predicted by the developed model and
experimental results. In last we show that developed model describe
the evolution of the drying shrinkage of high performances concretes
correctly.
Abstract: Biodiesel is one of the alternative fuels that promising
for substituting petro diesel as energy source which is advantage on
sustainability and ecofriendly. Due to the raw material that tend to
decompose during storage, biodiesel also have the same characteristic
that tend to decompose and formed higher acid value which is the
result of oxidation to double bond on a chain of ester. Decomposition of biodiesel due to oxidation reaction could
prevent by introduce a small amount of antioxidant. The origin of raw
materials and the process for producing biodiesel will determine the
effectiveness of antioxidant. The quality degradation on biodiesel
could evaluate by measuring iodine value and acid number of
biodiesel. Biodiesel made from high fatty acid Jatropha curcas oil by using
esterification and transesterification process will stand on the quality
by introduce 90 ppm pyrogallol powder on the biodiesel, which could
increase Induction period time from 2 hours to more than 6 hours in
rancimat test evaluation.
Abstract: The Composite Shear Walls (CSW) with steel encased
profiles can be used as lateral-load resisting systems for buildings
that require considerable large lateral-load capacity. The aim of this
work is to propose the experimental work conducted on CSW having
L section folded plate (L shape steel made-up sections) as
longitudinal reinforcement in boundary regions. The study in this
paper present the experimental test conducted on CSW having L
section folded plate as longitudinal reinforcement in boundary
regions. The tested 1/3 geometric scaled CSW has aspect ratio of 3.2.
L-shape structural steel materials with 2L-19x57x7mm dimensions
were placed in shear wall boundary zones. The seismic behavior of
CSW test specimen was investigated by evaluating and interpreting
the hysteresis curves, envelope curves, rigidity and consumed energy
graphs of this tested element. In addition to this, the experimental
results, deformation and cracking patterns were evaluated, interpreted
and suggestions of the design recommendations were proposed.
Abstract: The use of engineered nanomaterials has increased as
a result of their positive impact on many sectors of the economy,
including agriculture. Silver nanoparticles (AgNPs) are now used to
enhance seed germination, plant growth, and photosynthetic quantum
efficiency and as antimicrobial agents to control plant diseases. In
this study, we examined the effect of AgNP dosage on the seed
germination of three plant species: corn (Zea mays L.), watermelon
(Citrullus lanatus [Thunb.] Matsum. & Nakai) and zucchini
(Cucurbita pepo L.). This experiment was designed to study the
effect of AgNPs on germination percentage, germination rate, mean
germination time, root length and fresh and dry weight of seedlings
for the three species. Seven concentrations (0.05, 0.1, 0.5, 1, 1.5, 2
and 2.5 mg/ml) of AgNPs were examined at the seed germination
stage. The three species had different dose responses to AgNPs in
terms of germination parameters and the measured growth
characteristics. The germination rates of the three plants were
enhanced in response to AgNPs. Significant enhancement of the
germination percentage values was observed after treatment of the
watermelon and zucchini plants with AgNPs in comparison with
untreated seeds. AgNPs showed a toxic effect on corn root
elongation, whereas watermelon and zucchini seedling growth were
positively affected by certain concentrations of AgNPs. This study
showed that exposure to AgNPs caused both positive and negative
effects on plant growth and germination.
Abstract: Typical load-bearing biological materials like bone,
mineralized tendon and shell, are biocomposites made from both
organic (collagen) and inorganic (biomineral) materials. This
amazing class of materials with intrinsic internally designed
hierarchical structures show superior mechanical properties with
regard to their weak components from which they are formed.
Extensive investigations concentrating on static loading conditions
have been done to study the biological materials failure. However,
most of the damage and failure mechanisms in load-bearing
biological materials will occur whenever their structures are exposed
to dynamic loading conditions. The main question needed to be
answered here is: What is the relation between the layout and
architecture of the load-bearing biological materials and their
dynamic behavior? In this work, a staggered model has been
developed based on the structure of natural materials at nanoscale and
Finite Element Analysis (FEA) has been used to study the dynamic
behavior of the structure of load-bearing biological materials to
answer why the staggered arrangement has been selected by nature to
make the nanocomposite structure of most of the biological materials.
