Modification of Anodized Mg Alloy Surface By Pulse Condition for Biodegradable Material
Magnesium is used implant material potentially for
non-toxicity to the human body. Due to the excellent
bio-compatibility, Mg alloys is applied to implants avoiding removal
second surgery. However, it is found commercial magnesium alloys
including aluminum has low corrosion resistance, resulting
subcutaneous gas bubbles and consequently the approach as
permanent bio-materials. Generally, Aluminum is known to pollution
substance, and it raises toxicity to nervous system. Therefore
especially Mg-35Zn-3Ca alloy is prepared for new biodegradable
materials in this study. And the pulsed power is used in
constant-current mode of DC power kinds of anodization. Based on
the aforementioned study, it examines corrosion resistance and
biocompatibility by effect of current and frequency variation. The
surface properties and thickness were compared using scanning
electronic microscopy. Corrosion resistance was assessed via
potentiodynamic polarization and the effect of oxide layer on the body
was assessed cell viability. Anodized Mg-35Zn-3Ca alloy has good
biocompatibility in vitro by current and frequency variation.
[1] J. E. Gray and B. Luan, "Protective coatings on magnesium and its alloys
ÔÇö a critical review," Journal of Alloys and Compounds vol. 336, pp.
88-113, 2002.
[2] H. Kuwahara, N. Mazaki, M. Mabuchi, C. Wein, and T. Aizawa,
"Behavior of magnesium in Hank's solution aimed to trabecular pattern of
natural bone," Materials Science Forum vol. 419-422, pp. 1007-1012
2003.
[3] H. Kuwahara, Y. Al-Abdullat, N. Mazaki, S. Tsutsumi, and T. Aizawa,
"Precipitation of Magnesium Apatite on Pure Magnesium Surface during
Immersing in Hanks solution," Materias transactions vol. 42, pp.
1317-1321 2001.
[4] H. Li, Y. He, and Z. D. Zeng, "A neural network model for prediction on
mechanical properties of QA110-5-5 aluminum bronze after aging,"
Jinshu Rechuli/Heat Treatment of Metals, vol. 31, pp. 28-30, 2006.
[5] V. T. Truong, P. K. Lai, B. T. Moore, R. F. Muscat, and M. S. Russo,
"Corrosion protection of magnesium by electroactive polypyrrole/paint
coatings," Synthetic Metals, vol. 110, pp. 7-15, 2000.
[6] A. A. Voevodin, A. L. Yerokhin, V. V. Lyubimov, M. S. Donley, and J. S.
Zabinski, "Characterization of wear protective Al-Si-O coatings formed
on Al-based alloys by micro-arc discharge treatment " Surface and
Coatings Technology vol. 86-87, pp. 516-521 1996.
[7] W. B. Xue, Z. W. Deng, R. Y. Cheng, and T. H. Zhang, "Growth
regularity of ceramic coatings formed by microarc oxidation on
Al-Cu-Mg alloy " Thin Solid Films, vol. 372, p. 114, 2000.
[8] V. S. Rudnev, T. P. Yarovaya, D. L. Boguta, L. M. Tyrina, P. M.
Nedozorov, and P. S. Gordienko, "Anodic spark deposition of P, Me(II)
or Me(III) containing coatings on aluminium and titanium alloys in
electrolytes with polyphosphate complexes " Journal of Electroanalytical
Chemistry vol. 497, pp. 150-158 2001.
[9] A. L. Yerokhin, A. Leyland, and A. Matthews, "Kinetic aspects of
aluminium titanate layer formation on titanium alloys by plasma
electrolytic oxidation " Applied Surface Science vol. 200, pp. 172-184,
2002.
[10] H. Duan, K. Du, C. Yan, and F. Wang, "Electrochemical corrosion
behavior of composite coatings of sealed MAO film on magnesium alloy
AZ91D," Electrochimica Acta, vol. 51, pp. 2898-2908, 2006.
[11] (1999). Biological evaluation of medical devices. Part 5. Tests for
cytotoxicity: in vitro methods Arlington, VA: ANSI/AAMI ISO 10993-5.
[12] Y. S. Jang, Y. K. Kim, I. S. Park, S. J. Lee, M. H. Lee, J. M. Yoon, and T.
S. Bae, "Film characteristics of anodic oxidized AZ91D magnesium alloy
by applied power," Surface interface analysis, vol. 41, pp. 524-530, 2009.
[13] I. S. Park, Y. S. Jang, Y. K. Kim, M. H. Lee, J. Yoon, and T. S. Bae,
"Surface characteristics of AZ91D alloy anodized with various
conditions," surface and interface analysis, vol. 40, pp. 1270-1277, 2008.
[14] I. Ostrovsky, "Method of anodizing of magnesium and producing
conductive layers on anodized surface," United states Patent, 2003.
[15] N. Kurihara, S. Ishizuka, M. Kiyoki, Y. Haketa , K. Ileda, and M.
Kumegawa "Effects of 1,25-dihydroxyvitamin D3 on osteoblastic
MC3T3-E1 cells," Endocrinology, vol. 118, pp. 940-947, 1986.
[16] S. El-Rahman, "Neuropathology of aluminum toxicity in rats (glutamate
and GABA impairment)," Pharmacological Research, vol. 47, pp.
189-194, 2003.
[17] N. Yumiko, T. Yukari, T. Yasuhide, S. Tadashi, and I. Yoshio,
"Differences in behavior among the chlorides of seven rare earth elements
administered intravenously to rats," Fundam Appl Toxicol, vol. 37, pp.
106-116, 1997.
[1] J. E. Gray and B. Luan, "Protective coatings on magnesium and its alloys
ÔÇö a critical review," Journal of Alloys and Compounds vol. 336, pp.
