Abstract: Zirconium diamine and triamine complexes can possess biological activities. These complexes were synthesised via the reaction of equimolar quantities of 1,10-phenanthroline {NC3H3(C6H2)NC3H3} (L1) or 4-4-amino phenazone {ONC6H5(NH)CH(NH2} (L2) or diphenyl carbizon {HNNCO(NH)2(C6H5)} (L3) with a Zirconium Salt {ZrOCl2} in a 1:1 ratio to form complexes [{NC3H3(C6H2)NC3H3}ZrOCl2}] [ZrOCl2L1], [{(O2NC6H4(NH)(NH2)}ZrOCl2] [ZrOCl2L2] and [{HNNCO(NH)2(C6H5)ZrOCl2}] [ZrOCl2L3] respectively. They were characterised using Fourier Transform Infrared (FT-IR) and UV-Visible spectroscopy. Also a variable temperature study of these complexes was completed, using UV-Visible spectroscopy to observe electronic transitions under temperature control. Also a DFT study was done on these complexes via the information from FT-IR and UV-Visible spectroscopy.
These complexes were found to show different inhibition to the growth of bacterial strains of Bacillus spp. & Klebsiella spp. & E. coli & Proteus spp. & Pseudomona spp. at different concentrations (0.001, 0.2 and 1M). For better understanding these complexes were examined by using a Density Functional Theory (DFT) calculation.
Abstract: This paper argues that fostering mutual understanding in landscape planning is as much about the planners educating stakeholder groups as the stakeholders educating the planners. In other words it is an epistemological agreement as to the meaning and nature of place, especially where an effort is made to go beyond the quantitative aspects, which can be achieved by the phenomenological experience of the Virtual Reality (VR) environment. This education needs to be a bi-directional process in which distance can be both temporal as well as spatial separation of participants, that there needs to be a common framework of understanding in which neither 'side' is disadvantaged during the process of information exchange and it follows that a medium such as VR offers an effective way of overcoming some of the shortcomings of traditional media by taking advantage of continuing technological advances in Information, Technology and Communications (ITC). In this paper we make particular reference to this as an extension to Geographical Information Systems (GIS). VR as a two-way communication tool offers considerable potential particularly in the area of Public Participation GIS (PPGIS). Information rich virtual environments that can operate over broadband networks are now possible and thus allow for the representation of large amounts of qualitative and quantitative information 'side-by-side'. Therefore, with broadband access becoming standard for households and enterprises alike, distributed virtual reality environments have great potential to contribute to enabling stakeholder participation and mutual learning within the planning context.
Abstract: The purpose of the article is to illustrate the main
characteristics of the corporate governance challenge facing the
countries of South-Eastern Europe (SEE) and to subsequently
determine and assess the extensiveness and effectiveness of corporate
governance regulations in these countries. Therefore, we start with an
overview on the subject of the key problems of corporate governance
in transition. We then address the issue of corporate governance
measurement for SEE countries. To this end, we include a review of
the methodological framework for determining both the
extensiveness and the effectiveness of corporate governance
legislation. We then focus on the actual analysis of the quality of
corporate governance codes, as well as of legal institutions
effectiveness and provide a measure of corporate governance in
Romania and other SEE emerging markets. The paper concludes by
emphasizing the corporate governance enforcement gap and by
identifying research issues that require further study.
Abstract: A direct adaptive controller for a class of unknown nonlinear discrete-time systems is presented in this article. The proposed controller is constructed by fuzzy rules emulated network (FREN). With its simple structure, the human knowledge about the plant is transferred to be if-then rules for setting the network. These adjustable parameters inside FREN are tuned by the learning mechanism with time varying step size or learning rate. The variation of learning rate is introduced by main theorem to improve the system performance and stabilization. Furthermore, the boundary of adjustable parameters is guaranteed through the on-line learning and membership functions properties. The validation of the theoretical findings is represented by some illustrated examples.