The results showed that the staggered structures will efficiently
attenuate the stress wave rather than the layered structure.
Furthermore, such staggered architecture is effectively in charge of
utilizing the capacity of the biostructure to resist both normal and
shear loads. In this work, the geometrical parameters of the model
like the thickness and aspect ratio of the mineral inclusions selected
from the typical range of the experimentally observed feature sizes
and layout dimensions of the biological materials such as bone and
mineralized tendon. Furthermore, the numerical results validated with
existing theoretical solutions. Findings of the present work emphasize
on the significant effects of dynamic behavior on the natural
evolution of load-bearing biological materials and can help scientists
to design bioinspired materials in the laboratories.
Abstract: Ceramic Waste Aggregates (CWAs) were made from
electric porcelain insulator wastes supplied from an electric power
company, which were crushed and ground to fine aggregate sizes. In
this study, to develop the CWA mortar as an eco–efficient, ground
granulated blast–furnace slag (GGBS) as a Supplementary
Cementitious Material (SCM) was incorporated. The water–to–binder
ratio (W/B) of the CWA mortars was varied at 0.4, 0.5, and 0.6. The
cement of the CWA mortar was replaced by GGBS at 20 and 40% by
volume (at about 18 and 37% by weight). Mechanical properties of
compressive and splitting tensile strengths, and elastic modulus were
evaluated at the age of 7, 28, and 91 days. Moreover, the chloride
ingress test was carried out on the CWA mortars in a 5.0% NaCl
solution for 48 weeks. The chloride diffusion was assessed by using an
electron probe microanalysis (EPMA). To consider the relation of the
apparent chloride diffusion coefficient and the pore size, the pore size
distribution test was also performed using a mercury intrusion
porosimetry at the same time with the EPMA. The compressive
strength of the CWA mortars with the GGBS was higher than that
without the GGBS at the age of 28 and 91 days. The resistance to the
chloride ingress of the CWA mortar was effective in proportion to the
GGBS replacement level.
Abstract: A bauxite ore can be utilized in Bayer Process, if the
mass ratio of Al2O3 to SiO2 is greater than 10. Otherwise, its FexOy
and SiO2 content should be removed. On the other hand, removal of
TiO2 from the bauxite ore would be beneficial because of both
lowering the red mud residue and obtaining a valuable raw material
containing TiO2 mineral. In this study, the low grade diasporic
bauxite ore of Yalvaç, Isparta, Turkey was roasted under reducing
atmosphere and subjected to magnetic separation. According to the
experimental results, 800°C for reduction temperature and 20000
Gauss of magnetic intensity were found to be the optimum
parameters for removal of iron oxide and rutile from the nonmagnetic
ore. On the other hand, 600°C and 5000 Gauss were
determined to be the optimum parameters for removal of silica from
the non-magnetic ore.
Abstract: In this paper, the specific sound Transmission Loss
(TL) of the Laminated Composite Plate (LCP) with different material
properties in each layer is investigated. The numerical method to
obtain the TL of the LCP is proposed by using elastic plate theory. The
transfer matrix approach is novelty presented for computational
efficiency in solving the numerous layers of dynamic stiffness matrix
(D-matrix) of the LCP. Besides the numerical simulations for
calculating the TL of the LCP, the material properties inverse method
is presented for the design of a laminated composite plate analogous to
a metallic plate with a specified TL. As a result, it demonstrates that
the proposed computational algorithm exhibits high efficiency with a
small number of iterations for achieving the goal. This method can be
effectively employed to design and develop tailor-made materials for
various applications.
Abstract: Superabsorbent polymers received much attention and
are used in many fields because of their superior characters to
traditional absorbents, e.g., sponge and cotton. So, it is very
important but challenging to prepare highly and fast-swelling
superabsorbents. A reliable, efficient and low-cost technique for
removing heavy metal ions from wastewater is the adsorption using
bio-adsorbents obtained from biological materials, such as
polysaccharides-based hydrogels superabsorbents. In this study, novel multi-functional superabsorbent composites
type semi-interpenetrating polymer networks (Semi-IPNs) were
prepared via graft polymerization of acrylamide onto chitosan
backbone in presence of gelatin, CTS-g-PAAm/Ge, using potassium
persulfate and N,N’-methylene bisacrylamide as initiator and
crosslinker, respectively. These hydrogels were also partially
hydrolyzed to achieve superabsorbents with ampholytic properties
and uppermost swelling capacity. The formation of the grafted
network was evidenced by Fourier Transform Infrared Spectroscopy
(ATR-FTIR) and Thermogravimetric Analysis (TGA). The porous
structures were observed by Scanning Electron Microscope (SEM).
