Abstract: Investigations of the unimolecular decomposition of
vinyl ethyl ether (VEE), vinyl propyl ether (VPE) and vinyl butyl
ether (VBE) have shown that activation of the molecule of a ether
results in formation of a cyclic construction - the transition state (TS),
which may lead to the displacement of the thermodynamic
equilibrium towards the reaction products. The TS is obtained by
applying energy minimization relative to the ground state of an ether
under the program MM2 when taking into account the hydrogen bond
formation between a hydrogen atom of alkyl residue and the extreme
atom of carbon of the vinyl group. The dissociation of TS up to the
products is studied by energy minimization procedure using the
mathematical program Gaussian. The obtained calculation data for
VEE testify that the decomposition of this ether may be conditioned
by hydrogen bond formation for two possible versions: when α- or β-
hydrogen atoms of the ethyl group are bound to carbon atom of the
vinyl group. Applying the same calculation methods to other ethers
(VPE and VBE) it is shown that only in the case of hydrogen bonding
between α-hydrogen atom of the alkyl residue and the extreme atom
of carbon of the vinyl group (αH---C) results in decay of theses
ethers.
Abstract: Air conditioning is mainly to be used as human
comfort medium. It has been use more often in country in which the
daily temperatures are high. In scientific, air conditioning is defined
as a process of controlling the moisture, cooling, heating and cleaning
air. Without proper estimation of cooling load, big amount of waste
energy been used because of unsuitable of air conditioning system are
not considering to overcoming heat gains from surrounding. This is
due to the size of the room is too big and the air conditioning has to
use more energy to cool the room and the air conditioning is too
small for the room. The studies are basically to develop a program to
calculate cooling load. Through this study it is easy to calculate
cooling load estimation. Furthermore it-s help to compare the cooling
load estimation by hourly and yearly. Base on the last study that been
done, the developed software are not user-friendly. For individual
without proper knowledge of calculating cooling load estimation
might be problem. Easy excess and user-friendly should be the main
objective to design something. This program will allow cooling load
able be estimate by any users rather than estimation by using rule of
thumb. Several of limitation of case study is judged to sure it-s
meeting to Malaysia building specification. Finally validation is done
by comparison manual calculation and by developed program.
Abstract: The pulp and paper mill effluent is one of the high
polluting effluent amongst the effluents obtained from polluting
industries. All the available methods for treatment of pulp and paper
mill effluent have certain drawbacks. The coagulation is one of the
cheapest process for treatment of various organic effluents. Thus, the
removal of chemical oxygen demand (COD) and colour of paper mill
effluent is studied using coagulation process. The batch coagulation
process was performed using various coagulants like: aluminium
chloride, poly aluminium chloride and copper sulphate. The initial
pH of the effluent (Coagulation pH) has tremendous effect on COD
and colour removal. Poly aluminium chloride (PAC) as coagulant
reduced COD to 84 % and 92 % of colour was removed at an
optimum pH 5 and coagulant dose of 8 ml l-1. With aluminium
chloride at an optimum pH = 4 and coagulant dose of 5 g l-1, 74 %
COD and 86 % colour removal were observed. The results using
copper sulphate as coagulant (a less commercial coagulant) were
encouraging. At an optimum pH 6 and mass loading of 5 g l-1, 76 %
COD reduction and 78 % colour reduction were obtained. It was also
observed that after addition of coagulant, the pH of the effluent
decreases. The decrease in pH was highest for AlCl3, which was
followed by PAC and CuSO4. Significant amount of COD reductions
was obtained by coagulation process. Since the coagulation process
is the first stage for treatment of effluent and some of the coagulant
cations usually remain in the treated effluents. Thus, cation like
copper may be one of the good catalyst for second stage of treatment
process like wet oxidation. The copper has been found to be good
oxidation catalyst then iron and aluminum.
Abstract: In this paper, we present an innovative scheme of
blindly extracting message bits from an image distorted by an attack.
Support Vector Machine (SVM) is used to nonlinearly classify the
bits of the embedded message. Traditionally, a hard decoder is used
with the assumption that the underlying modeling of the Discrete
Cosine Transform (DCT) coefficients does not appreciably change.