88-113, 2002.
[2] H. Kuwahara, N. Mazaki, M. Mabuchi, C. Wein, and T. Aizawa,
"Behavior of magnesium in Hank's solution aimed to trabecular pattern of
natural bone," Materials Science Forum vol. 419-422, pp. 1007-1012
2003.
[3] H. Kuwahara, Y. Al-Abdullat, N. Mazaki, S. Tsutsumi, and T. Aizawa,
"Precipitation of Magnesium Apatite on Pure Magnesium Surface during
Immersing in Hanks solution," Materias transactions vol. 42, pp.
1317-1321 2001.
[4] H. Li, Y. He, and Z. D. Zeng, "A neural network model for prediction on
mechanical properties of QA110-5-5 aluminum bronze after aging,"
Jinshu Rechuli/Heat Treatment of Metals, vol. 31, pp. 28-30, 2006.
[5] V. T. Truong, P. K. Lai, B. T. Moore, R. F. Muscat, and M. S. Russo,
"Corrosion protection of magnesium by electroactive polypyrrole/paint
coatings," Synthetic Metals, vol. 110, pp. 7-15, 2000.
[6] A. A. Voevodin, A. L. Yerokhin, V. V. Lyubimov, M. S. Donley, and J. S.
Zabinski, "Characterization of wear protective Al-Si-O coatings formed
on Al-based alloys by micro-arc discharge treatment " Surface and
Coatings Technology vol. 86-87, pp. 516-521 1996.
[7] W. B. Xue, Z. W. Deng, R. Y. Cheng, and T. H. Zhang, "Growth
regularity of ceramic coatings formed by microarc oxidation on
Al-Cu-Mg alloy " Thin Solid Films, vol. 372, p. 114, 2000.
[8] V. S. Rudnev, T. P. Yarovaya, D. L. Boguta, L. M. Tyrina, P. M.
Nedozorov, and P. S. Gordienko, "Anodic spark deposition of P, Me(II)
or Me(III) containing coatings on aluminium and titanium alloys in
electrolytes with polyphosphate complexes " Journal of Electroanalytical
Chemistry vol. 497, pp. 150-158 2001.
[9] A. L. Yerokhin, A. Leyland, and A. Matthews, "Kinetic aspects of
aluminium titanate layer formation on titanium alloys by plasma
electrolytic oxidation " Applied Surface Science vol. 200, pp. 172-184,
2002.
[10] H. Duan, K. Du, C. Yan, and F. Wang, "Electrochemical corrosion
behavior of composite coatings of sealed MAO film on magnesium alloy
AZ91D," Electrochimica Acta, vol. 51, pp. 2898-2908, 2006.
[11] (1999). Biological evaluation of medical devices. Part 5. Tests for
cytotoxicity: in vitro methods Arlington, VA: ANSI/AAMI ISO 10993-5.
[12] Y. S. Jang, Y. K. Kim, I. S. Park, S. J. Lee, M. H. Lee, J. M. Yoon, and T.
S. Bae, "Film characteristics of anodic oxidized AZ91D magnesium alloy
by applied power," Surface interface analysis, vol. 41, pp. 524-530, 2009.
[13] I. S. Park, Y. S. Jang, Y. K. Kim, M. H. Lee, J. Yoon, and T. S. Bae,
"Surface characteristics of AZ91D alloy anodized with various
conditions," surface and interface analysis, vol. 40, pp. 1270-1277, 2008.
[14] I. Ostrovsky, "Method of anodizing of magnesium and producing
conductive layers on anodized surface," United states Patent, 2003.
[15] N. Kurihara, S. Ishizuka, M. Kiyoki, Y. Haketa , K. Ileda, and M.
Kumegawa "Effects of 1,25-dihydroxyvitamin D3 on osteoblastic
MC3T3-E1 cells," Endocrinology, vol. 118, pp. 940-947, 1986.
[16] S. El-Rahman, "Neuropathology of aluminum toxicity in rats (glutamate
and GABA impairment)," Pharmacological Research, vol. 47, pp.
189-194, 2003.
[17] N. Yumiko, T. Yukari, T. Yasuhide, S. Tadashi, and I. Yoshio,
"Differences in behavior among the chlorides of seven rare earth elements
administered intravenously to rats," Fundam Appl Toxicol, vol. 37, pp.
106-116, 1997.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:56416", author = "Y.K. Kim and Y.S. Jang and H.H. Park and J.H. Ji and I.S. Park and T.S. Bae and M.H. Lee", title = "Modification of Anodized Mg Alloy Surface By Pulse Condition for Biodegradable Material", abstract = "Magnesium is used implant material potentially for
non-toxicity to the human body. Due to the excellent
bio-compatibility, Mg alloys is applied to implants avoiding removal
second surgery. However, it is found commercial magnesium alloys
including aluminum has low corrosion resistance, resulting
subcutaneous gas bubbles and consequently the approach as
permanent bio-materials. Generally, Aluminum is known to pollution
substance, and it raises toxicity to nervous system. Therefore
especially Mg-35Zn-3Ca alloy is prepared for new biodegradable
materials in this study. And the pulsed power is used in
constant-current mode of DC power kinds of anodization. Based on
the aforementioned study, it examines corrosion resistance and
biocompatibility by effect of current and frequency variation. The
surface properties and thickness were compared using scanning
electronic microscopy. Corrosion resistance was assessed via
potentiodynamic polarization and the effect of oxide layer on the body
was assessed cell viability. Anodized Mg-35Zn-3Ca alloy has good
biocompatibility in vitro by current and frequency variation.", keywords = "Biodegradable material, Mg, anodization, osteoblast
cell, pulse power.", volume = "6", number = "10", pages = "937-5", }