From TGA analysis, it was concluded that the incorporation of the Ge
in the CTS-g-PAAm network has marginally affected its thermal
stability. The effect of gelatin content on the swelling capacities of
these superabsorbent composites was examined in various media
(distilled water, saline and pH-solutions). The water absorbency was
enhanced by adding Ge in the network, where the optimum value was
reached at 2 wt. % of Ge. Their hydrolysis has not only greatly
optimized their absorption capacity but also improved the swelling
kinetic.These materials have also showed reswelling ability. We
believe that these super-absorbing materials would be very effective
for the adsorption of harmful metal ions from wastewater.
Abstract: Processing of Al-19.4Si alloy by high intensive
electron beam has been carried out and multiple increases in fatigue
life of the material have been revealed. Investigations of structure and
surface modified layer destruction of Al-19.4Si alloy subjected to
multicycle fatigue tests to fracture have been carried out by methods
of scanning electron microscopy. The factors responsible for the
increase of fatigue life of Al-19.4Si alloy have been revealed and
analyzed.
Abstract: Background: The change in foot posture can possibly
generate changes in the pelvic alignment. There is still a lack of
evidence about the effects of bilateral and unilateral flatfoot on
possible changes in pelvic alignment. The purpose of this study was
to investigate the effect of flatfoot on the sagittal and frontal planes of
pelvic postures. Materials and Methods: 56 subjects, aged 18–40
years, were assigned into three groups: 20 healthy subjects, 19
subjects with bilateral flexible second-degree flat foot, and 17
subjects with unilateral flexible second-degree flat foot. 3D
assessment of the pelvis using the formetric-II device was used to
evaluate pelvic alignment in the frontal and sagittal planes by
measuring pelvic inclination and pelvic tilt angles. Results: ANOVA
test with LSD test were used for statistical analysis. Both Unilateral
and bilateral second degree flatfoot produced significant (P
Abstract: In present global scenario, aluminum alloys are
coining the attention of many innovators as competing structural
materials for automotive and space applications. Comparing to other
challenging alloys, especially, 7xxx series aluminum alloys have
been studied seriously because of benefits such as moderate strength;
better deforming characteristics and affordable cost. It is expected
that substitution of aluminum alloys for steels will result in great
improvements in energy economy, durability and recyclability.
However, it is necessary to improve the strength and the formability
levels at low temperatures in aluminum alloys for still better
applications. Aluminum–Zinc–Magnesium with or without other
wetting agent denoted as 7XXX series alloys are medium strength
heat treatable alloys. In addition to Zn, Mg as major alloying
additions, Cu, Mn and Si are the other solute elements which
contribute for the improvement in mechanical properties by suitable
heat treatment process. Subjecting to suitable treatments like age
hardening or cold deformation assisted heat treatments; known as low
temperature thermomechanical treatments (LTMT) the challenging
properties might be incorporated. T6 is the age hardening or
precipitation hardening process with artificial aging cycle whereas T8
comprises of LTMT treatment aged artificially with X% cold
deformation. When the cold deformation is provided after solution
treatment, there is increase in hardness related properties such as
wear resistance, yield and ultimate strength, toughness with the
expense of ductility. During precipitation hardening both hardness
and strength of the samples are increasing. The hardness value may
further improve when room temperature deformation is positively
supported with age hardening known as thermomechanical treatment.
It is intended to perform heat treatment and evaluate hardness, tensile
strength, wear resistance and distribution pattern of reinforcement in
the matrix. 2 to 2.5 and 3 to 3.5 times increase in hardness is reported
in age hardening and LTMT treatments respectively as compared to
as-cast composite. There was better distribution of reinforcements in
the matrix, nearly two fold increase in strength levels and up to 5
times increase in wear resistance are also observed in the present
study.
