Abstract: Sclareolide is made from sclareol by oxidiative synthesis and subsequent crystallization, while the crystallization mother liquor still contains 15%~30%wt of sclareolide to be reclaimed. With the reaction material of sclareol is provided as plant extract, many sorts of complex impurities exist in the mother liquor. Due to the difficulty in recycling sclareolide after solvent recovery, it is common practice for the factories to discard the mother liquor, which not only results in loss of sclareolide, but also contributes extra environmental burden. In this paper, a process based on adsorption and elution has been presented for recycling of sclareolide from mother liquor. After pretreatment of the crystallization mother liquor by HZ-845 resin to remove parts of impurities, sclareolide is adsorbed by HZ-816 resin. The HZ-816 resin loaded with sclareolide is then eluted by elution solvent. Finally, the eluent containing sclareolide is concentrated and fed into the crystallization step in the process. By adoption of the recycle from mother liquor, total yield of sclareolide increases from 86% to 90% with a stable purity of the final sclareolide products maintained.
Abstract: Medicinal and aromatic plants are promising and are characterized by the biosynthesis of odorous molecules that make up the so-called essential oils (EO), which have long been known for their antiseptic and therapeutic activity in folk medicine. Essential oils have many therapeutic properties. In herbal medicine, they are used for their antiseptic properties against infectious diseases of fungal origin, against dermatophytes, those of bacterial origin. The objective of this study was to evaluate the influence of drying in the shade on the water content and on the content of essential oils extracted from leaves of Eucalyptus camendulensis for better quality control of medicinal and aromatic plants. The water content of the Eucalyptus camendulensis plant material decreases during the drying process. It decreased from 100% to 0.006% for the drying in the shade after ten days. The moisture content is practically constant at the end of the drying period. The drying in the shade increases the concentration of essential oils of Eucalyptus camendulensis. When the leaves of Eucalyptus camendulensis plant are in the shade, the maximum of the essential oil content was obtained on the eighth day, the recorded value was 1.43% ± 0.01%. Beyond these periods, the content continuously drop in before stabilizing. The optimum drying time is between 6 and 9 days.
Abstract: In this paper, an Infinite Impulse Response (IIR) filter
has been designed and simulated on an Field Programmable Gate
Arrays (FPGA). The implementation is based on Multiply Add and
Accumulate (MAC) algorithm which uses multiply operations for
design implementation. Parallel Pipelined structure is used to
implement the proposed IIR Filter taking optimal advantage of the
look up table of target device. The designed filter has been
synthesized on Digital Signal Processor (DSP) slice based FPGA to
perform multiplier function of MAC unit. The DSP slices are useful
to enhance the speed performance. The proposed design is simulated
with Matlab, synthesized with Xilinx Synthesis Tool, and
implemented on FPGA devices. The Virtex 5 FPGA based design can
operate at an estimated frequency of 81.5 MHz as compared to 40.5
MHz in case of Spartan 3 ADSP based design. The Virtex 5 based
implementation also consumes less slices and slice flip flops of target
FPGA in comparison to Spartan 3 ADSP based implementation to
provide cost effective solution for signal processing applications.
Abstract: The number and adequacy of Performance-Indicators
(PIs) for organisational purposes are core to the success of
organisations and a major concern to the sponsor of this research.
This assignment developed a procedure to improve a firm’s
performance assessment system, by identifying two key-PIs out of 28
initial ones, and by setting criteria and their relative importance to
validate and rank the adequacy and the right number of operational
metrics. The Analytical-Hierarchy-Process was used with a synthesismethod
to treat data coming from the management inquiries.
Although organisational alignment has been achieved, business
processes should also be targeted and PIs continuously revised.
