Effect of Gold Loading on CeO2–Fe2O3 for Oxidative Steam Reforming of Methanol
In this study, oxidative steam reforming of methanol (OSRM) over a Au/CeO2–Fe2O3 catalyst prepared by a depositionprecipitation (DP) method was studied to produce hydrogen in order to feed a Proton Exchange Membrane Fuel Cell (PEMFC). The support (CeO2, Fe2O3, and CeO2–Fe2O3) were prepared by precipitation and co-precipitation methods. The impact of the support composition on the catalytic performance was studied by varying the Ce/(Ce+Fe) atomic ratio, it was found that the 1%Au/CF(0.25) calcined at 300 °C exhibited the highest catalytic activity in the whole temperature studied. In addition, the effect of Au content was investigated and 3%Au/CF(0.25) exhibited the highest activity under the optimum condition in the temperature range of 200 °C to 400 °C. The catalysts were characterized by various techniques: XRD, TPR, XRF, and UV-vis.
[1] K. Faungnawakij, R. Kikuchi, and K. Eguchi, "Thermodynamic
evaluation of methanol steam reforming for hydrogen production,"
Journal of Power Sources, vol. 161, pp. 87-94, 2006.
[2] T. Shishido, Y. Yamamoto, H. Morioka, and K. Takehira, "Production
of hydrogen from methanol over Cu/ZnO and Cu/ZnO/Al2O3 catalysts
prepared by homogeneous precipitation: Steam reforming and oxidative
steam reforming," Journal of Molecular Catalysis A: Chemical, vol.
268, pp. 185-194, 2007.
[3] S. Patel, and K.K. Pant, and L. Paturzo, "Hydrogen production by
oxidative steam reforming of methanol using ceria promoted copper-
alumina catalysts," Fuel Processing Technology, vol. 88, pp. 825-832,
2007.
[4] T. Shishido, Y. Yamamoto, H. Morioka, and K. Takehira, "Production
of hydrogen from methanol over Cu/ZnO and Cu/ZnO/Al2O3 catalysts
prepared by homogeneous precipitation: Steam reforming and oxidative
steam reforming," Journal of Molecular Catalysis A: Chemical, vol.
268, pp. 185-194, 2007.
[5] X. Honga, and S. Ren, "Selective hydrogen production from methanol
oxidative steam reforming over Zn-Cr catalysts with or without Cu
loading," International Journal of Hydrogen Energy, vol. 33, pp. 700 -
708, 2008.
[6] M. Turco, G. Bagnasco, C. Cammarano, P. Senese, U. Costantino, and
M. Sisani, "Cu/ZnO/Al2O3 catalysts for oxidative steam reforming of
methanol: The role of Cu and the dispersing oxide matrix," Applied
Catalysis B: Environmental, vol. 77, pp. 46-57, 2007.
[7] F. Pinzari, P. Patrono, and U. Costantino, "Methanol reforming reactions
over Zn/TiO2 catalysts," Catalysis Communications, vol. 7, pp. 696-700,
2006.
[8] M. Haruta, and M. DateÔÇ▓, "Advances in the catalysis of Au
nanoparticles," Applied Catalysis A: General, vol. 222, pp. 427-437,
2001.
[9] T. Tabakova, G. Avgouropoulos, J. Papavasiliou, M. Manzoli, F.
Boccuzzi, K. Tenchev, F. Vindigni, and T. Ioannides, "CO-free
hydrogen production over Au/CeO2-Fe2O3 catalysts: Part 1. Impact of
the support composition on the performance for the preferential CO
oxidation reaction," Applied Catalysis B: Environmental, vol. 101, pp.
256-265, 2011.
[10] M. Makkee, J.A. Moulijin, , A.R. Overweg, and S.T. Daniells, "The
mechanism of low-temperature CO oxidation with Au/Fe2O3 catalysts: a
combined Mössbauer, FT-IR, and TAP reactor study," Journal of
Catalysis, vol. 230, pp. 52-65, 2005.
[11] L. Hongyan, M. Zhiqiang, D. Ling, Q. Jieshan, and L. Changhai,
"Preparation of Nanoscale CexFe1-xO2 Solid Solution Catalyst by the
Template Method and Its Catalytic Properties for Ethanol Steam
Reforming," Chinese Journal Catalysis, vol. 29(5), pp. 418-420, 2008
[12] J. Kunming, Z. Huili, and L. Wencui, "Effect of morphology of the ceria
support on the activity of Au/CeO2 catalysts fot CO oxidation," Chinese
Journal of Catalysis, vol. 29, pp. 2089-1092, 2008.
[13] H. Lin, Z. Ma, L. ding, J. Qiu, and C. Liang, "Preparation of nanoscale
CexFe1-xO2 solid solution catalyst by the template method and its
catalytic propeties for ethanol steam reforming," Chinese Journal of
Catalysis, vol. 29, pp. 418-420, 2008.