Abstract: Cytogenetic analysis still remains the gold standard method for prenatal diagnosis of trisomy 21 (Down syndrome, DS). Nevertheless, the conventional cytogenetic analysis needs live cultured cells and is too time-consuming for clinical application. In contrast, molecular methods such as FISH, QF-PCR, MLPA and quantitative Real-time PCR are rapid assays with results available in 24h. In the present study, we have successfully used a novel MGB TaqMan probe-based real time PCR assay for rapid diagnosis of trisomy 21 status in Down syndrome samples. We have also compared the results of this molecular method with corresponding results obtained by the cytogenetic analysis. Blood samples obtained from DS patients (n=25) and normal controls (n=20) were tested by quantitative Real-time PCR in parallel to standard G-banding analysis. Genomic DNA was extracted from peripheral blood lymphocytes. A high precision TaqMan probe quantitative Real-time PCR assay was developed to determine the gene dosage of DSCAM (target gene on 21q22.2) relative to PMP22 (reference gene on 17p11.2). The DSCAM/PMP22 ratio was calculated according to the formula; ratio=2 -ΔΔCT. The quantitative Real-time PCR was able to distinguish between trisomy 21 samples and normal controls with the gene ratios of 1.49±0.13 and 1.03±0.04 respectively (p value
Abstract: In this paper, a new learning algorithm based on a
hybrid metaheuristic integrating Differential Evolution (DE) and
Reduced Variable Neighborhood Search (RVNS) is introduced to train
the classification method PROAFTN. To apply PROAFTN, values of
several parameters need to be determined prior to classification. These
parameters include boundaries of intervals and relative weights for
each attribute. Based on these requirements, the hybrid approach,
named DEPRO-RVNS, is presented in this study. In some cases, the
major problem when applying DE to some classification problems
was the premature convergence of some individuals to local optima.
To eliminate this shortcoming and to improve the exploration and
exploitation capabilities of DE, such individuals were set to iteratively
re-explored using RVNS. Based on the generated results on
both training and testing data, it is shown that the performance of
PROAFTN is significantly improved. Furthermore, the experimental
study shows that DEPRO-RVNS outperforms well-known machine
learning classifiers in a variety of problems.
Abstract: Morphogenesis is the process that underpins the selforganised development and regeneration of biological systems. The ability to mimick morphogenesis in artificial systems has great potential for many engineering applications, including production of biological tissue, design of robust electronic systems and the co-ordination of parallel computing. Previous attempts to mimick these complex dynamics within artificial systems have relied upon the use of evolutionary algorithms that have limited their size and complexity. This paper will present some insight into the underlying dynamics of morphogenesis, then show how to, without the assistance of evolutionary algorithms, design cellular architectures that converge to complex patterns.
Abstract: This work presents a new approach of securing a
wireless network. The configuration is focused on securing &
Protecting wireless network traffic for a small network such as a
home or dorm room. The security Mechanism provided both
authentication, allowing only known authorized users access to the
wireless network, and encryption, preventing anyone from reading
the wireless traffic. The mentioned solution utilizes the open source
free S/WAN software which implements the Internet Protocol
Security –IPSEC. In addition to wireless components, wireless NIC
in PC and wireless access point needs a machine running Linux to act
as security gateway. While the current configuration assumes that the
wireless PC clients are running Linux, Windows XP/VISTA/7 based
machines equipped with VPN software which will allow to interface
with this configuration.
Abstract: Adsorption of CS2 vapors has been studied on
different types of activated carbons obtained from different source
raw materials. The activated carbons have different surface areas and
are associated with varying amounts of the carbon-oxygen surface
groups. The adsorption of CS2 vapors is not directly related to surface
area, but is considerably influenced by the presence of carbonoxygen
surface groups. The adsorption decreases on increasing the
amount of carbon-oxygen surface groups on oxidation and increases
when these surface groups are eliminated on degassing. The
adsorption is maximum in case of the 950°-degassed carbon sample
which is almost completely free of any associated oxygen. The
kinetic data as analysed by Empirical diffusion model and Linear
driving force mass transfer model indicate that the adsorption does
not involve Fickian diffusion but may be considered as a pseudo first
order mass transfer process. The activation energy of adsorption and
isosteric enthalpies of adsorption indicate that the adsorption does not
involve interaction between CS2 and carbon-oxygen surface groups,
but hydrophobic interactions between CS2 and C-C atoms in the
carbon lattice.
