Abstract: Mesoporous materials are very commonly used as adsorbent materials for removing phenolic compounds. However, the adsorption mechanism of these compounds is still poorly controlled. However, understanding the interactions mesoporous materials/adsorbed molecules is very important in order to optimize the processes of liquid phase adsorption. The difficulty of synthesis is to keep an orderly and cubic pore structure and achieve a homogeneous surface modification. The grafting of Si(CH3)3 was chosen, to transform hydrophilic surfaces hydrophobic surfaces. The aim of this work is to study the kinetics and thermodynamics of two volatile organic compounds VOC phenol (PhOH) and P hydroxy benzoic acid (4AHB) on a mesoporous material of type MCM-48 grafted with an organosilane of the Trimethylchlorosilane (TMCS) type, the material thus grafted or functionalized (hereinafter referred to as MCM-48-G). In a first step, the kinetic and thermodynamic study of the adsorption isotherms of each of the VOCs in mono-solution was carried out. In a second step, a similar study was carried out on a mixture of these two compounds. Kinetic models (pseudo-first order, pseudo-second order) were used to determine kinetic adsorption parameters. The thermodynamic parameters of the adsorption isotherms were determined by the adsorption models (Langmuir, Freundlich). The comparative study of adsorption of PhOH and 4AHB proved that MCM-48-G had a high adsorption capacity for PhOH and 4AHB; this may be related to the hydrophobicity created by the organic function of TMCS in MCM-48-G. The adsorption results for the two compounds using the Freundlich and Langmuir models show that the adsorption of 4AHB was higher than PhOH. The values obtained by the adsorption thermodynamics show that the adsorption interactions for our sample with the phenol and 4AHB are of a physical nature. The adsorption of our VOCs on the MCM-48 (G) is a spontaneous and exothermic process.
Abstract: Fixed bed adsorption has become a frequently used
industrial application in wastewater treatment processes. Various low
cost adsorbents have been studied for their applicability in treatment
of different types of effluents. In this work, the intention of the study
was to explore the efficacy and feasibility for azo dye, Acid Orange 7
(AO7) adsorption onto fixed bed column of NaOH Treated eggshell
(TES). The effect of various parameters like flow rate, initial dye
concentration, and bed height were exploited in this study. The
studies confirmed that the breakthrough curves were dependent on
flow rate, initial dye concentration solution of AO7 and bed depth.
The Thomas, Yoon–Nelson, and Adams and Bohart models were
analysed to evaluate the column adsorption performance. The
adsorption capacity, rate constant and correlation coefficient
associated to each model for column adsorption was calculated and
mentioned. The column experimental data were fitted well with
Thomas model with coefficients of correlation R2 ≥0.93 at different
conditions but the Yoon–Nelson, BDST and Bohart–Adams model
(R2=0.911), predicted poor performance of fixed-bed column. The
(TES) was shown to be suitable adsorbent for adsorption of AO7
using fixed-bed adsorption column.
Abstract: In this work, a polyaniline/Iron oxide (PANI/Fe2O3)
composite was chemically prepared by oxidative polymerization of
aniline in acid medium, in presence of ammonium persulphate as an
oxidant and amount of Fe2O3. The composite was characterized by a
scanning electron microscopy (SEM). The prepared composite has
been used as adsorbent to remove Tartrazine dye form aqueous
solutions.
The effects of initial dye concentration and temperature on the
adsorption capacity of PANI/Fe2O3 for Tartrazine dye have been
studied in this paper.
The Langmuir and Freundlich adsorption models have been used
for the mathematical description of adsorption equilibrium data. The
best fit is obtained using the Freundlich isotherm with an R2 value of
0.998. The change of Gibbs energy, enthalpy, and entropy of
adsorption has been also evaluated for the adsorption of Tartrazine
onto PANI/ Fe2O3. It has been proved according the results that the
adsorption process is endothermic in nature.
Abstract: The potential of economically cheaper cellulose
containing natural materials like rice husk was assessed for nickel
adsorption from aqueous solutions. The effects of pH, contact time,
sorbent dose, initial metal ion concentration and temperature on the
uptake of nickel were studied in batch process. The removal of nickel
was dependent on the physico-chemical characteristics of the
adsorbent, adsorbate concentration and other studied process
parameters. The sorption data has been correlated with Langmuir,
Freundlich and Dubinin-Radush kevich (D-R) adsorption models. It
was found that Freundlich and Langmuir isotherms fitted well to the
data. Maximum nickel removal was observed at pH 6.0. The
efficiency of rice husk for nickel removal was 51.8% for dilute
solutions at 20 g L-1 adsorbent dose. FTIR, SEM and EDAX were
recorded before and after adsorption to explore the number and
position of the functional groups available for nickel binding on to
the studied adsorbent and changes in surface morphology and
elemental constitution of the adsorbent. Pseudo-second order model
explains the nickel kinetics more effectively. Reusability of the
adsorbent was examined by desorption in which HCl eluted 78.93%
nickel. The results revealed that nickel is considerably adsorbed on
rice husk and it could be and economic method for the removal of
nickel from aqueous solutions.
Abstract: High pressure adsorption of carbon dioxide on zeolite
13X was investigated in the pressure range (0 to 4) Mpa and
temperatures 298, 308 and 323K. The data fitting is accomplished
with the Toth, UNILAN, Dubinin-Astakhov and virial adsorption
models which are generally used for micro porous adsorbents such as
zeolites. Comparison with experimental data from the literature
indicated that the virial model would best determine results. These
results may be partly attributed to the flexibility of the virial model
which can accommodate as many constants as the data warrants.
Abstract: The equilibrium, thermodynamics and kinetics of the
biosorption of Cd (II) and Pb(II) by a Spore Forming Bacillus (MGL
75) were investigated at different experimental conditions. The
Langmuir and Freundlich, and Dubinin-Radushkevich (D-R)
equilibrium adsorption models were applied to describe the
biosorption of the metal ions by MGL 75 biomass. The Langmuir
model fitted the equilibrium data better than the other models.
Maximum adsorption capacities q max for lead (II) and cadmium (II)
were found equal to 158.73mg/g and 91.74 mg/g by Langmuir model.
The values of the mean free energy determined with the D-R equation
showed that adsorption process is a physiosorption process. The
thermodynamic parameters Gibbs free energy (ΔG°), enthalpy (ΔH°),
and entropy (ΔS°) changes were also calculated, and the values
indicated that the biosorption process was exothermic and
spontaneous. Experiment data were also used to study biosorption
kinetics using pseudo-first-order and pseudo-second-order kinetic
models. Kinetic parameters, rate constants, equilibrium sorption
capacities and related correlation coefficients were calculated and
discussed. The results showed that the biosorption processes of both
metal ions followed well pseudo-second-order kinetics.