Preparation of ATO Conductive Particles with Narrow Size Distribution
Antimosy-doped tin oxide (ATO) particles were
prepared via chemical coprecipitation and reverse emulsion. The size
and size distribution of ATO particles were obviously decreased via
reverse microemulsion method. At the relatively high yield the ATO
particles were nearly spherical in shape, meanwhile the crystalline
structure and excellent conductivity were reserved, which could satisfy
the requirement as composite fillers, such as dielectric filler of
polyimide film.
[1] A. Gamard, O. Babot, B. Jousseaume, M. C. Rascle, T. Toupance and G.
Campet, "Conductive F-doped tin dioxide sol-gel materials from
fluorinated beta-diketonate tin(IV) complexes. Characterization and
thermolytic behavior," Chem. Mater., vol.12, pp. 3419-3426, Oct. 2000.
[2] G. Granqvist Claes, "Transparent conductors as solar energy materials: A
panoramic review," Solar Energy Materials & Solar Cells., vol.91,
pp.1529-1598, Oct. 2007.
[3] F. Gu, S. F. Wang, M. K. Lu, G. J. Zhou, D. Xu and D. R. Yuan,
"Photoluminescence properties of SnO2 nanoparticles synthesized by
sol-gel method," J. Phys. Chem., vol. 108, pp. 8119-8123, Jun. 2004.
[4] J. Zhang and L. Gao, "Synthesis and characterization of antimony-doped
tin oxide (ATO) nanoparticles by a new hydrothermal method," Mater.
Chem. Phys.,vol.87, pp.10-13, Sep. 2004.
[5] J. B. Han, H. J. Zhou and Q. Q. Wang, "Conductivity and optical
nonlinearity of Sb doped SnO2 films," Mater. Lett., vol.60, pp.252-254,
Jan. 2006.
[6] L. Yuan, K. Konstantinov, G. X. Wang, H. K. liu and S. X. Do,
"Nano-structured SnO2-carbon composites obtained by in situ spray
pyrolysis method as anodes in lithium batteries," J. Power Sources,
vol.146, Aug. 2005, pp. 180-184 [12th International Meeting on Lithium
Batteries Japan Jun, 2004].
[7] Z. Fang, K. B Tang, G. Z. Shen, D. Chen, R. Kong and S. J. Lei,
"Self-assembled ZnO 3D flowerlike nanostructures," Mater. Lett.,
vol.60, pp. 2530-2533, Sep. 2006.
[8] C. K. Chen and C. Y. Tai, "Competing effects of operating variables in
the synthesis of CaCO(3) particles using the reverse microemulsion
technique," Chem. Eng. Sci., vol. 65, pp. 4761-4770. Aug. 2010.
[9] T. Hirai, H. Sato and I. Komasawa, "Mechanism of formation of Cds and
Zns ultrafine particles in reverse micelles," Ind. Eng. Chem. Res., vol.33,
pp.3262-3266, Dec. 1994.
[10] G. L. Li and G. H. Wang, "Synthesis of nanometer-sized TiO2 particles
by a microemulsion method," Nanostruct. Mater., vol.11, pp. 663-668,
Aug. 1999.
[11] R. P. Bagwe and K. C. Khilar, "Effects of intermicellar exchange rate on
the formation of silver nanoparticles in reverse microemulsions of AOT,"
Langmuir, vol.16, pp. 905-910, Feb. 2000.
[12] C. Y. Tai and C. K. Chen. "Particle morphology, habit, and size control of
CaCO3 using reverse microemulsion technique," Chem. Eng. Sci., vol.
63, pp. 3632-3642. July 2008.
[13] J. Samuel, O. Raccurt, O. Poncelet, A. l. Auger, W. L. Ling, P. Cherns, D.
Grunwald and O. Tillement, "Surface characterizations of
fluorescent-functionalized silica nanoparticles: from the macroscale to
the nanoscale," J. Nanopart. Res., vol 12, pp. 2255-2265. Aug. 2010.
[14] N. Chandra, D. K. Singh, M. Sharma, R. K. Upadhyay, S. S. Amritphale,
and S. K. Sanghi, "Synthesis and characterization of nano-sized zirconia
powder synthesized by single emulsion-assisted direct precipitation," J.
Colloid Interf. Sci., vol. 342, pp. 327-332. Feb. 2010.
[1] A. Gamard, O. Babot, B. Jousseaume, M. C. Rascle, T. Toupance and G.
