Product Yields and Chemical Compounds of Cogongrass by Pyrolysis in Twin Screw Feeder

Continuous pyrolysis of Cogongrass by control temperature in the novel pyrolysis reactor were conducted at three difference temperatures 400, 450 and 500°C. Preliminary calculate of the product yields founded the liquid yield of Cogongrass was highest of 41.45 %, at 500 oC. Indicated that the liquid yield from Cogongrass had good received yields because it gave over 40 % and its produced more liquid than that solid and gas. The compounds detected in bio-oil from Cogongrass showed the functional group, especially; Phenol, Phenol, 2,5-dimethyl, Phenol, 3-methyl, 2- methyl-1,3-oxathiofane, Benzene,1-ethyl-4-methoxy, 2-Cyclopenten- 1-one,2,3-dimethyl, 2- Cyclopenten-1- one, 3-Methyl.




References:
[1] M. Patel, M. Neelis, D. Gielen, J. Olivier, T. Simmons, and J., Theunis,
"Carbon dioxide emissions from non-energy use of fossil fuels:
Summary of key issues and conclusions from the country analyses,"
Resources, Conservation and Recycling , 45 (3) (2005) 195-209.
[2] M. Garcia-Perez, J. Shen, X. S., Wang, and C-Z Li, "Production and fuel
properties of fast pyrolysis oil/bio-diesel blends," Fuel Processing
Technology, 91 (3) (2010) 296-305.
[3] G. Duman, C. Okutucu, S. Ucar, R. Stahl, and J., Yanik, "The slow and
fast pyrolysis of cherry seed," Bioresource Technology, Vol 102, Issue
2, pp.1869-1878, January 2011.
[4] D. Wu, S. Zhang, J. Xu and T., Zhu, "The CO2 Reduction Effects and
Climate Benefit of Beijing 2008 Summer Olympics Green Practice,"
Energy Procedia, Volume 5, pp. 280-296, April 2011.
[5] Q. Lu, W-Z. Li, and X-F., Zhu, "Overview of fuel properties of
biomass fast pyrolysis oils," Energy Conversion and Management, 50,
pp.1376-1383, May 2009.
[6] H. Li, Q. Xu, H. Xue, and Y., Yan. 2009, "Catalytic reforming of the
aqueous phase derived from fast-pyrolysis of biomass," Renewable
Energy, pp.1-6, April 2009.
[7] H.S. Heo, H.J. Park, J-H. Yim, J.M. Sohn, J.H. Park, S-S. Kim, C.K.
Ryu, J-K. Jeon, and Y-K., Park. "Influence of operation variables on
fast pyrolysis of Miscanthus sinensis var. purpurascens," Bioresource
Technology, Vol 101, Issue 10, 2010, pp.3672-3677.
[8] K. Promdee, T. Vitidsant, and S. Vanpetch. "Comparative study of some
physical and chemical properties of bio-oil from Manila grass and Water
hyacinth transformed by pyrolysis process", International Journal of
Chemical Engineering and Applications, Vol.3, No.1, pp.72-75.
February 2012.
[9] U. Jena, and K. C. Das. "Comparative evaluation of thermochemical
liquefaction and pyrolysis for bio-oil production from microalgae.
Energy fuels", 25 (2011), p. 5472-5482.
[10] S. Sevgi, and D., Angin, "Pyrolysis of safflower (Charthamus tintorius
L.) seed press cake: Part 1. The effect of pyrolysis parameters on the
product yields," Bioresource Technology, 99, pp.5492-5497. September
2008.
[11] S. Sevgi, and D., Angin, "Pyrolysis of safflower (Charthamus tintorius
L.) seed press cake in a fixed-bed reactor: Part 2. Structural
characterization of pyrolysis bio-oils," Bioresource Technology, 99,
pp.5498-5504, September 2008.
[12] P. Duan, and P. E., Savage, "Upgrading of crude algal bio-oil in
supercritical water," Bioresource Technology, Vol 102, pp.1899-1906,
January 2011.
[13] C.A. Mullen, A. Charles, and A., Akwasi, "Chemical Composition of
Bio-oils Produced by Fast Pyrolysis of Two Energy Crops," Energy &
Fuels, pp.2104-2109, April 2008.
[14] P.M. Mortensen, J-D. Grunwaldt, P.A. Jensen, K.G. Knudsen, and A.D.,
Jensen, A review of catalytic upgrading of bio-oil to engine fuels.
Applied Catalysis A: General, Vol 407, Issues 1-2, pp.1-19, August
2011.
[15] R. Razuan, Q. Chen, N.K.Finney, V.N. Russell, N.V. Sharifi, and J.,
Swithenbank. Combustion of oil palm stone in a pilot-scle fluidsed bed
reactor. Fuel Processing Technology, 92 (2011), p. 2219-2225.
[16] L. Mei-kuei, T. Wem-tien; S. Yi-lin and L. Sheau-horng. Pyrolysis of
Napier Grass in an Induction-heating Reactor. Analytical and Applied
Pyrolysis, (2010),Vol 88, Issues 2, pp. 110-116, July 2010.
[17] H. Kazemi Esfeh, B. Ghanavati, and T. GhaleGolabi. "Properties of
modified bitumen obtained from natural bitumen by adding pyrolysis
fuel oil", International Journal of Chemical Engineering and
Applications, Vol.2, No.3, pp.168-172. June 2011.
[18] H. Chen, B. Dou, Y. Song, Y. Xu, Y. Zhang, C. Wang and X. Zhang.
Pyrolysis characteristics of sucrose biomass in a tubular reactor and a
thermogravimetric analysis. Fuel 2012 (95), pp. 425-430.
[19] S. Bilgen, S. Keles and K. Kaygusuz. Calculation of higher and lower
heating values and chemical exergy values of liquid products obtained
from pyrolysis of hazelnut cupulae. Energy 2012, pp. 1-6.
[20] C. LaMarca, B.M. Moreno, and M.T. Klein. Characteristics of optimal
chain transfer solvents for pyrolysis kinetics. Energy & Fuels 2012, 26.
55-57.
[21] Y. Wang, X. Li, D. Mourant, R. Gunawan, S. Zhang, and C-Z. Li.
Formation of aromatic structures during the pyrolysis of bio-oil. Energy
& Fuels 2012, 26. 241-247.
[22] Y. Huang, S Kudo, K. Norinaga, M. Amaike, and J-I Hayashi. Selective
production of light oil by biomass pyrolysis with feedstock-mediated
recycling of heavy oil. Energy & Fuels. 2012, 26. 256-264.