Ammonia Removal from Nitrogenous Industrial Waste Water Using Iranian Natural Zeolite of Clinoptilolite Type
Ammonia nitrogen is one of the most hazardous
water pollutants, discharging into water receptors through industrial
effluents. Negative environmental impacts of such chemical species
in hydrosphere include accelerated eutrophication, water toxicity and
harming the aquatics. Natural zeolite clinoptilolite has very high
selectivity & capacity for ammonium cation sorption. It occurs in
high abundances and rich mines of this zeolite exist in different parts
of Iran and thus are available more cheaply and with different sizing.
The aim of this study is to investigate ammonia nitrogen removal
over this natural sorbent from real samples of high polluted
wastewater discharging from a fertilizer producing plant. The
experimental results showed that this natural sorbent without even
any pre treatment system & with the same particle size available in
Iranian markets has still high capability & selectivity in ammonia
nitrogen removal both in batch and continuous tests.
[1] Y. Wang, Sh. Liu, S. Chuan, Z. Xu, T. Han, and T. Zhu, "Ammonia
removal from leachate solution using natural Chinese clinoptilolite," J.
Hazard. Mater., vol. 136, pp. 735-740, 2006.
[2] AR. Rahmani, S. Nasseri, AR. Mesdaghinia, and AH. Mahvi,
"Investigation of ammonia removal from polluted waters by
Clinoptilolite zeolite," Inter. J. Envi. Sci. and Tech., vol. 1, pp. 125-133,
2004.
[3] N. Keyvani, Regulations & Environmental Standards in Human
Environment Field. Iran Enviromental Protection Agancy, 2008, pp. 45-
54.
[4] A. Zorpas, V. Inglezakis, M. Stylianou, V. Irene, "Sustainable Treatment
Method of a High Concentrated NH3 Wastewater by Using Natural
Zeolite in Closed-Loop Fixed Bed Systems," Open Envi. Sci., vol. 3, pp.
70-76, 2009.
[5] MI. Nguyen, CC. Tanner, "Ammonium removal from wastewaters using
natural New Zealand zeolites," New Zealand. J. Agri. Res., vol. 41, pp.
427-446, 1998.
[6] M. Sarioglu, "Removal of ammonium from municipal wastewater using
natural Turkish (Dogantepe) zeolite," Sep. Pur. Tech., vol. 41, pp. 1-11,
2005.
[7] D. Karadag, Y. Kok, M. Turan, B. Armagan, "Removal of ammonium
ion from aqueous solution using natural Turkish clinoptilolite," J.
Hazard. Mater., vol. 136, pp. 604-609, 2006.
[8] LR. Weatherly, ND. Miladinovic, "Comparison of the ion exchange
uptake of ammonium ion onto New Zealand clinoptilolite and
mordenite," Water Res., vol. 38, pp. 4305-4312, 2004.
[9] Y.-F. Wang, F. Lina, W.-Q. Pang, "Ammonium exchange in aqueous
solution using Chinese natural clinoptilolite and modified zeolite," J.
Hazard. Mater., vol. 142, pp. 160-164, 2007.
[10] Q. Du, Sh. Liu, Zh. Cao, Y. Wang, "Ammonia removal from aqueous
solution using natural Chinese clinoptilolite," Sep. Pur. Tech., vol. 44,
pp. 229-234, 2005.
[11] TC. Jorgensen, LR. Weatherly, "Ammonia removal from wastewater by
ion exchange in the presence of organic contaminants," Water Res., vol.
37, pp. 1723-1728, 2003.
[1] Y. Wang, Sh. Liu, S. Chuan, Z. Xu, T. Han, and T. Zhu, "Ammonia
removal from leachate solution using natural Chinese clinoptilolite," J.
Hazard. Mater., vol. 136, pp. 735-740, 2006.
[2] AR. Rahmani, S. Nasseri, AR. Mesdaghinia, and AH. Mahvi,
"Investigation of ammonia removal from polluted waters by
Clinoptilolite zeolite," Inter. J. Envi. Sci. and Tech., vol. 1, pp. 125-133,
2004.
[3] N. Keyvani, Regulations & Environmental Standards in Human
Environment Field. Iran Enviromental Protection Agancy, 2008, pp. 45-
54.
[4] A. Zorpas, V. Inglezakis, M. Stylianou, V. Irene, "Sustainable Treatment
Method of a High Concentrated NH3 Wastewater by Using Natural
Zeolite in Closed-Loop Fixed Bed Systems," Open Envi. Sci., vol. 3, pp.
70-76, 2009.
[5] MI. Nguyen, CC. Tanner, "Ammonium removal from wastewaters using
natural New Zealand zeolites," New Zealand. J. Agri. Res., vol. 41, pp.
427-446, 1998.
[6] M. Sarioglu, "Removal of ammonium from municipal wastewater using
natural Turkish (Dogantepe) zeolite," Sep. Pur. Tech., vol. 41, pp. 1-11,
2005.
[7] D. Karadag, Y. Kok, M. Turan, B. Armagan, "Removal of ammonium
ion from aqueous solution using natural Turkish clinoptilolite," J.
Hazard. Mater., vol. 136, pp. 604-609, 2006.
[8] LR. Weatherly, ND. Miladinovic, "Comparison of the ion exchange
uptake of ammonium ion onto New Zealand clinoptilolite and
mordenite," Water Res., vol. 38, pp. 4305-4312, 2004.
[9] Y.-F. Wang, F. Lina, W.-Q. Pang, "Ammonium exchange in aqueous
solution using Chinese natural clinoptilolite and modified zeolite," J.
Hazard. Mater., vol. 142, pp. 160-164, 2007.
[10] Q. Du, Sh. Liu, Zh. Cao, Y. Wang, "Ammonia removal from aqueous
solution using natural Chinese clinoptilolite," Sep. Pur. Tech., vol. 44,
pp. 229-234, 2005.
[11] TC. Jorgensen, LR. Weatherly, "Ammonia removal from wastewater by
ion exchange in the presence of organic contaminants," Water Res., vol.
37, pp. 1723-1728, 2003.
@article{"International Journal of Earth, Energy and Environmental Sciences:62013", author = "M.M. Jafarpour and Ar. Foolad and M.K. Mansouri and Z. Nikbakhsh and H. Saeedizade", title = "Ammonia Removal from Nitrogenous Industrial Waste Water Using Iranian Natural Zeolite of Clinoptilolite Type", abstract = "Ammonia nitrogen is one of the most hazardous
water pollutants, discharging into water receptors through industrial
effluents. Negative environmental impacts of such chemical species
in hydrosphere include accelerated eutrophication, water toxicity and
harming the aquatics. Natural zeolite clinoptilolite has very high
selectivity & capacity for ammonium cation sorption. It occurs in
high abundances and rich mines of this zeolite exist in different parts
of Iran and thus are available more cheaply and with different sizing.
The aim of this study is to investigate ammonia nitrogen removal
over this natural sorbent from real samples of high polluted
wastewater discharging from a fertilizer producing plant. The
experimental results showed that this natural sorbent without even
any pre treatment system & with the same particle size available in
Iranian markets has still high capability & selectivity in ammonia
nitrogen removal both in batch and continuous tests.", keywords = "Ammonia nitrogen removal, Clinoptilolite, Naturalzeolite, Waste water.", volume = "4", number = "10", pages = "479-7", }