Compost quality Management by Adding Sulfuric Acid and Alkaline Wastewater of Paper Mill as two Amendments

In composting process, N high-organic wastes loss the great part of its nitrogen as ammonia; therefore, using compost amendments can promote the quality of compost due to the decrease in ammonia volatilization. With regard to the effect of pH on composting, microorganisms- activity and ammonia volatilization, sulfuric acid and alkaline wastewater of paper mill (as liming agent with Ca and Mg ions) were used as compost amendments. Study results indicated that these amendments are suitable for reclamation of compost quality properties. These held nitrogen in compost caused to reduce C/N ratio. Both amendments had a significant effect on total nitrogen, but it should be used sulfuric acid in fewer amounts (20 ml/kg fresh organic wastes); and the more amounts of acid is not proposed.




References:
[1] Y.K. Jeong and J. S. Kim. "A new method for conservation of nitrogen
in aerobic composting processes". Bioresour. Technology, no. 79, pp.
129-133. 2001.
[2] M.S. Switzenbaum, C. Holden, H. Soares and G. A. Kuter. "Effect of
amendments on nitrogen conservation in wastewater biosolid
composting". Compost Sci. Utilization, vol. 2, no. 2, pp. 35-42, 1994.
[3] N. Morisaki, C. G. Phae, K. Nakasaki, M. Shoda and H. Kubota.
"Nitrogen transformation during thermophilic composting". J. Ferment.
Bioeng., no. 67, pp. 57-61, 1989.
[4] Y. Eklind, and H. Kirchmann. "Composting and storage of organic
household waste with different litter amendments". II. Nitrogen turnover
and losses. Bioresour. Technol., vol. 74, no. 2, pp. 125-133, 2000.
[5] E. Witter, and J. Lopez-Real., "Nitrogen losses during the composting of
sewage sludge, and the effectiveness of clay soil, zeolite, and compost in
adsorbing the volatilized ammonia". Biol. Wastes, vol. 23, no. 4, pp.
279-294. 1988.
[6] R.C. Hansen, H.M. Keener, H.A.J. Hoitink. "Poultry manure
composting: Design guidelines for ammonia". ASAE paper, No. 89-
4075. ASAE, St. Joseph, MI. 10p. 1989.
[7] M.T. Baca, F. Fornasier, M. De Nobili. "Mineralization and
humification pathways in two composting process applied to cotton
wastes". J. Ferment. Bioeng. vol. 74, no. 3, pp. 179-184, 1992.
[8] N. Brink, "Composting of food waste with straw and other carbon
sources for nitrogen catching". Acta. Agric. Scandinavica-Section B Soil
Plant Sci. vol. 45, pp. 118-123, 1995.
[9] S. Mahimairaja, N.S. Bolan, M.J. Hedley, A.N. "Macgregor. Losses and
transformation of nitrogen during composting of poultry manure with
different amendments: an incubation experiment". Bioresour. Technol.
Vol. 47, no. 3, pp. 265-273, 1994.
[10] Y. Liang, J. J. Leonard, J. J. R. Feddes and W. B. McGill. "Influence of
carbon and buffer amendment on ammonia volatilization in
composting". Bioresour. Technol., vol. 97, pp. 748-761. 2006.
[11] S. Subair, J. W. Fyles and I. P. O,Halloran. "Ammonia volatilization
from liquid hog manure amended with paper products in the laboratory".
J. Environ. Qual. Vol. 28, pp. 202-207. 1999.
[12] M. Meyer, and H. Sticher. "The significance of straw content for the
retention of nitrogen during the composting of cattle manure". Z.
Pflanzenernaehr. Bodenk no. 46, pp. 199-206. 1983.
[13] R. Singh and Pradhan, K. "Determination of nitrogen and protein by
Kjeldahl method. In: Forage Evaluation Science". Pvt. Publishers Ltd.,
New Delhi, p. 23. 1981.
[14] J.A. Walkey and J.A. Black. "Estimation of organic carbon by the
chromic acid titration method". Soil Sci. vol. 37, pp. 29-31. 1934
[15] P.F. "Storm. Effect of temperature on bacterial species diversity in
thermophilic solid-waste composting". Appl. Environ. Microbiol. Vol.
50, no. 4, pp. 899-905. 1985.
[16] B. Xi, G. Zhang and H. Liu. "Process kinetics of inoculation composting
of municipal solid waste". J. Hazard. Mat. B124, pp. 165-172. 2005.
[17] J.R. Freney, J. R. Simpson and O. T. Denmead. "Volatilization of
ammonia. In: Freney, J. R., J. R. Simpson (Eds.), Gaseous Loss of Nitrogen from Plant-Soil Systems". Martinus Nijhoff/Dr. W. Junk
Publishers, Hingham, MA, pp. 1-32. 1983.
[18] K. Nakasaki, H. Yaguchi, Y. Sasaki and H. Kubota. "Effects of pH
control on composting of garbage". Waste Manag. Res., vol. 11, pp.
117-125. 1993.
[19] D.S. Carey, H. M. Keener and D. L. Elwell. "The effect of ammonium
sulfate addition to partially to composted poultry manure". ASAE paper.
No. 98-4099. St. Joseph, MI. 20p. 1998.
[20] K. Ekinci, H. M. Keener and D. L. Elwell. "Composting short paper
fiber with broiler litter and additives: I. Effect of initial pH and
carbon/nitrogen ratio on ammonia emission". Composting Sci. Utiliz.
Vol. 8, pp. 160-172. 2000.
[21] M. Kithom, J. W. Paul and A. A. Bomke. "Reducing nitrogen losses
during simulated composting of poultry manure using absorbents or
chemical amendments". J. Environ. Qual. 28: 194-201.1999.
[22] E. Witter and H. Kirchmann. "Effects of addition of calcium and
magnesium salts on ammonia volatilization during manure composting".
Plant and Soil, vol. 115, pp. 53-58. 1989.
[23] K.N. Ohliger, T. M. Young and E. D. Schroeder. "Kinetics effects on
preferential struvite accumulation in wastewater". J. Environ.
Engineering ASCE, vol. 125, no. 8, pp. 730-737. 1999.