Magnetic carbon nanotubes composites were obtained
by filling carbon nanotubes with paramagnetic iron oxide particles.
Detailed investigation of magnetic behaviour of resulting composites
was done at different temperatures. Measurements indicate that these
functionalized nanotubes are superparamagnetic at room temperature;
however, no superparamagnetism was observed at 125 K and 80 K.
The blocking temperature TB was estimated at 145 K. These magnetic
carbon nanotubes have the potential of being used in a wide range of
applications, in particular, the production of nanofluids, which can be
controlled and steered by appropriate magnetic fields.
[1] Iijima, S. Helical microtubules of graphitic carbon, Nature, vol.354,
1991, pp.56-58.
[2] Dresselhaus, M.; Dresselhaus, G.; Jorio, A. Unusual properties and
structure of carbon nanotubes. Annu. Rev. Meter. Res. 2004, 34, 247-
278.
[3] Kornev, K.; Halverson, D.; Korneva, G.; Gogotsi , Y.;Friedman, G.
Magnetostatic interactions between carbon nanotubes filled with
magnetic nanoparticles.Appl. Phys. Lett. 2008, 92, 233117.
[4] Godson, L.; Raja, B.; Mohan Lal, D.; Wongwises, S.Enhancement of
heat transfer using nanofluids - An overview. Renewable and
sustainable energy reviews 2010, 14, 629-641.
[5] Saidur R.; Leong K.; Mahammad H. Renewable and sustainable energy
reviews 2011, 15, 1646-1668.
[6] Ajayan, P. M. and Iijima, S. Capillarity-Induced filling of carbon
nanotubes. Nature 1993, 361, 333-334.
[7] Dujardin, E.; Ebbesen, T. W.; Hiura, H.; Tanigaki, K. Capillarity and
Wetting of Carbon Nanotubes, Science 1994, 265 (5180), 1850-1852.
[8] Ugarte, D.; Chatelain, A.; de Heer, W. A. Nanocapillarity and Chemistry
on Carbon Nanotubes, Science 1996, 274 (5294), 1897-1899.
[9] Wu, H.; Wei, X.; Shao, M.; Gu, J.; Qu, M. Preparation of Fe-Ni Alloy
Nanoparticles Inside Carbon Nanotubes via Wet Chemistry. J. Mater.
Chem. 2002, 12, 6, 1919-1921.
[10] Leonhardt, A.; Ritschel, A.; Kozhuharova, R.; Graff, A.; Muhl, T.;
Huhle, R.; Monch, I.; Elefant, D.; Schneider, C. Synthesis and
Properties of Filled Carbon Nanotubes, Diamond Relat. Mater. 2003, 12,
3-7, 790-793.
[11] Ebbesen, T. Wetting filling and decorating carbon nanotubes. Phys
Chem Solids 1996, 57 (6-8), 951-955.
[12] Korneva, G.; Ye, H.; Gogotsi, Y.; Halverson, D.;Friedman, G.; Bradley,
J.; Kornev K. Carbon nanotubes loaded with magnetic particles. Nano
letters 2005, 5, 5,879-884.
[13] Pal, S.; Chandra, S.; Phan, M.-H.; Mukherjee, P.; Srikanth, H. Carbon
nanostraws. Nanotubes filled with superparamagnetic nanoparticles.
Nanotechnology 2009, 20, 48, 485604 (7pp).
[14] Mattia, D.; Gogotsi, Y. Review: static and dynamic behaviour of liquids
inside carbon nanotubes. Microfluid Nanofluid 2008, 5: 289-305.
[15] Kopyl, S.; Bystrov, V.; Maiorov, M.; Bdikin, I.; Sousa, ACM. Filling
the carbon nanotubes with magnetic particles. J. Mater. Chem. 2012
(submitted).
[16] Qiang, F.; Weinberg, G.; Dang-Sheng, S. Selective filling of carbon
nanotubes with metals by selective washing. New carbon materials.
2008, 23 (1), 17-20.
[17] Tessonnier, J.-P.; Ersen, O.; Weinberg, G.; Pham-Huu, C.; Su, D. S.;
Schlögl, R.; Selective Deposition of Metal Nanoparticles Inside or
Outside Multiwalled Carbon Nanotubes, ACS Nano 2009, 3, 2081-2089.
[18] Tan, F.; Fan, X.; Zhang, G.; Zhang, F. Coating and filling of carbon
nanotubes with homogeneous magnetic nanoparticles. Materials letters
2007, 61, 1805-1808.
[19] Fonseca, F.; Goya, G.; Jardim, R.; Muccillo, R.; Carreno, V.; Longo, E.;
Leite, E. Superparamagnetizm and magnetic properties of Ni
nanoparticles embedded in SiO2. PHYSICAL REVIEW B 2002, 66,
104406.
[20] Salado, J.; Insausti, M.; Lesama, L.; Muro, I.G.; Goikolea, E.; Rojo, T.
Preparation and Characterization of Monodisperse Fe3O4
Nanoparticles: An Electron Magnetic Resonance Study. Chem. Mater.
2011, 23, 2879-2885.
[21] Majetich, SA.; Sachan, M. Magnetostatic interactions in magnetic
nanoparticle assemblies: energy, time and length scales. J. Phys. D:
Appl. Phys. 2006, 39,R407- R422.
[22] Vonsovskij, S.V. Magnetizm. M.:Nauka (rus), 1971, 805 p.
[1] Iijima, S. Helical microtubules of graphitic carbon, Nature, vol.354,
1991, pp.56-58.
[2] Dresselhaus, M.; Dresselhaus, G.; Jorio, A. Unusual properties and
structure of carbon nanotubes. Annu. Rev. Meter. Res. 2004, 34, 247-
278.