Abstract: With the advancement of knowledge about the utility
and impact of sustainability, its feasibility has been explored into
different walks of life. Scientists, however; have established their
knowledge in four areas viz environmental, economic, social and
cultural, popularly termed as four pillars of sustainability. Aspects of
environmental and economic sustainability have been rigorously
researched and practiced and huge volume of strong evidence of
effectiveness has been founded for these two sub-areas. For the social
and cultural aspects of sustainability, dependable evidence of
effectiveness is still to be instituted as the researchers and
practitioners are developing and experimenting methods across the
globe. Therefore, the present research aimed to identify globally used
practices of social and cultural sustainability and through evidence
synthesis assess their outcomes to determine the effectiveness of
those practices. A PICO format steered the methodology which
included all populations, popular sustainability practices including
walkability/cycle tracks, social/recreational spaces, privacy, health &
human services and barrier free built environment, comparators
included ‘Before’ and ‘After’, ‘With’ and ‘Without’, ‘More’ and
‘Less’ and outcomes included Social well-being, cultural coexistence,
quality of life, ethics and morality, social capital, sense of
place, education, health, recreation and leisure, and holistic
development. Search of literature included major electronic
databases, search websites, organizational resources, directory of
open access journals and subscribed journals. Grey literature,
however, was not included. Inclusion criteria filtered studies on the
basis of research designs such as total randomization, quasirandomization,
cluster randomization, observational or single studies
and certain types of analysis. Studies with combined outcomes were
considered but studies focusing only on environmental and/or
economic outcomes were rejected. Data extraction, critical appraisal
and evidence synthesis was carried out using customized tabulation,
reference manager and CASP tool. Partial meta-analysis was carried
out and calculation of pooled effects and forest plotting were done.
As many as 13 studies finally included for final synthesis explained
the impact of targeted practices on health, behavioural and social
dimensions. Objectivity in the measurement of health outcomes
facilitated quantitative synthesis of studies which highlighted the
impact of sustainability methods on physical activity, Body Mass
Index, perinatal outcomes and child health. Studies synthesized
qualitatively (and also quantitatively) showed outcomes such as
routines, family relations, citizenship, trust in relationships, social
inclusion, neighbourhood social capital, wellbeing, habitability and
family’s social processes. The synthesized evidence indicates slight
effectiveness and efficacy of social and cultural sustainability on the
targeted outcomes. Further synthesis revealed that such results of this
study are due weak research designs and disintegrated implementations. If architects and other practitioners deliver their
interventions in collaboration with research bodies and policy
makers, a stronger evidence-base in this area could be generated.
Abstract: Searching the “Island of stability” is a topic of
extreme interest in theoretical as well as experimental modern
physics today. This “island of stability” is spanned by superheavy
elements (SHE's) that are produced in the laboratory. SHE's are
believed to exist primarily due to the “magic” stabilizing effects of
nuclear shell structure. SHE synthesis is extremely difficult due to
their very low production cross section, often of the order of pico
barns or less. Stabilizing effects of shell closures at proton number
Z=82 and neutron number N=126 are predicted theoretically. Though
stabilizing effects of Z=82 have been experimentally verified, no
concluding observations have been made with N=126, so far. We
measured and analyzed the total evaporation residue (ER) cross
sections for a number of systems with neutron number around 126 to
explore possible shell closure effects in ER cross sections, in this
work.
Abstract: Zinc borates are used as a multi-functional flame
retardant additive for its high dehydration temperature. In this study,
the method of ultrasonic mixing was used in the synthesis of zinc
borates. The reactants of zinc oxide (ZnO) and boric acid (H3BO3)
were used at the constant reaction parameters of 90°C reaction
temperature and 55 min of reaction time. Several molar ratios of
ZnO:H3BO3 (1:1, 1:2, 1:3, 1:4 and 1:5) were conducted for the
determination of the optimum reaction ratio. Prior to synthesis the
characterization of the synthesized zinc borates were made by X-Ray
Diffraction (XRD) and Fourier Transform Infrared Spectroscopy
(FT-IR). From the results Zinc Oxide Borate Hydrate
[Zn3B6O12.3.5H2O], were synthesized optimum at the molar ratio of
1:3, with a reaction efficiency of 95.2%.
Abstract: Cadmium oxide (CdO) nanoparticles have been
prepared by chemical coprecipitation method. The synthesized
nanoparticles were characterized by X-ray diffraction analysis
(XRD), scanning electron microscopy (SEM), transmission electron
microscopy (TEM), UV analysis, and dielectric studies. The
crystalline nature and particle size of the CdO nanoparticles were
characterized by Powder X-ray diffraction analysis (XRD). The
morphology of prepared CdO nanoparticles was studied by scanning
electron microscopy. The particle size was studied using the
transmission electron microscopy (TEM).The optical properties were
obtained from UV-Vis absorption spectrum. The dielectric properties
of CdO nanoparticles were studied in the frequency range of 50 Hz–5
MHz at different temperatures. The frequency dependence of the
dielectric constant and dielectric loss is found to decrease with an
increase in the frequency at different temperatures. The ac
conductivity of CdO nanoparticle has been studied.
