Interaction of Electroosmotic Flow on Isotachophoretic Transport of Ions

A numerical study on the influence of electroosmotic flow on analyte preconcentration by isotachophoresis ( ITP) is made. We consider that the double layer induced electroosmotic flow ( EOF) counterbalance the electrophoretic velocity and a stationary ITP stacked zones results. We solve the Navier-Stokes equations coupled with the Nernst-Planck equations to determine the local convective velocity and the preconcentration dynamics of ions. Our numerical algorithm is based on a finite volume method along with a secondorder upwind scheme. The present numerical algorithm can capture the the sharp boundaries of step-changes ( plateau mode) or zones of steep gradients ( peak mode) accurately. The convection of ions due to EOF reduces the resolution of the ITP transition zones and produces a dispersion in analyte zones. The role of the electrokinetic parameters which induces dispersion is analyzed. A one-dimensional model for the area-averaged concentrations based on the Taylor-Aristype effective diffusivity is found to be in good agreement with the computed solutions.

Numerical Solution of Second-Order Ordinary Differential Equations by Improved Runge-Kutta Nystrom Method

In this paper we developed the Improved Runge-Kutta Nystrom (IRKN) method for solving second order ordinary differential equations. The methods are two step in nature and require lower number of function evaluations per step compared with the existing Runge-Kutta Nystrom (RKN) methods. Therefore, the methods are computationally more efficient at achieving the higher order of local accuracy. Algebraic order conditions of the method are obtained and the third and fourth order method are derived with two and three stages respectively. The numerical results are given to illustrate the efficiency of the proposed method compared to the existing RKN methods.

Direct Measurements of Wind Data over 100 Meters above the Ground in the Site of Lendinara, Italy

The wind resource in the Italian site of Lendinara (RO) is analyzed through a systematic anemometric campaign performed on the top of the bell tower, at an altitude of over 100 m above the ground. Both the average wind speed and the Weibull distribution are computed. The resulting average wind velocity is in accordance with the numerical predictions of the Italian Wind Atlas, confirming the accuracy of the extrapolation of wind data adopted for the evaluation of wind potential at higher altitudes with respect to the commonly placed measurement stations.