Abstract: A dynamic of Bertrand duopoly game is analyzed, where players use different production methods and choose their prices with bounded rationality. The equilibriums of the corresponding discrete dynamical systems are investigated. The stability conditions of Nash equilibrium under a local adjustment process are studied. The stability conditions of Nash equilibrium under a local adjustment process are studied. The stability of Nash equilibrium, as some parameters of the model are varied, gives rise to complex dynamics such as cycles of higher order and chaos. On this basis, we discover that an increase of adjustment speed of bounded rational player can make Bertrand market sink into the chaotic state. Finally, the complex dynamics, bifurcations and chaos are displayed by numerical simulation.
Abstract: Medical image segmentation based on image smoothing followed by edge detection assumes a great degree of importance in the field of Image Processing. In this regard, this paper proposes a novel algorithm for medical image segmentation based on vigorous smoothening by identifying the type of noise and edge diction ideology which seems to be a boom in medical image diagnosis. The main objective of this algorithm is to consider a particular medical image as input and make the preprocessing to remove the noise content by employing suitable filter after identifying the type of noise and finally carrying out edge detection for image segmentation. The algorithm consists of three parts. First, identifying the type of noise present in the medical image as additive, multiplicative or impulsive by analysis of local histograms and denoising it by employing Median, Gaussian or Frost filter. Second, edge detection of the filtered medical image is carried out using Canny edge detection technique. And third part is about the segmentation of edge detected medical image by the method of Normalized Cut Eigen Vectors. The method is validated through experiments on real images. The proposed algorithm has been simulated on MATLAB platform. The results obtained by the simulation shows that the proposed algorithm is very effective which can deal with low quality or marginal vague images which has high spatial redundancy, low contrast and biggish noise, and has a potential of certain practical use of medical image diagnosis.
Abstract: Consider a mass production of HDD arms where
hundreds of CNC machines are used to manufacturer the HDD arms.
According to an overwhelming number of machines and models of
arm, construction of separate control chart for monitoring each HDD
arm model by each machine is not feasible. This research proposed a
strategy to optimize the SPC management on shop floor. The
procedure started from identifying the clusters of the machine with
similar manufacturing performance using clustering technique. The
three way control chart ( I - MR - R ) is then applied to each
clustered group of machine. This proposed research has
advantageous to the manufacturer in terms of not only better
performance of the SPC but also the quality management paradigm.
Abstract: As a method of expanding a higher-order tensor data to tensor products of vectors we have proposed the Third-order Orthogonal Tensor Product Expansion (3OTPE) that did similar expansion as Higher-Order Singular Value Decomposition (HOSVD). In this paper we provide a computation algorithm to improve our previous method, in which SVD is applied to the matrix that constituted by the contraction of original tensor data and one of the expansion vector obtained. The residual of the improved method is smaller than the previous method, truncating the expanding tensor products to the same number of terms. Moreover, the residual is smaller than HOSVD when applying to color image data. It is able to be confirmed that the computing time of improved method is the same as the previous method and considerably better than HOSVD.