[3] Kornev, K.; Halverson, D.; Korneva, G.; Gogotsi , Y.;Friedman, G.
Magnetostatic interactions between carbon nanotubes filled with
magnetic nanoparticles.Appl. Phys. Lett. 2008, 92, 233117.
[4] Godson, L.; Raja, B.; Mohan Lal, D.; Wongwises, S.Enhancement of
heat transfer using nanofluids - An overview. Renewable and
sustainable energy reviews 2010, 14, 629-641.
[5] Saidur R.; Leong K.; Mahammad H. Renewable and sustainable energy
reviews 2011, 15, 1646-1668.
[6] Ajayan, P. M. and Iijima, S. Capillarity-Induced filling of carbon
nanotubes. Nature 1993, 361, 333-334.
[7] Dujardin, E.; Ebbesen, T. W.; Hiura, H.; Tanigaki, K. Capillarity and
Wetting of Carbon Nanotubes, Science 1994, 265 (5180), 1850-1852.
[8] Ugarte, D.; Chatelain, A.; de Heer, W. A. Nanocapillarity and Chemistry
on Carbon Nanotubes, Science 1996, 274 (5294), 1897-1899.
[9] Wu, H.; Wei, X.; Shao, M.; Gu, J.; Qu, M. Preparation of Fe-Ni Alloy
Nanoparticles Inside Carbon Nanotubes via Wet Chemistry. J. Mater.
Chem. 2002, 12, 6, 1919-1921.
[10] Leonhardt, A.; Ritschel, A.; Kozhuharova, R.; Graff, A.; Muhl, T.;
Huhle, R.; Monch, I.; Elefant, D.; Schneider, C. Synthesis and
Properties of Filled Carbon Nanotubes, Diamond Relat. Mater. 2003, 12,
3-7, 790-793.
[11] Ebbesen, T. Wetting filling and decorating carbon nanotubes. Phys
Chem Solids 1996, 57 (6-8), 951-955.
[12] Korneva, G.; Ye, H.; Gogotsi, Y.; Halverson, D.;Friedman, G.; Bradley,
J.; Kornev K. Carbon nanotubes loaded with magnetic particles. Nano
letters 2005, 5, 5,879-884.
[13] Pal, S.; Chandra, S.; Phan, M.-H.; Mukherjee, P.; Srikanth, H. Carbon
nanostraws. Nanotubes filled with superparamagnetic nanoparticles.
Nanotechnology 2009, 20, 48, 485604 (7pp).
[14] Mattia, D.; Gogotsi, Y. Review: static and dynamic behaviour of liquids
inside carbon nanotubes. Microfluid Nanofluid 2008, 5: 289-305.
[15] Kopyl, S.; Bystrov, V.; Maiorov, M.; Bdikin, I.; Sousa, ACM. Filling
the carbon nanotubes with magnetic particles. J. Mater. Chem. 2012
(submitted).
[16] Qiang, F.; Weinberg, G.; Dang-Sheng, S. Selective filling of carbon
nanotubes with metals by selective washing. New carbon materials.
2008, 23 (1), 17-20.
[17] Tessonnier, J.-P.; Ersen, O.; Weinberg, G.; Pham-Huu, C.; Su, D. S.;
Schlögl, R.; Selective Deposition of Metal Nanoparticles Inside or
Outside Multiwalled Carbon Nanotubes, ACS Nano 2009, 3, 2081-2089.
[18] Tan, F.; Fan, X.; Zhang, G.; Zhang, F. Coating and filling of carbon
nanotubes with homogeneous magnetic nanoparticles. Materials letters
2007, 61, 1805-1808.
[19] Fonseca, F.; Goya, G.; Jardim, R.; Muccillo, R.; Carreno, V.; Longo, E.;
Leite, E. Superparamagnetizm and magnetic properties of Ni
nanoparticles embedded in SiO2. PHYSICAL REVIEW B 2002, 66,
104406.
[20] Salado, J.; Insausti, M.; Lesama, L.; Muro, I.G.; Goikolea, E.; Rojo, T.
Preparation and Characterization of Monodisperse Fe3O4
Nanoparticles: An Electron Magnetic Resonance Study. Chem. Mater.
2011, 23, 2879-2885.
[21] Majetich, SA.; Sachan, M. Magnetostatic interactions in magnetic
nanoparticle assemblies: energy, time and length scales. J. Phys. D:
Appl. Phys. 2006, 39,R407- R422.
[22] Vonsovskij, S.V. Magnetizm. M.:Nauka (rus), 1971, 805 p.
@article{"International Journal of Chemical, Materials and Biomolecular Sciences:62835", author = "Svitlana Kopyl and Vladimir Bystrov and Mikhail Maiorov and Manuel Valente and Igor Bdikin and Antonio C.M. Sousa", title = "Carbon Nanotubes with Magnetic Particles", abstract = "Magnetic carbon nanotubes composites were obtained
by filling carbon nanotubes with paramagnetic iron oxide particles.
Detailed investigation of magnetic behaviour of resulting composites
was done at different temperatures. Measurements indicate that these
functionalized nanotubes are superparamagnetic at room temperature;
however, no superparamagnetism was observed at 125 K and 80 K.
The blocking temperature TB was estimated at 145 K. These magnetic
carbon nanotubes have the potential of being used in a wide range of
applications, in particular, the production of nanofluids, which can be
controlled and steered by appropriate magnetic fields.", keywords = "carbon nanotubes, magnetic nanoparticles,
magnetization, nanofluids", volume = "6", number = "7", pages = "625-6", }
