High Performance of Hollow Fiber Supported Liquid Membrane to Separate Silver Ions from Medicinal Wastewater
The separation of silver ions from medicinal wastewater via hollow fiber supported liquid membrane (HFSLM) was examined to promote the performance of this technique. The wastewater consisting of 30mg/L silver ions and 120mg/L ferric ions was used as the feed solution. LIX84I dissolving in kerosene and sodium thiosulfate pentahydrate solution were used as the liquid membrane and stripping solution, respectively. In order to access the highest performance of HFSLM, the optimum condition was investigated via several influential variables. Final concentration of silver ions in feed solution was obtained 0.2mg/L which was lower than the discharge limit of Thailand’s mandatory.
[1] Y. Liu, B. Shi, "Hollow fiber supported liquid membrane for extraction of ethylbenzene and nitrobenzene from aqueous solution: A Hansen Solubility Parameter approach,” Sep. Purif. Technol., vol. 65, pp. 233-242, 2009.
[2] R. Güell, E. Anticό, V. Salvadό, C. Fontàs, "Efficient hollow fiber supported liquid membrane system for the removal and preconcentration of Cr(VI) at trace levels,” Sep. Purif. Technol., vol. 62, pp. 389-393, 2008.
[3] C. Fontàs, M. Hidalgo, V. Salvadό, E. Anticό, "Selective recovery and preconcentration of mercury with a benzoylthiourea-solid supported liquid membrane system,” Anal. Chim. Acta, vol. 547, pp. 255-261, 2005.
[4] A. Uheida, Y. Zhang, M. Muhammed, "Transport of palladium(II) through hollow fiber supported liquid membrane facilitated by nonylthiourea,” J. Membr. Sci., vol. 241, pp. 289-295, 2004.
[5] N. S. Rathore, J. V. Sonawane, Anil Kumar, A. K. Venugopalan, R. K. Singh, D. D. Bajpai, J. P. Shukla, "Hollow fiber supported liquid membrane: a novel technique for separation and recovery of plutonium from aqueous acidic wastes,” J. Membr. Sci., vol. 189, pp. 119-128, 2001.
[6] U. Pancharoen, T. Wongsawa, A.W. Lothongkum, "A reaction flux model for extraction of Cu(II) with LIX84I in HFSLM,” Sep. Sci. Technol., vol. 46, pp. 2183-2190, 2011.
[7] S. W. P. Wijnhoven, W. J. G. M. Peijnenburg, C. A. Herberts, W. I. Hagens, A. G. Oomen, E. H. W. Heugens, B. Roszek, J. Bisschops, I. Gosens, D. van de Meent, S. Dekkers, W.H. de Jong, M. van Zijverden, A.J.A.M. Sips, R.E. Geertsma, "Nano-silver – a review of available data and knowledge gaps in human and environmental risk assessment,” Nanotoxicology, vol. 3, no. 2, pp. 109-138, 2009.
[8] S. Altin, Y. Yildirim, A. Altin, "Transport of silver ions through a flat-sheet supported liquid membrane,” Hydrometallurgy, vol. 103, pp. 144-149, 2010.
[9] N. Othman, H. Mat, M. Goto, "Separation of silver from photographic wastes by emulsion liquid membrane system,” J. Membr. Sci., vol. 282, pp. 171-177, 2006.
[10] Amata Nakorn and Amata City Industrial Estate, 1998, "Effluent from factory to central waste water treatment plant (pdf),” available from: <http://www.amatawater.com/upload/waterlawfile/26_Discharge%20from%2031-3-11.pdf>, accessed on 5/1/2012.
[11] B. Sengupta, M.S. Bhakhar, R. Sengupta, "Extraction of zinc and copper-zinc mixtures from ammoniacal solutions into emulsion liquid membranes using LIX84I,” Hydrometallurgy, vol. 99, pp. 25-32, 2009.
[12] N. Alizadeh, S. Salimi, A. Jabbari, "Transport study of palladium through a bulk liquid membrane using hexadecylpyridinium as carrier,” Sep. Purif. Technol., vol. 28, pp. 173- 180, 2002.
[13] A.A. Amiri, A. Safavi, A.R. Hasaninejad, H. Shrghi, M. Shamsipur, "Highly selective transport of silver ion through a supported liquid membrane using calix[4]pyrroles as suitable ion carriers,” J. Membr. Sci., vol. 325, pp. 295-300, 2008.
[1] Y. Liu, B. Shi, "Hollow fiber supported liquid membrane for extraction of ethylbenzene and nitrobenzene from aqueous solution: A Hansen Solubility Parameter approach,” Sep. Purif. Technol., vol. 65, pp. 233-242, 2009.
