Learning Materials of Atmospheric Pressure Plasma Process: Turning Hydrophilic Surface to Hydrophobic
This paper investigates the use of atmospheric pressure plasma for improving the surface hydrophobicity of polyurethane synthetic leather with tetramethylsilane (TMS). The atmospheric pressure plasma treatment with TMS is a single-step process to enhance the hydrophobicity of polyurethane synthetic leather. The hydrophobicity of the treated surface was examined by contact angle measurement. The physical and chemical surface changes were evaluated by scanning electron microscopy (SEM) and infrared spectroscopy (FTIR). The purpose of this paper is to provide learning materials for understanding how to use atmospheric pressure plasma in the textile finishing process to transform a hydrophilic surface to hydrophobic.
[1] D.I. Walsh and J.P. Casey, Synthetic Suede, United State Patent 3973065, 1976.
[2] V. Raballand, J. Benedikt and A. von Keudell, “Deposition of carbon-free silicon dioxide from pure hexamethyldisiloxane using an atmospheric microplasma jet,” Applied Physics Letters, vol. 92, pp. 091502, 2008.
[3] A. Schütze, Y.J. James, E.B. Steven, J. Park, G.S. Selwyn and R.F. Hicks, “The atmospheric-pressure plasma jet: a review and comparison to other plasma sources,” IEEE Transactions on Plasma Science, vol. 26(6), pp. 1685-1694, 1998.
[4] C. Cheng, Z. Liye and R.J. Zhan, “Surface modification of polymer fibre by the new atmospheric pressure cold plasma jet,” Surface and Coatings Technology, vol. 200, pp. 6659-6665, 2005.
[5] L. Zhu, C. Wang and Y. Qiu, “Influence of the amount of absorbed moisture in nylon fibers on atmospheric pressure plasma processing,” Surface and Coatings Technology, vol. 201, pp. 7453-7461, 2007.
[6] J.L.C. Fonseca, D.C. Apperley and J.P.S. Badyal, “Plasma polymerization of tetramethylsilane, Chemistry of Materials, vol. 5, pp. 1676-1682, 1993.
[7] P. Favia, R. Lamendola and R. d’Agostino, “The role of substrate temperature and bias in the plasma deposition from tetramethylsilane. Plasma Sources Science and Technology, vol. 1, pp. 59-66, 1992.
[8] J.L.C. Fonseca, S. Tasker, D.C. Apperley and J.P.S. Badyal, “Plasma-enhanced chemical vapor deposition of organosilicon materials: a comparison of hexamethyldisilane and tetramethylsilane precursors,” Macromolecules, vol. 29, pp. 1705-1710, 1996.
[9] S.Y. Park, H. Kim, U. Hong and H. Sasabe, “Plasma polymerization of hexamethyldisilazane,” Polymer Journal, vol. 22(3), pp. 242-249, 1990.
[10] C.W. Kan and C.W.M. Yuen, “Effect of atmospheric pressure plasma treatment on wettability and dryability of synthetic textile fibres,” Surface and Coatings Technology, vol. 228(S10, pp. S607-S610, 2013.
[11] C.H. Kwong, S.P. Ng, C.W. Kan and R. Molina, “Inducing hydrophobic surface on polyuretahne synthetic leather by atmospheric pressure plasma,” Fibers and Polymers, vol. 15, pp. 1596-1600, 2014.
[12] C.W. Kan, C.H. Kwong and S.P. Ng, “Surface modification of polyester synthetic leather with tetramethylsilane by atmospheric pressure plasma,” Applied Surface Science, vol. 346, 270-277. 2015.
[13] H. Rauscher, M. Perucca and G. Bule, Plasma Technology for Hyperfunctional Surfaces. Weinheim: Wiley-VCH GmbH & Co., 2010.
[14] R. Förch, A. Schönherr and A.T.A. Jenkins, Surface Design: Applications in Bioscience and Nanotechnology. Germany: Wiley-VCH, 2009.
[15] V. Krishnamurthy, I.L. Kamel and Y. Wei, “Fourier transform infrared analysis of plasma-polymerized hexamethyldisiloxane,” Journal of Applied Polymer Science, vol. 38, pp. 605-618, 1989.
[16] N. Inagaki and H. Katsuoka, “Gas separation membrane made by plasma polymerization of mixtures of silanes and fluoromethane, Journal of Membrane Science, vol. 34, pp. 297-305, 1987.
[17] K. Hamada and H. Morishita, “Raman, Infrared and 1H-NMR spectra of hexamethyldisilylchalcogenides, Spectroscopy Letters, vol. 19(7), pp. 815-826, 1986.
[18] P.C. Painter, M.M. Coleman and J.J. Koenig, The Theory of Vibrational Spectroscopy and Its Application to Polymeric Materials, New Yprk: Wiley, 1982.
[19] I. Tajama and M. Yamamoto, M. Characterization of plasma polymers from tetramethylsilane, octamethylcyclotetrasiloxane, and methyltrimethoxysilane. Journal of Polymer Sci. A: Polymer Chemistry, vol. 25(7), pp. 1737-1744, 1987.
[1] D.I. Walsh and J.P. Casey, Synthetic Suede, United State Patent 3973065, 1976.
