Abstract: Sol-gel method has been used to fabricate
nanocomposite films on glass substrates composed halloysite clay
mineral and nanocrystalline TiO2. The methodology for the synthesis
involves a simple chemistry method utilized nonionic surfactant
molecule as pore directing agent along with the acetic acid-based solgel
route with the absence of water molecules. The thermal treatment
of composite films at 450oC ensures elimination of organic material
and lead to the formation of TiO2 nanoparticles onto the surface of
the halloysite nanotubes. Microscopy techniques and porosimetry
methods used in order to delineate the structural characteristics of the
materials. The nanocomposite films produced have no cracks and
active anatase crystal phase with small crystallite size were deposited
on halloysite nanotubes. The photocatalytic properties for the new
materials were examined for the decomposition of the Basic Blue 41
azo dye in solution. These, nanotechnology based composite films
show high efficiency for dye’s discoloration in spite of different
halloysite quantities and small amount of halloysite/TiO2 catalyst
immobilized onto glass substrates. Moreover, we examined the
modification of the halloysite/TiO2 films with silver particles in order
to improve the photocatalytic properties of the films. Indeed, the
presence of silver nanoparticles enhances the discoloration rate of the
Basic Blue 41 compared to the efficiencies obtained for unmodified
films.
Abstract: The paper reports the preparation and photocatalytic
activity of ZnO/SnO2 and SnO2 nanoparticles. These nanoparticles
were synthesized by hydrothermal method. The products were
characterized by X-ray diffraction (XRD) and scanning electron
microscopy (SEM). Their grain sizes are about 50-100 nm. The
photocatalytic activities of these materials were investigated for
congo red removal from aqueous solution under UV light irradiation.
It was shown that the use of ZnO/SnO2 as photocatalyst have better
photocatalytic activity for degradation of congo red than SnO2 or
TiO2 (anatase, particle size: 30nm) alone.
Abstract: Concatenative speech synthesis is a method that can
make speech sound which has naturalness and high-individuality of a
speaker by introducing a large speech corpus. Based on this method, in
this paper, we propose a voice conversion method whose conversion
speech has high-individuality and naturalness. The authors also have
two subjective evaluation experiments for evaluating individuality and
sound quality of conversion speech. From the results, following three
facts have be confirmed: (a) the proposal method can convert the
individuality of speakers well, (b) employing the framework of unit
selection (especially join cost) of concatenative speech synthesis into
conventional voice conversion improves the sound quality of
conversion speech, and (c) the proposal method is robust against the
difference of genders between a source speaker and a target speaker.
Abstract: The Tropical Data Hub (TDH) is a virtual research environment that provides researchers with an e-research infrastructure to congregate significant tropical data sets for data reuse, integration, searching, and correlation. However, researchers often require data and metadata synthesis across disciplines for crossdomain analyses and knowledge discovery. A triplestore offers a semantic layer to achieve a more intelligent method of search to support the synthesis requirements by automating latent linkages in the data and metadata. Presently, the benchmarks to aid the decision of which triplestore is best suited for use in an application environment like the TDH are limited to performance. This paper describes a new evaluation tool developed to analyze both features and performance. The tool comprises a weighted decision matrix to evaluate the interoperability, functionality, performance, and support availability of a range of integrated and native triplestores to rank them according to requirements of the TDH.
Abstract: Polymeric microreactors have emerged as a new
generation of carriers that hold tremendous promise in the areas of
cancer therapy, controlled delivery of drugs, for removal of
pollutants etc. Present work reports a simple and convenient
methodology for synthesis of polystyrene and poly caprolactone
microreactors. An aqueous suspension of carboxylated (1μm)
polystyrene latex particles was mixed with toluene solution followed
by freezing with liquid nitrogen. Freezed particles were incubated at
-20°C and characterized for formation of voids on the surface of
polymer microspheres by Field Emission Scanning Electron
Microscope. The hollow particles were then overnight incubated at
40ºC with unfunctionalized quantum dots (QDs) in 5:1 ratio. QDs
Encapsulated polystyrene microcapsules were characterized by
fluorescence microscopy.
