Abstract: In this work, the influence of temperature on the
different parameters of solar cells based on organic semiconductors
are studied. The short circuit current Isc increases so monotonous
with temperature and then saturates to a maximum value before
decreasing at high temperatures. The open circuit voltage Vco
decreases linearly with temperature. The fill factor FF and efficiency,
which are directly related with Isc and Vco follow the variations of
the letters. The phenomena are explained by the behaviour of the
mobility which is a temperature activated process.
Abstract: Nano fibers produced by electrospinning are of industrial and scientific attention due to their special characteristics such as long length, small diameter and high surface area. Applications of electrospun structures in nanotechnology are included tissue scaffolds, fibers for drug delivery, composite reinforcement, chemical sensing, enzyme immobilization, membrane-based filtration, protective clothing, catalysis, solar cells, electronic devices and others. Many polymer and ceramic precursor nano fibers have been successfully electrospun with diameters in the range from 1 nm to several microns. The process is complex so that fiber diameter is influenced by various material, design and operating parameters. The objective of this work is to apply genetic algorithm on the parameters of electrospinning which have the most significant effect on the nano fiber diameter to determine the optimum parameter values before doing experimental set up. Effective factors including initial polymer concentration, initial jet radius, electrical potential, relaxation time, initial elongation, viscosity and distance between nozzle and collector are considered to determine finest diameter which is selected by user.
Abstract: In this research, the main aim is to investigate the
antimicrobial effectiveness of ammonyx solutions finishing on
Sweatshirt Sport with immersion method. 60 Male healthy subjects
(football player) participated in this study. They were dressed in a
Sweatshirt for 14 days and some microbes found on them were
investigated. The antimicrobial effect of different ammonyx
solutions(1/100, 1/500, 1/1000, 1/2000 v/v solutions of Ammonyx)
on the identified microbes was studied by the zone inhabitation
method in vitro. In the next step the Sweatshirt Sports were treated
with the same different solutions of ammonyx and the antimicrobial
effectiveness was assessed by colony count method in different times
and the results were compared whit untreated ones. Some mechanical
properties of treated cotton/polyester yarn that used in Sweatshirt
Sport were measured after 30 days and were compared with
untreated one. Finally after finishing, scanning electron microscopy
(SEM) was used to compare the surfaces of the finished and
unfinished specimens. The results showed the presence of five
pathogenic microbes on Sweatshirt Sports such as Escherichia coli,
Staphylococcus aureus, Aspergillus, Mucor and Candida. The
inhalation time for treated on Sweatshirt Sports improved. The
amount of colony growth on treated clothes reduced considerably
and moreover the mechanical tests results showed no significant
deterioration effect of studies properties in comparison to the
untreated yarn. The visual examination of the SEM indicated that the
antimicrobial treatments were applied usefully to fabrics.
Abstract: Silver/polylactide nanocomposites (Ag/PLA-NCs) were
synthesized via chemical reduction method in diphase solvent. Silver
nitrate and sodium borohydride were used as a silver precursor
and reducing agent in the polylactide (PLA). The properties of
Ag/PLA-NCs were studied as a function of the weight percentages
of silver nanoparticles (8, 16 and 32 wt% of Ag-NPs) relative to
the weight of PLA. The Ag/PLA-NCs were characterized by Xray
diffraction (XRD), transmission electron microscopy (TEM),
electro-optical microscopy (EOM), UV-visible spectroscopy (UV-vis)
and Fourier transform infrared spectroscopy (FT-IR). XRD patterns
confirmed that Ag-NPs crystallographic planes were face centered
cubic (fcc) type. TEM images showed that mean diameters of Ag-NPs
were 3.30, 3.80 and 4.80 nm. Electro-optical microscopy revealed
excellent dispersion and interaction between Ag-NPs and PLA films.
