Abstract: Cement is a basic material used for building construction. Chromium as an indelible non-volatile trace element of raw materials occurs in cement clinker in the trivalent or hexavalent form. Hexavalent form of chromium is harmful and allergenic having very high water solubility and thus can easily come into contact with the human skin. The paper is aimed at analyzing the content of total chromium in Portland cements and leaching rate of hexavalent chromium in various leachants: Deionized water, Britton-Robinson buffer, used to simulate the natural environment, and hydrochloric acid (HCl). The concentration of total chromium in Portland cement samples was in a range from 173.2 to 218.5 mg/kg. The content of dissolved hexavalent chromium ranged 0.23-3.19, 2.0-5.78 and 8.88-16.25 mg/kg in deionized water, Britton-Robinson solution and hydrochloric acid, respectively. The calculated leachable fraction of Cr(VI) from cement samples was observed in the range 0.1--7.58 %.
Abstract: Arthrobacter viscosus biomass was used for Cr(VI)
biosorption. The effect of pH on Cr(VI) reduction and removal from
aqueous solution was studied in the range of 1-4. The Cr(VI) removal
involves both redox reaction and adsorption of metal ions on biomass
surface. The removal rate of Cr(VI) was enhanced by very acid
conditions, while higher solution pH values favored the removal of
total chromium. The best removal efficiency and uptake were
reached at pH 4, 72.5 % and 12.6 mgCr/gbiomass, respectively.