[2] R. Güell, E. Anticό, V. Salvadό, C. Fontàs, "Efficient hollow fiber supported liquid membrane system for the removal and preconcentration of Cr(VI) at trace levels,” Sep. Purif. Technol., vol. 62, pp. 389-393, 2008.
[3] C. Fontàs, M. Hidalgo, V. Salvadό, E. Anticό, "Selective recovery and preconcentration of mercury with a benzoylthiourea-solid supported liquid membrane system,” Anal. Chim. Acta, vol. 547, pp. 255-261, 2005.
[4] A. Uheida, Y. Zhang, M. Muhammed, "Transport of palladium(II) through hollow fiber supported liquid membrane facilitated by nonylthiourea,” J. Membr. Sci., vol. 241, pp. 289-295, 2004.
[5] N. S. Rathore, J. V. Sonawane, Anil Kumar, A. K. Venugopalan, R. K. Singh, D. D. Bajpai, J. P. Shukla, "Hollow fiber supported liquid membrane: a novel technique for separation and recovery of plutonium from aqueous acidic wastes,” J. Membr. Sci., vol. 189, pp. 119-128, 2001.
[6] U. Pancharoen, T. Wongsawa, A.W. Lothongkum, "A reaction flux model for extraction of Cu(II) with LIX84I in HFSLM,” Sep. Sci. Technol., vol. 46, pp. 2183-2190, 2011.
[7] S. W. P. Wijnhoven, W. J. G. M. Peijnenburg, C. A. Herberts, W. I. Hagens, A. G. Oomen, E. H. W. Heugens, B. Roszek, J. Bisschops, I. Gosens, D. van de Meent, S. Dekkers, W.H. de Jong, M. van Zijverden, A.J.A.M. Sips, R.E. Geertsma, "Nano-silver – a review of available data and knowledge gaps in human and environmental risk assessment,” Nanotoxicology, vol. 3, no. 2, pp. 109-138, 2009.
[8] S. Altin, Y. Yildirim, A. Altin, "Transport of silver ions through a flat-sheet supported liquid membrane,” Hydrometallurgy, vol. 103, pp. 144-149, 2010.
[9] N. Othman, H. Mat, M. Goto, "Separation of silver from photographic wastes by emulsion liquid membrane system,” J. Membr. Sci., vol. 282, pp. 171-177, 2006.
[10] Amata Nakorn and Amata City Industrial Estate, 1998, "Effluent from factory to central waste water treatment plant (pdf),” available from: <http://www.amatawater.com/upload/waterlawfile/26_Discharge%20from%2031-3-11.pdf>, accessed on 5/1/2012.
[11] B. Sengupta, M.S. Bhakhar, R. Sengupta, "Extraction of zinc and copper-zinc mixtures from ammoniacal solutions into emulsion liquid membranes using LIX84I,” Hydrometallurgy, vol. 99, pp. 25-32, 2009.
[12] N. Alizadeh, S. Salimi, A. Jabbari, "Transport study of palladium through a bulk liquid membrane using hexadecylpyridinium as carrier,” Sep. Purif. Technol., vol. 28, pp. 173- 180, 2002.
[13] A.A. Amiri, A. Safavi, A.R. Hasaninejad, H. Shrghi, M. Shamsipur, "Highly selective transport of silver ion through a supported liquid membrane using calix[4]pyrroles as suitable ion carriers,” J. Membr. Sci., vol. 325, pp. 295-300, 2008.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:65553", author = "Thidarat Wongsawa and Ura Pancharoen and Anchaleeporn Waritswat Lothongkum", title = "High Performance of Hollow Fiber Supported Liquid Membrane to Separate Silver Ions from Medicinal Wastewater", abstract = "The separation of silver ions from medicinal wastewater via hollow fiber supported liquid membrane (HFSLM) was examined to promote the performance of this technique. The wastewater consisting of 30mg/L silver ions and 120mg/L ferric ions was used as the feed solution. LIX84I dissolving in kerosene and sodium thiosulfate pentahydrate solution were used as the liquid membrane and stripping solution, respectively. In order to access the highest performance of HFSLM, the optimum condition was investigated via several influential variables. Final concentration of silver ions in feed solution was obtained 0.2mg/L which was lower than the discharge limit of Thailand’s mandatory.
", keywords = "Hollow fiber, Liquid membrane, Separation, Silver ions.", volume = "7", number = "11", pages = "829-5", }