Abstract: In this study, the effects and interactions of reaction
time and capping agent assistance during sol-gel synthesis of
magnesium substituted hydroxyapatite nanopowder (MgHA) on
hydroxyapatite (HA) to β-tricalcium phosphate (β-TCP) ratio, Ca/P
ratio and mean crystallite size was examined experimentally as well
as through statistical analysis. MgHA nanopowders were synthesized
by sol-gel technique at room temperature using aqueous solution of
calcium nitrate tetrahydrate, magnesium nitrate hexahydrate and
potassium dihydrogen phosphate as starting materials. The reaction
time for sol-gel synthesis was varied between 15 to 60 minutes. Two
process routes were followed with and without addition of
triethanolamine (TEA) in the solutions. The elemental compositions
of as-synthesized powders were determined using X-ray fluorescence
(XRF) spectroscopy. The functional groups present in the assynthesized
MgHA nanopowders were established through Fourier
Transform Infrared Spectroscopy (FTIR). The amounts of phases
present, Ca/P ratio and mean crystallite sizes of MgHA nanopowders
were determined using X-ray diffraction (XRD). The HA content in
biphasic mixture of HA and β-TCP and Ca/P ratio in as-synthesized
MgHA nanopowders increased effectively with reaction time of sols
(p0.15, two way ANOVA). The MgHA nanopowders
synthesized with TEA assistance exhibited 14 nm lower crystallite
size (p
Abstract: This study evaluated the acute toxicity and tissue
distribution of intravenously administered gold nanoparticles
(AuNPs) in male rabbits. Rabbits were exposed to single dose of
AuNPs (300 μg/ kg). Toxic effects were assessed via general
behavior, hematological parameters, serum biochemical parameters,
and histopathological examination of various rabbits’ organs.
Inductively coupled plasma–mass spectrometry (ICP-MS) was used
to determine gold concentrations in tissue samples collected at
predetermined time intervals. After one week, AuNPs exerted no
obvious acute toxicity in rabbits. However, inflammatory reactions
were observed in liver, lungs and kidneys accompanied with mild
absolute neutrophilia and significant monocytosis. The highest gold
levels were found in the spleen and liver followed by lungs, and
kidneys. These results indicated that AuNPs could be distributed
extensively to various tissues in the body, but primarily in the spleen
and liver.
Abstract: In Algeria, the conditioning units of dates, generate
significant quantities of waste arising from sorting deviations. This
biomass, until then considered as a waste with high impact on the
environment can be transformed into high value added product. It is
possible to develop common dates of low commercial value, and put
on the local and international market a new generation of products
with high added values such as bio ethanol. Besides its use in
chemical synthesis, bio ethanol can be blended with gasoline to
produce a clean fuel while improving the octane.
Abstract: The 1:1 cocrystal of 2-amino-4-chloro-6-
methylpyrimidine (2A4C6MP) with 4-methylbenzoic acid (4MBA)
(I) has been prepared by slow evaporation method in methanol,
which was crystallized in monoclinic C2/c space group, Z = 8, and a
= 28.431 (2) Å, b = 7.3098 (5) Å, c = 14.2622 (10) Å and β =
109.618 (3)°. The presence of unionized –COOH functional group in
cocrystal I was identified both by spectral methods (1H and 13C
NMR, FTIR) and X-ray diffraction structural analysis. The
2A4C6MP molecule interact with the carboxylic group of the
respective 4MBA molecule through N—H⋯O and O—H⋯N
hydrogen bonds, forming a cyclic hydrogen–bonded motif R2
2(8).
The crystal structure was stabilized by Npyrimidine—H⋯O=C and
C=O—H⋯Npyrimidine types hydrogen bonding interactions.
Theoretical investigations have been computed by HF and density
function (B3LYP) method with 6–311+G (d,p)basis set. The
vibrational frequencies together with 1H and 13C NMR chemical
shifts have been calculated on the fully optimized geometry of
cocrystal I. Theoretical calculations are in good agreement with the
experimental results. Solvent–free formation of this cocrystal I is
confirmed by powder X-ray diffraction analysis.