Campet, "Conductive F-doped tin dioxide sol-gel materials from
fluorinated beta-diketonate tin(IV) complexes. Characterization and
thermolytic behavior," Chem. Mater., vol.12, pp. 3419-3426, Oct. 2000.
[2] G. Granqvist Claes, "Transparent conductors as solar energy materials: A
panoramic review," Solar Energy Materials & Solar Cells., vol.91,
pp.1529-1598, Oct. 2007.
[3] F. Gu, S. F. Wang, M. K. Lu, G. J. Zhou, D. Xu and D. R. Yuan,
"Photoluminescence properties of SnO2 nanoparticles synthesized by
sol-gel method," J. Phys. Chem., vol. 108, pp. 8119-8123, Jun. 2004.
[4] J. Zhang and L. Gao, "Synthesis and characterization of antimony-doped
tin oxide (ATO) nanoparticles by a new hydrothermal method," Mater.
Chem. Phys.,vol.87, pp.10-13, Sep. 2004.
[5] J. B. Han, H. J. Zhou and Q. Q. Wang, "Conductivity and optical
nonlinearity of Sb doped SnO2 films," Mater. Lett., vol.60, pp.252-254,
Jan. 2006.
[6] L. Yuan, K. Konstantinov, G. X. Wang, H. K. liu and S. X. Do,
"Nano-structured SnO2-carbon composites obtained by in situ spray
pyrolysis method as anodes in lithium batteries," J. Power Sources,
vol.146, Aug. 2005, pp. 180-184 [12th International Meeting on Lithium
Batteries Japan Jun, 2004].
[7] Z. Fang, K. B Tang, G. Z. Shen, D. Chen, R. Kong and S. J. Lei,
"Self-assembled ZnO 3D flowerlike nanostructures," Mater. Lett.,
vol.60, pp. 2530-2533, Sep. 2006.
[8] C. K. Chen and C. Y. Tai, "Competing effects of operating variables in
the synthesis of CaCO(3) particles using the reverse microemulsion
technique," Chem. Eng. Sci., vol. 65, pp. 4761-4770. Aug. 2010.
[9] T. Hirai, H. Sato and I. Komasawa, "Mechanism of formation of Cds and
Zns ultrafine particles in reverse micelles," Ind. Eng. Chem. Res., vol.33,
pp.3262-3266, Dec. 1994.
[10] G. L. Li and G. H. Wang, "Synthesis of nanometer-sized TiO2 particles
by a microemulsion method," Nanostruct. Mater., vol.11, pp. 663-668,
Aug. 1999.
[11] R. P. Bagwe and K. C. Khilar, "Effects of intermicellar exchange rate on
the formation of silver nanoparticles in reverse microemulsions of AOT,"
Langmuir, vol.16, pp. 905-910, Feb. 2000.
[12] C. Y. Tai and C. K. Chen. "Particle morphology, habit, and size control of
CaCO3 using reverse microemulsion technique," Chem. Eng. Sci., vol.
63, pp. 3632-3642. July 2008.
[13] J. Samuel, O. Raccurt, O. Poncelet, A. l. Auger, W. L. Ling, P. Cherns, D.
Grunwald and O. Tillement, "Surface characterizations of
fluorescent-functionalized silica nanoparticles: from the macroscale to
the nanoscale," J. Nanopart. Res., vol 12, pp. 2255-2265. Aug. 2010.
[14] N. Chandra, D. K. Singh, M. Sharma, R. K. Upadhyay, S. S. Amritphale,
and S. K. Sanghi, "Synthesis and characterization of nano-sized zirconia
powder synthesized by single emulsion-assisted direct precipitation," J.
Colloid Interf. Sci., vol. 342, pp. 327-332. Feb. 2010.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:56614", author = "Yueying Wu and Fengzhu Lv and Yihe Zhang and Zixian Xu", title = "Preparation of ATO Conductive Particles with Narrow Size Distribution", abstract = "Antimosy-doped tin oxide (ATO) particles were
prepared via chemical coprecipitation and reverse emulsion. The size
and size distribution of ATO particles were obviously decreased via
reverse microemulsion method. At the relatively high yield the ATO
particles were nearly spherical in shape, meanwhile the crystalline
structure and excellent conductivity were reserved, which could satisfy
the requirement as composite fillers, such as dielectric filler of
polyimide film.", keywords = "ATO particle, Conductivity, Distribution, Reverse
emulsion", volume = "5", number = "11", pages = "976-3", }