[14] K. Sirichaiprasert, A. Luengnaruemitchai, and S. Pongstabodee,
"Selective oxidation of CO to CO2 over Cu-Ce-Fe-O compostie-oxide
catalyst in hydrogen feed stream," International Jornal of Hydrogen
Energy, vol. 32, pp. 915-926, 2006.
[15] G. Neri, A. Bonavita, G. Rizzo, S. Galvagno, S. Capone, and P.
Siciliano, "Methanol gas-sensing properties of CeO2-Fe2O3 thin films,"
Sensors and Actuators B, vol. 114, pp. 687-695, 2006.
[16] L. Rui-hui, Z. Cun-man, and M. Jian-xin, "Gold catalysts supported on
crystalline Fe2O3 for low-temperature CO oxidation," Chemical
Research Chinese University, vol. 26(1), pp. 98-104, 2010.
[17] S. Scirè, C. Crisafulli, S. Minic├▓, G.G. Condorelli, and A.D. Mauro,
"Selectivity oxidation of CO in H2-rich stream over gold/iron oxide: An
insight on the effect of catalyst pretreatment," Journal of Molecular
Catalysis A, vol. 284, pp. 24-32, 2008.
[18] A. Venugopal, and M. Scurrell, "Low temperature reductive
pretreatment of Au/Fe2O3 catalysts, TPR/TPO sudies and behaviour in
the water-gas shift reaction," Applied Catalysis A: General, vol. 258, pp.
241-249, 2003.
[19] S. Park, K. Yoo, H.J. Park, J.C. Lee, and J.H. Lee, "Rapid gold ion
recovery from wastewater by photocatalytic ZnO nanopowders,"
Journal of Electroceram, vol. 17, pp. 831-834, 2006.
[20] R. Zanella, S. Giorgio, C.H. Shin, C.R. Henry, and C. Louis,
"Characterization and reactivity in CO oxidation of gold nanoparticles
supported on TiO2 prepared by deposition-precipitaion with NaOH and
urea," Journal of Catalysis, vol. 222, pp. 357-367, 2004.
[21] F.W. Chang, L.S Roselin, and T.C. Ou, "Hydrogen production by partial
oxidation of methanol over bimetallic Au-Ru/Fe2O3 catalysts," Applied
Catalysis A: General, vol. 334, pp. 147-155, 2008.
[1] K. Faungnawakij, R. Kikuchi, and K. Eguchi, "Thermodynamic
evaluation of methanol steam reforming for hydrogen production,"
Journal of Power Sources, vol. 161, pp. 87-94, 2006.
[2] T. Shishido, Y. Yamamoto, H. Morioka, and K. Takehira, "Production
of hydrogen from methanol over Cu/ZnO and Cu/ZnO/Al2O3 catalysts
prepared by homogeneous precipitation: Steam reforming and oxidative
steam reforming," Journal of Molecular Catalysis A: Chemical, vol.
268, pp. 185-194, 2007.
[3] S. Patel, and K.K. Pant, and L. Paturzo, "Hydrogen production by
oxidative steam reforming of methanol using ceria promoted copper-
alumina catalysts," Fuel Processing Technology, vol. 88, pp. 825-832,
2007.
[4] T. Shishido, Y. Yamamoto, H. Morioka, and K. Takehira, "Production
of hydrogen from methanol over Cu/ZnO and Cu/ZnO/Al2O3 catalysts
prepared by homogeneous precipitation: Steam reforming and oxidative
steam reforming," Journal of Molecular Catalysis A: Chemical, vol.
268, pp. 185-194, 2007.
[5] X. Honga, and S. Ren, "Selective hydrogen production from methanol
oxidative steam reforming over Zn-Cr catalysts with or without Cu
loading," International Journal of Hydrogen Energy, vol. 33, pp. 700 -
708, 2008.
[6] M. Turco, G. Bagnasco, C. Cammarano, P. Senese, U. Costantino, and
M. Sisani, "Cu/ZnO/Al2O3 catalysts for oxidative steam reforming of
methanol: The role of Cu and the dispersing oxide matrix," Applied
Catalysis B: Environmental, vol. 77, pp. 46-57, 2007.
[7] F. Pinzari, P. Patrono, and U. Costantino, "Methanol reforming reactions
over Zn/TiO2 catalysts," Catalysis Communications, vol. 7, pp. 696-700,
2006.
[8] M. Haruta, and M. DateÔÇ▓, "Advances in the catalysis of Au
nanoparticles," Applied Catalysis A: General, vol. 222, pp. 427-437,
2001.
[9] T. Tabakova, G. Avgouropoulos, J. Papavasiliou, M. Manzoli, F.
Boccuzzi, K. Tenchev, F. Vindigni, and T. Ioannides, "CO-free
hydrogen production over Au/CeO2-Fe2O3 catalysts: Part 1. Impact of
the support composition on the performance for the preferential CO
oxidation reaction," Applied Catalysis B: Environmental, vol. 101, pp.
