Abstract: Trace element speciation of an integrated soil
amendment matrix was studied with a modified BCR sequential
extraction procedure. The analysis included pseudo-total
concentration determinations according to USEPA 3051A and
relevant physicochemical properties by standardized methods. Based
on the results, the soil amendment matrix possessed neutralization
capacity comparable to commercial fertilizers. Additionally, the
pseudo-total concentrations of all trace elements included in the
Finnish regulation for agricultural fertilizers were lower than the
respective statutory limit values. According to chemical speciation,
the lability of trace elements increased in the following order: Hg <
Cr < Co < Cu < As < Zn < Ni < Pb < Cd < V < Mo < Ba. The
validity of the BCR approach as a tool for chemical speciation was
confirmed by the additional acid digestion phase. Recovery of trace
elements during the procedure assured the validity of the approach
and indicated good quality of the analytical work.
Abstract: Predict daily global solar radiation (GSR) based on meteorological variables, using Multi-layer perceptron (MLP) neural networks is the main objective of this study. Daily mean air temperature, relative humidity, sunshine hours, evaporation, wind speed, and soil temperature values between 2002 and 2006 for Dezful city in Iran (32° 16' N, 48° 25' E), are used in this study. The measured data between 2002 and 2005 are used to train the neural networks while the data for 214 days from 2006 are used as testing data.
Abstract: In this study, the reduction of Cr(VI) by use of scrap
iron, a cheap and locally available industrial waste, was investigated
in continuous system. The greater scrap iron efficiency observed for
the first two sections of the column filling indicate that most of the
reduction process was carried out in the bottom half of the column
filling. This was ascribed to a constant decrease of Cr(VI)
concentration inside the filling, as the water front passes from the
bottom to the top end of the column. While the bottom section of the
column filling was heavily passivated with secondary mineral phases,
the top section was less affected by the passivation process; therefore
the column filling would likely ensure the reduction of Cr(VI) for
time periods longer than 216 hours. The experimental results indicate
that fixed beds columns packed with scrap iron could be successfully
used for the first step of Cr(VI) polluted wastewater treatment.
However, the mass of scrap iron filling should be carefully estimated
since it significantly affects the Cr(VI) reduction efficiency.
Abstract: Renewable water resources are crucial production
variables in arid and semi-arid regions where intensive agriculture is
practiced to meet ever-increasing demand for food and fiber. This is
crucial for the Dez and Moghan command areas where water delivery
problems and adverse environmental issues are widespread. This
paper aims to identify major problems areas using on-farm surveys of
200 farmers, agricultural extensionists and water suppliers which was
complemented by secondary data and field observations during 2010-
2011 cultivating season. The SPSS package was used to analyze and
synthesis data. Results indicated inappropriate canal operations in
both schemes, though there was no unanimity about the underlying
causes. Inequitable and inflexible distribution was found to be rooted
in deficient hydraulic structures particularly in the main and
secondary canals. The inadequacy and inflexibility of water
scheduling regime was the underlying causes of recurring pest and
disease spread which often led to the decline of crop yield and
quality, although these were not disputed, the water suppliers were
not prepared to link with the deficiencies in the operation of the main
and secondary canals. They rather attributed these to the prevailing
salinity; alkalinity, water table fluctuations and leaching of the
valuable agro-chemical inputs from the plants- route zone with farreaching
consequences. Examples of these include the pollution of
ground and surface resources due to over-irrigation at the farm level
which falls under the growers- own responsibility. Poor irrigation
efficiency and adverse environmental problems were attributed to
deficient and outdated farming practices that were in turn rooted in
poor extension programs and irrational water charges.