The generation of silver nanoparticles was confirmed from the UVvisible
spectra. FT-IR spectra showed that there were no significant
differences between PLA and Ag/PLA-NCs films. The synthesized
Ag/PLA-NCs were stable in organic solution over a long period of
time without sign of precipitation.
Abstract: Wet chemistry methods are used to prepare the
SiO2/Au nanoshells. The purpose of this research was to synthesize
gold coated SiO2 nanoshells for biomedical applications. Tunable
nanoshells were prepared by using different colloidal concentrations.
The nanoshells are characterized by FTIR, XRD, UV-Vis
spectroscopy and atomic force microscopy (AFM). The FTIR results
confirmed the functionalization of the surfaces of silica nanoparticles
with NH2 terminal groups. A tunable absorption was observed
between 470-600 nm with a maximum range of 530-560 nm. Based
on the XRD results three main peaks of Au (111), (200) and (220)
were identified. Also AFM results showed that the silica core
diameter was about 100 nm and the thickness of gold shell about 10
nm.
Abstract: This research was to evaluate a technical feasibility of
making single-layer experimental particleboard panels from bamboo
waste (Dendrocalamus asper Backer) by converting bamboo into
strips, which are used to make laminated bamboo furniture. Variable
factors were density (600, 700 and 800 kg/m3) and temperature of
condition (25, 40 and 55 °C). The experimental panels were tested for
their physical and mechanical properties including modulus of
elasticity (MOE), modulus of rupture (MOR), internal bonding
strength (IB), screw holding strength (SH) and thickness swelling
values according to the procedures defined by Japanese Industrial
Standard (JIS). The test result of mechanical properties showed that
the MOR, MOE and IB values were not in the set criteria, except the
MOR values at the density of 700 kg/m3 at 25 °C and at the density
of 800 kg/m3 at 25 and 40 °C, the IB values at the density of 600
kg/m3, at 40 °C, and at the density of 800 kg/m3 at 55 °C. The SH
values had the test result according to the set standard, except with
the density of 600 kg/m3, at 40 and 55 °C. Conclusively, a valuable
renewable biomass, bamboo waste could be used to manufacture
boards.
Abstract: Gold coated silica core nanoparticles have an optical
response dictated by the plasmon resonance. The wavelength at
which the resonance occurs depends on the core and shell sizes,
allowing nanoshells to be tailored for particular applications. The
purposes of this study was to synthesize and use different
concentration of gold nanoshells as exogenous material for skin
tissue soldering and also to examine the effect of laser soldering
parameters on the properties of repaired skin. Two mixtures of
albumin solder and different concentration of gold nanoshells were
prepared. A full thickness incision of 2×20 mm2 was made on the
surface and after addition of mixtures it was irradiated by an 810nm
diode laser at different power densities. The changes of tensile
strength σt due to temperature rise, number of scan (Ns), and scan
velocity (Vs) were investigated. The results showed at constant laser
power density (I), σt of repaired incisions increases by increasing the
concentration of gold nanoshells, Ns and decreasing Vs. It is therefore
important to consider the trade off between the scan velocity and the
surface temperature for achieving an optimum operating condition. In
our case this corresponds to σt =1610 gr/cm2 at I~ 60 Wcm-2, T ~
65ºC, Ns =10 and Vs=0.2mms-1.
Abstract: A biocompatible ferrofluid have been prepared by coprecipitation
of FeCl2.4H2O and FeCl3.6H2O under ultrasonic
irradiation and with NaOH as alkaline agent. Cystein was also used
as capping agent in the solution. Magnetic properties of the produced
ferrofluid were then determined by VSM test and magnetite
nanoparticles were characterized by XRD and TEM techniques. The
effect of surfactant to Fe ion weight ratio was also studied during this
project by using two different amount of Dextran. Results showed the
presence of a biocompatible superparamagnetic ferrofluid including
magnetite nanoparticles with particle size ranging under 20 nm. The
increase in the surfactant content results in the narrowing of the size
distribution and reduction of the particle size and more solution
stability.