Abstract: Fly ash-slag based Geopolymer Cement (GPC) is presenting mechanical properties and environmental advantages that make it the predominant “green” alternative to Portland Cement (PC). Although numerous life-cycle analyses praising its environmental advantages, disposal after the end of its life remains as an issue that has been barely explored. The present study is investigating the recyclability of fly ash-slag GPC as aggregate in mortars. The purpose of the study was to evaluate the effect of GPC fine Recycled Aggregates (RA), at replacement levels of 25% and 50%, on the main mechanical properties of PC and GPC mortar mixes. The results were compared with those obtained by corresponding mixes incorporating natural and PC-RA. The main physical properties of GPC-RA were examined and proven to be comparable to those of PC-RA and slightly inferior to those of natural sand. A negligible effect was observed at 28-day compressive and flexural strength of PC mortars with GPC aggregates having a milder effect than PC. As far as GPC mortars are concerned, the influence of GPC aggregates was enhancing for the investigated mechanical properties. Additionally, a screening test showed that recycled geopolymer aggregates are not prone of inducing alkali silica reaction.
Abstract: The objective of this research is to mitigate and prevent
the alkali silica reactivity (ASR) in highway construction projects.
ASR is a deleterious reaction initiated when the silica content of the
aggregate reacts with alkali hydroxides in cement in the presence of
relatively high moisture content. The ASR results in the formation of
an expansive white colored gel-like material which forms the
destructive tensile stresses inside hardened concrete. In this research, different types of local aggregates available in the
State of Arkansas were mixed and mortar bars were poured according
to the ASTM specifications. Mortar bars expansion was measured
versus time and aggregates with potential ASR problems were
detected. Different types of supplementary cementitious materials
(SCMs) were used in remixing mortar bars with highly reactive
aggregates. Length changes for remixed bars proved that different
types of SCMs can be successfully used in reducing the expansive
effect of ASR. SCMs percentage by weight is highly dependent on
the SCM type. The result of this study will help avoiding future
losses due to ASR cracking in construction project and reduce the
maintenance, repair, and replacement budgets required for highways
network.
Abstract: This paper investigates the effectiveness of two
natural zeolites in reducing expansion of concrete due to alkali-silica
reaction. These natural zeolites have different reactive silica content.
Three aggregates; two natural sands and one crushed stone aggregate
were used while preparing mortar bars in accordance with accelerated
mortar bar test method, ASTM C1260. Performances of natural
zeolites are compared by examining the expansions due to alkali
silica reaction. Natural zeolites added to the mixtures at 10% and
20% replacement levels by weight of cement. Natural zeolite with
high reactive silica content had better performance on reducing
expansions due to ASR. In this research, using high reactive zeolite at
20% replacement levels was effective in mitigating expansions.
Abstract: Several review papers exist in literature related to the concrete containing mineral admixtures; however this paper reviews the durability characteristics of the concrete containing fly ash (FA), silica fume (SF), ground granulated blast furnace slag (GGBS), metakaolin (MK) and rice husk ash (RHA). Durability related properties reviewed include permeability, resistance to sulfate attack, alkali-silica reaction (ASR), carbonation, chloride ion penetration, freezing and thawing, abrasion, fire, acid and efflorescence. From review of existing literature, it is found that permeability of concrete depends upon the content of alumina in mineral admixtures, i.e. higher the alumina content, lesser the permeability which results higher resistance to sulfate and chloride ion penetration. Highly reactive mineral admixtures prevent more ASR and reduce efflorescence. The carbonation increases with the mineral admixtures because higher water binder ratio and lesser content of portlandite in concrete due to pozzolanic reaction. Mineral admixtures require air entrainment except MK and RHA for better resistance to freezing and thawing.