Abstract: Single angle connections, which are bolted to the beam
web and the column flange, are studied to investigate their
moment-rotation behavior. Elastic–perfectly plastic material behavior
is assumed. ABAQUS software is used to analyze the nonlinear
behavior of a single angle connection. The identical geometric and
material conditions with Lipson’s test are used for verifying finite
element models. Since Kishi and Chen’s Power model and Lee and
Moon’s Log model are accurate only for a limited range of mechanism,
simpler and more accurate hyperbolic function models are proposed.
Abstract: This paper aims to project the construction of a
prototype azimuthal thruster, mounted with materials of low cost and
easy access, testing in a controlled environment to measure their
performance, characteristics and feasibility of future projects. The
construction of the simulation of dynamic positioning software,
responsible for simulating a vessel and reposition it when necessary.
Validation tests were performed in the form of partial or complete
system. These tests validate the system manually or automatically.
The system provides an interface to the user and simulates the
conditions unfavorable positioning of a vessel, accurately calculates
the azimuth angle, the direction of rotation of the helix and the time
that this should be turned on so that the vessel back to position
original. A serial communication connects the Simulation Dynamic
Positioning System with Embedded System causing the usergenerated
data to simulate the DP system arrives in the form of
control signals to the motors of the propellant. This article addresses
issues in the marine industry employees.
Abstract: The using of waste materials in the construction
industry can reduce the dependence on the natural aggregates which
are going at the end to deplete. The glass waste is generated in a huge
amount which can make one of its disposals in concrete industry
effective not only as a green solution but also as an advantage to
enhance the performance of mechanical properties and durability of
concrete. This article reports the performance of concrete specimens
containing different percentages of milled glass waste as a partial
replacement of cement (Powder), when they are subject to cycles of
freezing and thawing. The tests were conducted on 75-mm cubes and
75 x 75 x 300-mm prisms. Compressive strength based on laboratory
testing and non-destructive ultrasonic pulse velocity test were
performed during the action of freezing-thawing cycles (F/T). The
results revealed that the incorporation of glass waste in concrete
mixtures is not only feasible but also showed generally better strength
and durability performance than control concrete mixture. It may be
said that the recycling of waste glass in concrete mixes is not only a
disposal way, but also it can be an exploitation in concrete industry.
Abstract: Greenhouses offer us suitable conditions which can
be controlled easily for the growth of the plant and they are made by
using a covering material that allows the sun light entering into the
system. Covering material can be glass, fiber glass, plastic or another
transparent element. This study investigates the solar energy usability
rates and solar energy benefitting rates of a semi-spherical (modified
arch) type greenhouse system according to different orientations and
positions which exists under climatic conditions of Bayburt. In the
concept of this study it is tried to determine the best direction and
best sizes of a semi-spherical greenhouse to get best solar benefit
from the sun. To achieve this aim a modeling study is made by using
MATLAB. However, this modeling study is run for some determined
shapes and greenhouses it can be used for different shaped
greenhouses or buildings. The basic parameters are determined as
greenhouse azimuth angle, the rate of size of long edge to short and
seasonal solar energy gaining of greenhouse. The optimum azimuth
angles of 400, 300, 250, 200, 150, 100, 50 m2 modified arch
greenhouse are 90o, 90o, 35o, 35o, 34o, 33o and 22o while their
optimum k values (ratio of length to width) are 10, 10, 10, 10, 6, 4
and 4 respectively. Positioning the buildings in order to get more
solar heat energy in winter and less in summer brings out energy and
money savings and increases the comfort.
Abstract: Cemented carbides, owing to their excellent
mechanical properties, have been of immense interest in the field of
hard materials for the past few decades. A number of processing
techniques have been developed to obtain high quality carbide tools,
with a wide range of grain size depending on the application and
requirements. Microwave sintering is one of the heating processes,
which has been used to prepare a wide range of materials including
ceramics. A deep understanding of microwave sintering and its
contribution towards control of grain growth and on deformation of
the resulting carbide materials requires further studies and attention.
In addition, the effect of binder materials and their behavior during
microwave sintering is another area that requires clear understanding.
This review aims to focus on microwave sintering, providing
information of how the process works and what type of materials it is
best suited for. In addition, a closer look at some microwave sintered
Tungsten Carbide-Cobalt samples will be taken and discussed,
highlighting some of the key issues and challenges faced in this
research area.