Abstract: Within this paper, latest results on processing of energetic nanomaterials by means of the Spray Flash Evaporation technique are presented. This technology constitutes a highly effective and continuous way to prepare fascinating materials on the nano- and micro-scale. Within the process, a solution is set under high pressure and sprayed into an evacuated atomization chamber. Subsequent ultrafast evaporation of the solvent leads to an aerosol stream, which is separated by cyclones or filters. No drying gas is required, so the present technique should not be confused with spray dying. Resulting nanothermites, insensitive explosives or propellants and compositions are foreseen to replace toxic (according to REACH) and very sensitive matter in military and civil applications. Diverse examples are given in detail: nano-RDX (n-Cyclotrimethylentrinitramin) and nano-aluminum based systems, mixtures (n-RDX/n-TNT - trinitrotoluene) or even cocrystalline matter like n-CL-20/HMX (Hexanitrohexaazaisowurtzitane/ Cyclotetra-methylentetranitramin). These nanomaterials show reduced sensitivity by trend without losing effectiveness and performance. An analytical study for material characterization was performed by using Atomic Force Microscopy, X-Ray Diffraction, and combined techniques as well as spectroscopic methods. As a matter of course, sensitivity tests regarding electrostatic discharge, impact, and friction are provided.
Abstract: NiFe2O4 (nickel ferrite), ZnFe2O4 (zinc ferrite) and
Ni0.5Zn0.5Fe2O4 (nickel-zinc ferrite) were prepared by
mechanochemical route in a planetary ball mill starting from mixture
of the appropriate quantities of the Ni(OH)2/Fe(OH)3,
Zn(OH)2/Fe(OH)3 and Ni(OH)2/Zn(OH)2/Fe(OH)3 hydroxide
powders. In order to monitor the progress of chemical reaction and
confirm phase formation, powder samples obtained after 25 h, 18 h
and 10 h of milling were characterized by X-ray diffraction (XRD),
transmission electron microscopy (TEM), IR, Raman and Mössbauer
spectroscopy. It is shown that the soft mechanochemical method, i.e.
mechanochemical activation of hydroxides, produces high quality
single phase ferrite samples in much more efficient way. From the IR
spectroscopy of single phase samples it is obvious that energy of
modes depends on the ratio of cations. It is obvious that all samples
have more than 5 Raman active modes predicted by group theory in
the normal spinel structure. Deconvolution of measured spectra
allows one to conclude that all complex bands in the spectra are made
of individual peaks with the intensities that vary from spectrum to
spectrum. The deconvolution of Raman spectra allows to separate
contributions of different cations to a particular type of vibration and
to estimate the degree of inversion.
Abstract: Cesium molybdates with general formula
CsMIII(MoO4)2, where MIII = Bi, Dy, Pr, Er, exhibit rich
polymorphism, and crystallize in a layered structure. These properties
cause intensive studies on cesium molybdates. CsBi(MoO4)2 was synthesized by microwave method by using
cerium sulphate, bismuth oxide and molybdenum (VI) oxide in an
appropriate molar ratio. Characterizations were done by x-ray
diffraction (XRD), fourier transform infrared (FTIR) spectroscopy,
scanning electron microscopy/energy dispersive analyze (SEM/EDS),
thermo gravimetric/differantial thermal analysis (TG/DTA).
Abstract: Abstract—[Tris (1,10-phenanthroline) lanthanum(III)]
trithiocyanate is a new compound that has shown high ability for
stopping the synthesis of DNA and also acting as a photosensitizer.
Nowadays, the radiation dose assessment resource (RADAR) method
is known as the most common method for absorbed dose calculation.
177Lu was produced by (n, gamma) reaction in a research reactor.
177Lu-PL3 was prepared in the optimized condition. The
radiochemical yield was checked by ITLC method. The
biodistribution of the complex was investigated by intravenously
injection to wild-type rats via their tail veins. In this study, the
absorbed dose of 177Lu-PL3 to human organs was estimated by
RADAR method. 177Lu was prepared with a specific activity of 2.6-3
GBq.mg-1 and radionuclide purity of 99.98 %. Final preparation of
the radiolabelled complex showed high radiochemical purity of >
99%. The results show that liver and spleen have received the highest
absorbed dose of 1.051 and 0.441 mSv/MBq, respectively. The
absorbed dose values for these two dose-limiting tissues suggest
more biological studies special in tumor-bearing animals.