In case of an attack, the distribution of the image coefficients is
heavily altered. The distribution of the sufficient statistics at the
receiving end corresponding to the antipodal signals overlap and a
simple hard decoder fails to classify them properly. We are
considering message retrieval of antipodal signal as a binary
classification problem. Machine learning techniques like SVM is
used to retrieve the message, when certain specific class of attacks is
most probable. In order to validate SVM based decoding scheme, we
have taken Gaussian noise as a test case. We generate a data set using
125 images and 25 different keys. Polynomial kernel of SVM has
achieved 100 percent accuracy on test data.
Abstract: Electromagnetic flow meter by measuring the varying of magnetic flux, which is related to the velocity of conductive flow, can measure the rate of fluids very carefully and precisely. Electromagnetic flow meter operation is based on famous Faraday's second Law. In these equipments, the constant magnetostatic field is produced by electromagnet (winding around the tube) outside of pipe and inducting voltage that is due to conductive liquid flow is measured by electrodes located on two end side of the pipe wall. In this research, we consider to 2-dimensional mathematical model that can be solved by numerical finite difference (FD) solution approach to calculate induction potential between electrodes. The fundamental concept to design the electromagnetic flow meter, exciting winding and simulations are come out by using MATLAB and PDE-Tool software. In the last stage, simulations results will be shown for improvement and accuracy of technical provision.
Abstract: In this article the homotopy continuation method (HCM) to solve the forward kinematic problem of the 3-PRS parallel manipulator is used. Since there are many difficulties in solving the system of nonlinear equations in kinematics of manipulators, the numerical solutions like Newton-Raphson are inevitably used. When dealing with any numerical solution, there are two troublesome problems. One is that good initial guesses are not easy to detect and another is related to whether the used method will converge to useful solutions. Results of this paper reveal that the homotopy continuation method can alleviate the drawbacks of traditional numerical techniques.
Abstract: Buoyancy driven heat transfer of nanofluids in a
cylindrical enclosure used as a control unit in the subsea hydrocarbon
injection wells is investigated in this study. The governing equations
obtained with the Boussinesq approximation are solved using Comsol
Multiphysics finite element analysis and simulation software. The
base fluid is water and CuO is used as nanoparticles. Solution is
obtained for nanoparticle solid volume fraction of 8% and for
Rayleigh number in the range of 105-107. The results show that
nanoparticle usage in the cylindrical electronic control unit has a
significant effect on the flow and heat transfer.
Abstract: Efficient luminescence is reported for the first time in Eu2+ activated double Chlorides A2BCl4 (A=Alkali metal, B=Alkaline earth element). A simple wet-chemical preparation is described. Emission intensities are comparable to that of the commercial phosphor. Excitation covers near UV region. These phosphors may be useful for applications like solid state lighting, scintillation detectors and X-ray storage using photo-stimulable phosphors.
Abstract: Intrusion detection is a mechanism used to protect a
system and analyse and predict the behaviours of system users. An
ideal intrusion detection system is hard to achieve due to
nonlinearity, and irrelevant or redundant features. This study
introduces a new anomaly-based intrusion detection model. The
suggested model is based on particle swarm optimisation and
nonlinear, multi-class and multi-kernel support vector machines.
Particle swarm optimisation is used for feature selection by applying
a new formula to update the position and the velocity of a particle;
the support vector machine is used as a classifier. The proposed
model is tested and compared with the other methods using the KDD
CUP 1999 dataset. The results indicate that this new method achieves
better accuracy rates than previous methods.
Abstract: User satisfaction is one of the most used success
indicators in the research of information system (IS). Literature
shows user expectations have great influence on user satisfaction.
Both expectation and satisfaction of users are important for Hospital
Information Systems (HIS). Education, IS experience, age, attitude
towards change, business title, sex and working unit of the hospital,
are examined as the potential determinant of the medical users’
expectations. Data about medical user expectations are collected by
the “Expectation Questionnaire” developed for this study.
Expectation data are used for calculating the Expectation Meeting
Ratio (EMR) with the evaluation framework also developed for this
study. The internal consistencies of the answers to the questionnaire
are measured by Cronbach´s Alpha coefficient. The multivariate
analysis of medical user’s EMRs of HIS is performed by forward
stepwise binary logistic regression analysis. Education and business
title is appeared to be the determinants of expectations from HIS.