Abstract: AAM has been successfully applied to face alignment,
but its performance is very sensitive to initial values. In case the initial
values are a little far distant from the global optimum values, there
exists a pretty good possibility that AAM-based face alignment may
converge to a local minimum. In this paper, we propose a progressive
AAM-based face alignment algorithm which first finds the feature
parameter vector fitting the inner facial feature points of the face and
later localize the feature points of the whole face using the first
information. The proposed progressive AAM-based face alignment
algorithm utilizes the fact that the feature points of the inner part of the
face are less variant and less affected by the background surrounding
the face than those of the outer part (like the chin contour). The
proposed algorithm consists of two stages: modeling and relation
derivation stage and fitting stage. Modeling and relation derivation
stage first needs to construct two AAM models: the inner face AAM
model and the whole face AAM model and then derive relation matrix
between the inner face AAM parameter vector and the whole face
AAM model parameter vector. In the fitting stage, the proposed
algorithm aligns face progressively through two phases. In the first
phase, the proposed algorithm will find the feature parameter vector
fitting the inner facial AAM model into a new input face image, and
then in the second phase it localizes the whole facial feature points of
the new input face image based on the whole face AAM model using
the initial parameter vector estimated from using the inner feature
parameter vector obtained in the first phase and the relation matrix
obtained in the first stage. Through experiments, it is verified that the
proposed progressive AAM-based face alignment algorithm is more
robust with respect to pose, illumination, and face background than the
conventional basic AAM-based face alignment algorithm.
Abstract: In this work we present an efficient approach for face
recognition in the infrared spectrum. In the proposed approach
physiological features are extracted from thermal images in order to
build a unique thermal faceprint. Then, a distance transform is used
to get an invariant representation for face recognition. The obtained
physiological features are related to the distribution of blood vessels
under the face skin. This blood network is unique to each individual
and can be used in infrared face recognition. The obtained results are
promising and show the effectiveness of the proposed scheme.
Abstract: In this study, a fuzzy integrated logical forecasting method (FILF) is extended for multi-variate systems by using a vector autoregressive model. Fuzzy time series forecasting (FTSF) method was recently introduced by Song and Chissom [1]-[2] after that Chen improved the FTSF method. Rather than the existing literature, the proposed model is not only compared with the previous FTS models, but also with the conventional time series methods such as the classical vector autoregressive model. The cluster optimization is based on the C-means clustering method. An empirical study is performed for the prediction of the chartering rates of a group of dry bulk cargo ships. The root mean squared error (RMSE) metric is used for the comparing of results of methods and the proposed method has superiority than both traditional FTS methods and also the classical time series methods.
Abstract: The model of neural networks on the small-world
topology, with metric (local and random connectivity) is investigated.
The synaptic weights are random, driving the network towards a
chaotic state for the neural activity. An ordered macroscopic neuron
state is induced by a bias in the network connections. When the
connections are mainly local, the network emulates a block-like
structure. It is found that the topology and the bias compete to
influence the network to evolve into a global or a block activity
ordering, according to the initial conditions.
Abstract: One of the most important power quality issues is voltage flicker. Nowadays this issue also impacts the power system all over the world. The fact of the matter is that the more and the larger capacity of wind generator has been installed. Under unstable wind power situation, the variation of output current and voltage have caused trouble to voltage flicker. Hence, the major purpose of this study is to analyze the impact of wind generator on voltage flicker of power system. First of all, digital simulation and analysis are carried out based on wind generator operating under various system short circuit capacity, impedance angle, loading, and power factor of load. The simulation results have been confirmed by field measurements.
Abstract: To reveal the temperature field distribution of disc
brake in downward belt conveyor, mathematical models of heat
transfer for disc brake were established combined with heat transfer
theory. Then, the simulation process was stated in detail and the
temperature field of disc brake under conditions of dynamic speed and
dynamic braking torque was numerically simulated by using ANSYS
software. Finally the distribution and variation laws of temperature
field in the braking process were analyzed. Results indicate that the
maximum surface temperature occurs at a time before the brake end
and there exist large temperature gradients in both radial and axial
directions, while it is relatively small in the circumferential direction.
Abstract: Scale Invariant Feature Transform (SIFT) has been
widely applied, but extracting SIFT feature is complicated and
time-consuming. In this paper, to meet the demand of the real-time
applications, SIFT is parallelized and optimized on cluster system,
which is named pSIFT. Redundancy storage and communication are
used for boundary data to improve the performance, and before
representation of feature descriptor, data reallocation is adopted to
keep load balance in pSIFT. Experimental results show that pSIFT
achieves good speedup and scalability.