Abstract: Zinc borate is an important inorganic hydrate borate
material, which can be used as a flame retardant agent and corrosion
resistance material. This compound can loss its structural water
content at higher than 290°C. Due to thermal stability; Zinc Borate
can be used as flame retardant at high temperature process of plastic
and gum. In this study, the ultrasonic reaction of zinc borates were
studied using hydrozincite (Zn5(CO3)2·(OH)6) and boric acid
(H3BO3) raw materials. Before the synthesis raw materials were
characterized by X-Ray Diffraction (XRD) and Fourier Transform
Infrared Spectroscopy (FT-IR). Ultrasonic method is a new
application on the zinc borate synthesis. The synthesis parameters
were set to 90°C reaction temperature and 55 minutes of reaction
time, with 1:1, 1:2, 1:3, 1:4 and 1:5 molar ratio of starting materials
(Zn5(CO3)2·(OH)6 : H3BO3). After the zinc borate synthesis, the
products were analyzed by XRD and FT-IR. As a result, optimum
molar ratio of 1:5 is determined for the synthesis of zinc borates with
ultrasonic method.
Abstract: Our sowing date experiment took place in the
Demonstration Garden of Institution of Plant Sciences, Centre for
Agricultural Sciences of University of Debrecen, in 2012-2014. The
paper contains data of test year 2014. Our purpose, besides several
other examinations, was to observe how sowing date influences the
leaf area index and the activity of photosynthesis of maize hybrids,
and how those factors affect fruiting. In the experiment we monitored
the change of the leaf area index and the photosynthesis of hybrids
with four different growing seasons. The results obtained confirm
that not only the environmental and agricultural factors in the
growing season have effect on the yield, but also other factors like
the leaf area index and the photosynthesis are determinative
parameters, and all those factors together, modifying the effects of
each other, develop average yields.
Abstract: Ceramic obtained on the base of aluminum oxide has
wide application range, because it has unique properties, for example,
wear-resistance, dielectric characteristics, and exploitation ability at
high temperatures and in corrosive atmosphere. Low temperature
synthesis of α-Al2O3 is energo-economical process and it is topical
for developing technologies of corundum ceramics fabrication. In the present work possibilities of low temperature transformation
of oxyhydroxides in α-Al2O3, during the presence of small amount of
rare–earth elements compounds (also Th, Re), have been discussed.
Aluminum unstable oxyhydroxides have been obtained by hydrolysis
of aluminium isopropoxide, nitrates, sulphate, and chloride in
alkaline environment at 80-90ºC temperatures. β-Al(OH)3 has been
received from aluminum powder by ultrasonic development. Drying
of oxyhydroxide sol has been conducted with presence of various
types seeds, which amount reaches 0,1-0,2% (mas). Neodymium,
holmium, thorium, lanthanum, cerium, gadolinium, disprosium
nitrates and rhenium carbonyls have been used as seeds and they
have been added to the sol specimens in amount of 0.1-0.2% (mas)
calculated on metals. Annealing of obtained gels is carried out at 70–
1100ºC for 2 hrs. The same specimen transforms in α-Al2O3 at
1100ºC. At this temperature in case of presence of lanthanum and
gadolinium transformation takes place by 70-85%. In case of
presence of thorium stabilization of γ-and θ-phases takes place. It is
established, that thorium causes inhibition of α-phase generation at
1100ºC, and at the time when in all other doped specimens α-phase is
generated at lower temperatures (1000-1050ºC). Synthesis of various
type compounds and simultaneous consolidation has developed in the
furnace of OXY-GON. Composite materials containing oxide and
non-oxide components close to theoretical data have been obtained in
this furnace respectively. During the work the following devices have
been used: X-ray diffractometer DRON-3M (Cu-Kα, Ni filter,
2º/min), High temperature vacuum furnace OXY-GON, electronic
scanning microscopes Nikon ECLIPSE LV 150, NMM-800TRF,
planetary mill Pulverisette 7 premium line, SHIMADZU Dynamic
Ultra Micro Hardness Tester, DUH-211S, Analysette 12 Dyna sizer.
Abstract: This paper describes a subarray based low
computational design method of multiuser massive multiple
input multiple output (MIMO) system. In our previous works, use of
large array is assumed only in transmitter, but this study considers
the case both of transmitter and receiver sides are equipped with
large array antennas. For this aim, receive arrays are also divided
into several subarrays, and the former proposed method is modified
for the synthesis of a large array from subarrays in both ends.
Through computer simulations, it is verified that the performance
of the proposed method is degraded compared with the original
approach, but it can achieve the improvement in the aspect of
complexity, namely, significant reduction of the computational load
to the practical level.