Abstract: Saturated hydraulic conductivity is one of the soil
hydraulic properties which is widely used in environmental studies
especially subsurface ground water. Since, its direct measurement is
time consuming and therefore costly, indirect methods such as
pedotransfer functions have been developed based on multiple linear
regression equations and neural networks model in order to estimate
saturated hydraulic conductivity from readily available soil
properties e.g. sand, silt, and clay contents, bulk density, and organic
matter. The objective of this study was to develop neural networks
(NNs) model to estimate saturated hydraulic conductivity from
available parameters such as sand and clay contents, bulk density,
van Genuchten retention model parameters (i.e. r
θ , α , and n) as well
as effective porosity. We used two methods to calculate effective
porosity: : (1) eff s FC φ =θ -θ , and (2) inf φ =θ -θ eff s , in which s
θ is
saturated water content, FC θ is water content retained at -33 kPa
matric potential, and inf θ is water content at the inflection point.
Total of 311 soil samples from the UNSODA database was divided
into three groups as 187 for the training, 62 for the validation (to
avoid over training), and 62 for the test of NNs model. A commercial
neural network toolbox of MATLAB software with a multi-layer
perceptron model and back propagation algorithm were used for the
training procedure. The statistical parameters such as correlation
coefficient (R2), and mean square error (MSE) were also used to
evaluate the developed NNs model. The best number of neurons in
the middle layer of NNs model for methods (1) and (2) were
calculated 44 and 6, respectively. The R2 and MSE values of the test
phase were determined for method (1), 0.94 and 0.0016, and for
method (2), 0.98 and 0.00065, respectively, which shows that method
(2) estimates saturated hydraulic conductivity better than method (1).
Abstract: Application of Expert System in the area of agriculture would take the form of Integrated Crop Management decision aids and would encompass water management, fertilizer management, crop protection systems and identification of implements. In order to remain competitive, the modern farmer often relies on agricultural specialists and advisors to provide information for decision-making. An expert system normally composed of a knowledge base (information, heuristics, etc.), inference engine (analyzes knowledge base), and end user interface (accepting inputs, generating outputs). Software named 'CROP-9-DSS' incorporating all modern features like, graphics, photos, video clippings etc. has been developed. This package will aid as a decision support system for identification of pest and diseases with control measures, fertilizer recommendation system, water management system and identification of farm implements for leading crops of Kerala (India) namely Coconut, Rice, Cashew, Pepper, Banana, four vegetables like Amaranthus, Bhindi, Brinjal and Cucurbits. 'CROP-9-DSS' will act as an expert system to agricultural officers, scientists in the field of agriculture and extension workers for decision-making and help them in suggesting suitable recommendations.
Abstract: In this paper, we introduce an effective strategy for
subgoal division and ordering based upon recursive subgoals and
combine this strategy with a genetic-based planning approach. This
strategy can be applied to domains with conjunctive goals. The main
idea is to recursively decompose a goal into a set of serializable
subgoals and to specify a strict ordering among the subgoals.
Empirical results show that the recursive subgoal strategy reduces the
size of the search space and improves the quality of solutions to
planning problems.
Abstract: A strategy is implemented to find the improved configuration design of an existing aircraft structure by executing topology and shape optimizations. Structural analysis of the Initial Design Space is performed in ANSYS under the loads pertinent to operating and ground conditions. By using the FEA results and data, an initial optimized layout configuration is attained by exploiting nonparametric topology optimization in TOSCA software. Topological optimized surfaces are then smoothened and imported in ANSYS to develop the geometrical features. Nodes at the critical locations of resulting voids are selected for sketching rough profiles. Rough profiles are further refined and CAD feasible geometric features are generated. The modified model is then analyzed under the same loadings and constraints as defined for topology optimization. Shape at the peak stress concentration areas are further optimized by exploiting the shape optimization in TOSCA.shape module. The harmonized stressed model with the modified surfaces is then imported in CATIA to develop the final design.
Abstract: Defense and Aerospace environment is continuously
striving to keep up with increasingly sophisticated Information
Technology (IT) in order to remain effective in today-s dynamic and
unpredictable threat environment. This makes IT one of the largest
and fastest growing expenses of Defense. Hundreds of millions of
dollars spent a year on IT projects. But, too many of those millions
are wasted on costly mistakes. Systems that do not work properly,
new components that are not compatible with old ones, trendy new
applications that do not really satisfy defense needs or lost through
poorly managed contracts.