[2] V. Raballand, J. Benedikt and A. von Keudell, “Deposition of carbon-free silicon dioxide from pure hexamethyldisiloxane using an atmospheric microplasma jet,” Applied Physics Letters, vol. 92, pp. 091502, 2008.
[3] A. Schütze, Y.J. James, E.B. Steven, J. Park, G.S. Selwyn and R.F. Hicks, “The atmospheric-pressure plasma jet: a review and comparison to other plasma sources,” IEEE Transactions on Plasma Science, vol. 26(6), pp. 1685-1694, 1998.
[4] C. Cheng, Z. Liye and R.J. Zhan, “Surface modification of polymer fibre by the new atmospheric pressure cold plasma jet,” Surface and Coatings Technology, vol. 200, pp. 6659-6665, 2005.
[5] L. Zhu, C. Wang and Y. Qiu, “Influence of the amount of absorbed moisture in nylon fibers on atmospheric pressure plasma processing,” Surface and Coatings Technology, vol. 201, pp. 7453-7461, 2007.
[6] J.L.C. Fonseca, D.C. Apperley and J.P.S. Badyal, “Plasma polymerization of tetramethylsilane, Chemistry of Materials, vol. 5, pp. 1676-1682, 1993.
[7] P. Favia, R. Lamendola and R. d’Agostino, “The role of substrate temperature and bias in the plasma deposition from tetramethylsilane. Plasma Sources Science and Technology, vol. 1, pp. 59-66, 1992.
[8] J.L.C. Fonseca, S. Tasker, D.C. Apperley and J.P.S. Badyal, “Plasma-enhanced chemical vapor deposition of organosilicon materials: a comparison of hexamethyldisilane and tetramethylsilane precursors,” Macromolecules, vol. 29, pp. 1705-1710, 1996.
[9] S.Y. Park, H. Kim, U. Hong and H. Sasabe, “Plasma polymerization of hexamethyldisilazane,” Polymer Journal, vol. 22(3), pp. 242-249, 1990.
[10] C.W. Kan and C.W.M. Yuen, “Effect of atmospheric pressure plasma treatment on wettability and dryability of synthetic textile fibres,” Surface and Coatings Technology, vol. 228(S10, pp. S607-S610, 2013.
[11] C.H. Kwong, S.P. Ng, C.W. Kan and R. Molina, “Inducing hydrophobic surface on polyuretahne synthetic leather by atmospheric pressure plasma,” Fibers and Polymers, vol. 15, pp. 1596-1600, 2014.
[12] C.W. Kan, C.H. Kwong and S.P. Ng, “Surface modification of polyester synthetic leather with tetramethylsilane by atmospheric pressure plasma,” Applied Surface Science, vol. 346, 270-277. 2015.
[13] H. Rauscher, M. Perucca and G. Bule, Plasma Technology for Hyperfunctional Surfaces. Weinheim: Wiley-VCH GmbH & Co., 2010.
[14] R. Förch, A. Schönherr and A.T.A. Jenkins, Surface Design: Applications in Bioscience and Nanotechnology. Germany: Wiley-VCH, 2009.
[15] V. Krishnamurthy, I.L. Kamel and Y. Wei, “Fourier transform infrared analysis of plasma-polymerized hexamethyldisiloxane,” Journal of Applied Polymer Science, vol. 38, pp. 605-618, 1989.
[16] N. Inagaki and H. Katsuoka, “Gas separation membrane made by plasma polymerization of mixtures of silanes and fluoromethane, Journal of Membrane Science, vol. 34, pp. 297-305, 1987.
[17] K. Hamada and H. Morishita, “Raman, Infrared and 1H-NMR spectra of hexamethyldisilylchalcogenides, Spectroscopy Letters, vol. 19(7), pp. 815-826, 1986.
[18] P.C. Painter, M.M. Coleman and J.J. Koenig, The Theory of Vibrational Spectroscopy and Its Application to Polymeric Materials, New Yprk: Wiley, 1982.
[19] I. Tajama and M. Yamamoto, M. Characterization of plasma polymers from tetramethylsilane, octamethylcyclotetrasiloxane, and methyltrimethoxysilane. Journal of Polymer Sci. A: Polymer Chemistry, vol. 25(7), pp. 1737-1744, 1987.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:72947", author = "C.W. Kan", title = "Learning Materials of Atmospheric Pressure Plasma Process: Turning Hydrophilic Surface to Hydrophobic", abstract = "This paper investigates the use of atmospheric pressure plasma for improving the surface hydrophobicity of polyurethane synthetic leather with tetramethylsilane (TMS). The atmospheric pressure plasma treatment with TMS is a single-step process to enhance the hydrophobicity of polyurethane synthetic leather. The hydrophobicity of the treated surface was examined by contact angle measurement. The physical and chemical surface changes were evaluated by scanning electron microscopy (SEM) and infrared spectroscopy (FTIR). The purpose of this paper is to provide learning materials for understanding how to use atmospheric pressure plasma in the textile finishing process to transform a hydrophilic surface to hydrophobic.
", keywords = "Learning materials, atmospheric pressure plasma treatment, hydrophobic, hydrophilic, surface.", volume = "10", number = "5", pages = "599-4", }
