CO2 Sequestration Potential of Construction and Demolition Alkaline Waste Material in Indian Perspective

In order to avoid the potentially devastating consequences of global warming and climate change, the carbon dioxide “CO2" emissions caused due to anthropogenic activities must be reduced considerably. This paper presents the first study examining the feasibility of carbon sequestration in construction and demolition “C&D" waste. Experiments were carried out in a self fabricated Batch Reactor at 40ºC, relative humidity of 50-70%, and flow rate of CO2 at 10L/min for 1 hour for water-to-solids ratio of 0.2 to 1.2. The effect of surface area was found by comparing the theoretical extent of carbonation of two different sieve sizes (0.3mm and 2.36mm) of C&D waste. A 38.44% of the theoretical extent of carbonation equating to 4% CO2 sequestration extent was obtained for C&D waste sample for 0.3mm sieve size. Qualitative, quantitative and morphological analyses were done to validate carbonate formation using X-ray diffraction “X.R.D.," thermal gravimetric analysis “T.G.A., “X-Ray Fluorescence Spectroscopy “X.R.F.," and scanning electron microscopy “S.E.M".




References:
[1] IPCC Fourth Assessment Report, Summary for Policymakers, Climate
Change 2007: Impacts, Adaptation and Vulnerability (WGII), (April
2007).
[2] IEA GHG. A regional assessment of the potential for CO2 storage in the
Indian Subcontinent. IEAGHG R&D Programme Report, International
Energy Agency Greenhouse Gas R&D Programme, Cheltenham, UK,
2008.
[3] U.S. Department of Energy, Carbon Sequestration Technology Roadmap
and Program Plan 2005, Developing the Technology Base and
Infrastructure to Enable Sequestration as a Greenhouse Gas Mitigation
Option, May 2005.
[4] W.J.J. Huijgen, and R.N.J. Comans, "Carbon Dioxide Sequestration by
Mineral Carbonation Literature Review, Energy Resource Center of the
Netherlands", ECNC-03-016, 2003.retrieved on 29.12.2010.
[5] D.J. Fauth, Y. Soong, and C.M.White, "Carbon Sequestration Utilizing
Industrial Solid Residues", Symposium-American Chemical Society,
Division Fuel Chemistry, pp. 37-38, 2002.
[6] M.F. Bertos, X. Li, S.J.R. Simons, C.D. Hills, and P.J. Carey,
"Investigation of Acceleration Carbonation for the Stabilisation of MSW
Incinerator Ashes and the Sequestration of CO2", Green Chemistry, vol.
6, pp. 428-436, 2004a.
[7] M.F. Bertos, X. Li, S.J.R. Simons, C.D. Hills, and P.J. Carey, "A Review
of Accelerated Carbonation Technology in the Treatment of Cement-
Based Materials and Sequestration of CO2", J. Hazardous Materials, B
112, pp. 193-205, 2004b.
[8] W.J.J. Huijgen, G.J. Witkamp, and R.N.J. Comans, "Mineral CO2
Sequestration by Steel Slag Carbonation, Environmental Science and
Technology", vol 39 (42), pp. 9676-9682, 2005.
[9] V.W.Y. Tam, and C.M. Tam, "Evaluation of existing waste recycling
methods: a Hong Kong study. Building and Environment", vol 41(12),
pp1649-60, 2006.
[10] CPCB, Status of Municipal Solid Waste Generation, Collection
Treatment, and Disposable in Class 1 Cities. Central Pollution Control
Board, Ministry of Environmental and Forests, Governments of India,
New Delhi, 2000.
[11] Environmental Protection Department (EPD). Monitoring of Solid Waste
in Hong Kong; 1998.
[12] L.Y. Shen, V.W.Y. Tam, C.M. Tam, and D. Drew, "Mapping approach
for examining waste management on construction sites", J. Construction
Engineering and Management, vol 130(4), pp.472-81, 2004.
[13] V.W.Y. Tam, and C.M. Tam, "Waste reduction through incentives: a
case study. Building Research and Information", vol 36(1),pp.37-
43,2008.
[14] S.R. Asolekar, "Incorporation of waste matrixes into building materials
in the context of regulatory framework. In: M.Saxena, P.K. Pasad, and
R. Dasgupta, editors. Proceedings of the recent trends in building
materials. Bhopal, India: MRSI, and RR , pp. 66-75,2004.
[15] M. Saxena, and P. Asokan, "Timber substitute products from industrial
solid wastes. In: Rajisnish Srivastava, editor. Proceedings of the 18th
national convention of environmental engineers and national seminar on
solid waste management, Bhopal, India", pp. 192-200, 2002
[16] B.A.G. Bossink, and H.J.H. Brouwers, "Construction waste:
quantification and source evaluation", J. Construction Engineering
Management, vol 122(1), pp.55-60, 1996.
[17] U.S. Environmental Protection Agency (EPA). Waste Wise Update:
Building For the Future; 2002. Available from http://www.epa.gov/
wastewise/pubs/wwupda16.pdf, accessed on 29.12.2010
[18] C. McGrath and M. Anderson, Waste minimizing on a construction site.
Building Research Establishment Digest no 447, 2000.
[19] N. Bell, Waste minimization and resource recovery. The environmental
design guide Gen 21, vol. 2. Canberra: Royal Australian Institute of
Architects, 1998.
[20] C.S. Poon, "Reducing construction waste", J. Waste Management, vol
27(12), pp. 1715-6, 2007.
[21] ASTM E 104-02 http://www.labthink.cn/service/iso.aspx?id=319,
accessed on 30.12.2010.
[22] H.H. Steinour, "Some Effects of Carbon Dioxide on Motars and
Concrete - Discussion, Concrete Briefs", J. American Concrete
Institute, pp. 905-907, February1959.
[23] D. Gallego, N. Higuita, F. Garcia, N. Ferrell, J. Derek, and D.J.
Hansford, "Bioactive coatings on Portland cement substrates: Surface
precipitation of apatite-like crystals", J. Materials Science and
Engineering, vol 28(3),pp. 347-352,2008.