This paper investigates and compiles the effective strategies that
aim to end exasperation with low returns and high cost of
Information Technology acquisition for defense; it tries to show how
to maximize value while reducing time and expenditure.
Abstract: Nowaday-s, many organizations use systems that
support business process as a whole or partially. However, in some
application domains, like software development and health care
processes, a normative Process Aware System (PAS) is not suitable,
because a flexible support is needed to respond rapidly to new
process models. On the other hand, a flexible Process Aware System
may be vulnerable to undesirable and fraudulent executions, which
imposes a tradeoff between flexibility and security. In order to make
this tradeoff available, a genetic-based anomaly detection model for
logs of Process Aware Systems is presented in this paper. The
detection of an anomalous trace is based on discovering an
appropriate process model by using genetic process mining and
detecting traces that do not fit the appropriate model as anomalous
trace; therefore, when used in PAS, this model is an automated
solution that can support coexistence of flexibility and security.
Abstract: This paper describes an interfacing of C and the
TMS320C6713 assembly language which is crucially important for
many real-time applications. Similarly, interfacing of C with the
assembly language of a conventional microprocessor such as
MC68000 is presented for comparison. However, it should be noted
that the way the C compiler passes arguments among various
functions in the TMS320C6713-based environment is totally
different from the way the C compiler passes arguments in a
conventional microprocessor such as MC68000. Therefore, it is very
important for a user of the TMS320C6713-based system to properly
understand and follow the register conventions when interfacing C
with the TMS320C6713 assembly language subroutine. It should be
also noted that in some cases (examples 6-9) the endian-mode of the
board needs to be taken into consideration. In this paper, one method
is presented in great detail. Other methods will be presented in the
future.
Abstract: In this paper we present the first Arabic sentence
dataset for on-line handwriting recognition written on tablet pc. The
dataset is natural, simple and clear. Texts are sampled from daily
newspapers. To collect naturally written handwriting, forms are
dictated to writers. The current version of our dataset includes 154
paragraphs written by 48 writers. It contains more than 3800 words
and more than 19,400 characters. Handwritten texts are mainly
written by researchers from different research centers. In order to use
this dataset in a recognition system word extraction is needed. In this
paper a new word extraction technique based on the Arabic
handwriting cursive nature is also presented. The technique is applied
to this dataset and good results are obtained. The results can be
considered as a bench mark for future research to be compared with.
Abstract: Simulation accuracy by recent dynamic vehicle
simulation multidimensional expression significantly has progressed
and acceptable results not only for passive vehicles but also for
active vehicles normally equipped with advanced electronic
components is also provided. Recently, one of the subjects that has it
been considered, is increasing the safety car in design. Therefore,
many efforts have been done to increase vehicle stability especially
in the turn. One of the most important efforts is adjusting the camber
angle in the car suspension system. Optimum control camber angle in
addition to the vehicle stability is effective in the wheel adhesion on
road, reducing rubber abrasion and acceleration and braking. Since
the increase or decrease in the camber angle impacts on the stability
of vehicles, in this paper, a car suspension system mechanism is
introduced that could be adjust camber angle and the mechanism is
application and also inexpensive. In order to reach this purpose, in
this paper, a passive double wishbone suspension system with
variable camber angle is introduced and then variable camber
mechanism designed and analyzed for study the designed system
performance, this mechanism is modeled in Visual Nastran software
and kinematic analysis is revealed.
Abstract: This paper introduces a mixed integer programming model to find the optimum development plan for port Anzali. The model minimizes total system costs taking into account both port infrastructure costs and shipping costs. Due to the multipurpose function of the port, the model consists of 1020 decision variables and 2490 constraints. Results of the model determine the optimum number of berths that should be constructed in each period and for each type of cargo. In addition to, the results of sensitivity analysis on port operation quantity provide useful information for managers to choose the best scenario for port planning with the lowest investment risks. Despite all limitations-due to data availability-the model offers a straightforward decision tools to port planners aspiring to achieve optimum port planning steps.