256-265, 2011.
[10] M. Makkee, J.A. Moulijin, , A.R. Overweg, and S.T. Daniells, "The
mechanism of low-temperature CO oxidation with Au/Fe2O3 catalysts: a
combined Mössbauer, FT-IR, and TAP reactor study," Journal of
Catalysis, vol. 230, pp. 52-65, 2005.
[11] L. Hongyan, M. Zhiqiang, D. Ling, Q. Jieshan, and L. Changhai,
"Preparation of Nanoscale CexFe1-xO2 Solid Solution Catalyst by the
Template Method and Its Catalytic Properties for Ethanol Steam
Reforming," Chinese Journal Catalysis, vol. 29(5), pp. 418-420, 2008
[12] J. Kunming, Z. Huili, and L. Wencui, "Effect of morphology of the ceria
support on the activity of Au/CeO2 catalysts fot CO oxidation," Chinese
Journal of Catalysis, vol. 29, pp. 2089-1092, 2008.
[13] H. Lin, Z. Ma, L. ding, J. Qiu, and C. Liang, "Preparation of nanoscale
CexFe1-xO2 solid solution catalyst by the template method and its
catalytic propeties for ethanol steam reforming," Chinese Journal of
Catalysis, vol. 29, pp. 418-420, 2008.
[14] K. Sirichaiprasert, A. Luengnaruemitchai, and S. Pongstabodee,
"Selective oxidation of CO to CO2 over Cu-Ce-Fe-O compostie-oxide
catalyst in hydrogen feed stream," International Jornal of Hydrogen
Energy, vol. 32, pp. 915-926, 2006.
[15] G. Neri, A. Bonavita, G. Rizzo, S. Galvagno, S. Capone, and P.
Siciliano, "Methanol gas-sensing properties of CeO2-Fe2O3 thin films,"
Sensors and Actuators B, vol. 114, pp. 687-695, 2006.
[16] L. Rui-hui, Z. Cun-man, and M. Jian-xin, "Gold catalysts supported on
crystalline Fe2O3 for low-temperature CO oxidation," Chemical
Research Chinese University, vol. 26(1), pp. 98-104, 2010.
[17] S. Scirè, C. Crisafulli, S. Minic├▓, G.G. Condorelli, and A.D. Mauro,
"Selectivity oxidation of CO in H2-rich stream over gold/iron oxide: An
insight on the effect of catalyst pretreatment," Journal of Molecular
Catalysis A, vol. 284, pp. 24-32, 2008.
[18] A. Venugopal, and M. Scurrell, "Low temperature reductive
pretreatment of Au/Fe2O3 catalysts, TPR/TPO sudies and behaviour in
the water-gas shift reaction," Applied Catalysis A: General, vol. 258, pp.
241-249, 2003.
[19] S. Park, K. Yoo, H.J. Park, J.C. Lee, and J.H. Lee, "Rapid gold ion
recovery from wastewater by photocatalytic ZnO nanopowders,"
Journal of Electroceram, vol. 17, pp. 831-834, 2006.
[20] R. Zanella, S. Giorgio, C.H. Shin, C.R. Henry, and C. Louis,
"Characterization and reactivity in CO oxidation of gold nanoparticles
supported on TiO2 prepared by deposition-precipitaion with NaOH and
urea," Journal of Catalysis, vol. 222, pp. 357-367, 2004.
[21] F.W. Chang, L.S Roselin, and T.C. Ou, "Hydrogen production by partial
oxidation of methanol over bimetallic Au-Ru/Fe2O3 catalysts," Applied
Catalysis A: General, vol. 334, pp. 147-155, 2008.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:58783", author = "Umpawan Satitthai and Apanee Luengnaruemitchai and Erdogan Gulari", title = "Effect of Gold Loading on CeO2–Fe2O3 for Oxidative Steam Reforming of Methanol", abstract = "In this study, oxidative steam reforming of methanol (OSRM) over a Au/CeO2–Fe2O3 catalyst prepared by a depositionprecipitation (DP) method was studied to produce hydrogen in order to feed a Proton Exchange Membrane Fuel Cell (PEMFC). The support (CeO2, Fe2O3, and CeO2–Fe2O3) were prepared by precipitation and co-precipitation methods. The impact of the support composition on the catalytic performance was studied by varying the Ce/(Ce+Fe) atomic ratio, it was found that the 1%Au/CF(0.25) calcined at 300 °C exhibited the highest catalytic activity in the whole temperature studied. In addition, the effect of Au content was investigated and 3%Au/CF(0.25) exhibited the highest activity under the optimum condition in the temperature range of 200 °C to 400 °C. The catalysts were characterized by various techniques: XRD, TPR, XRF, and UV-vis.
", keywords = "CeO2, Fe2O3, Gold catalyst, Hydrogen production,
Methanol, Oxidative steam reforming.", volume = "6", number = "4", pages = "337-6", }