Likewise Poly ε-caprolactone microreactors were prepared by
micro-volcanic rupture of freeze dried microspheres synthesized
using emulsification of polymer with aqueous Poly vinyl alcohol and
freezed with liquid nitrogen. Microreactors were examined with Field
Emission Scanning Electron Microscope for size and morphology.
Current study is an attempt to create hollow polymer particles which
can be employed for microencapsulation of nanoparticles and drug
molecules.
Abstract: Group contribution methods such as the UNIFAC are
of major interest to researchers and engineers involved synthesis,
feasibility studies, design and optimization of separation processes as
well as other applications of industrial use. Reliable knowledge of
the phase equilibrium behavior is crucial for the prediction of the fate
of the chemical in the environment and other applications. The
objective of this study was to predict the solubility of selected
volatile organic compounds (VOCs) in glycol polymers and
biodiesel. Measurements can be expensive and time consuming,
hence the need for thermodynamic models. The results obtained in
this study for the infinite dilution activity coefficients compare very
well those published in literature obtained through measurements. It
is suggested that in preliminary design or feasibility studies of
absorption systems for the abatement of volatile organic compounds,
prediction procedures should be implemented while accurate fluid
phase equilibrium data should be obtained from experiment.
Abstract: Equilibrium and rate based models have been applied
in the simulation of methyl tertiary-butyl ether (MTBE) synthesis
through reactive distillation. Temperature and composition profiles
were compared for both the models and found that both the profiles
trends, though qualitatively similar are significantly different
quantitatively. In the rate based method (RBM), multicomponent
mass transfer coefficients have been incorporated to describe
interphase mass transfer. MTBE mole fraction in the bottom stream is
found to be 0.9914 in the Equilibrium Model (EQM) and only 0.9904
for RBM when the same column configuration was preserved. The
individual tray efficiencies were incorporated in the EQM and
simulations were carried out. Dynamic simulation have been also
carried out for the two column configurations and compared.
Abstract: Recently, nanomaterials are developed in the form of nano-films, nano-crystals and nano-pores. Lanthanide phosphates as a material find extensive application as laser, ceramic, sensor, phosphor, and also in optoelectronics, medical and biological labels, solar cells and light sources. Among the different kinds of rare-earth orthophosphates, yttrium orthophosphate has been shown to be an efficient host lattice for rare earth activator ions, which have become a research focus because of their important role in the field of light display systems, lasers, and optoelectronic devices. It is in this context that the 4fn- « 4fn-1 5d transitions of rare earth in insulating materials, lying in the UV and VUV, are the aim of large number of studies .Though there has been a few reports on Eu3+, Nd3+, Pr3+,Er3+, Ce3+, Tm3+ doped YPO4. The 4fn- « 4fn-1 5d transitions of the rare earth dependent to the host-matrix, several matrices ions were used to study these transitions, in this work we are suggesting to study on a very specific class of inorganic material that are orthophosphate doped with rare earth ions. This study focused on the effect of Ce3+ concentration on the structural and optical properties of Ce3+ doped YPO4 yttrium orthophosphate with powder form prepared by the Sol Gel method.
Abstract: In this paper, the problem of reducing switching
activity in on-chip buses at the stage of high-level synthesis is
considered, and a high-level low power bus binding based on dynamic
bit reordering is proposed. Whereas conventional methods use a fixed
bit ordering between variables within a bus, the proposed method
switches a bit ordering dynamically to obtain a switching activity
reduction. As a result, the proposed method finds a binding solution
with a smaller value of total switching activity (TSA). Experimental
result shows that the proposed method obtains a binding solution
having 12.0-34.9% smaller TSA compared with the conventional
methods.
Abstract: Due to the environmental and price issues of current
energy crisis, scientists and technologists around the globe are
intensively searching for new environmentally less-impact form of
clean energy that will reduce the high dependency on fossil fuel.
Particularly hydrogen can be produced from biomass via thermochemical
processes including pyrolysis and gasification due to the
economic advantage and can be further enhanced through in-situ
carbon dioxide removal using calcium oxide. This work focuses on
the synthesis and development of the flowsheet for the enhanced
biomass gasification process in PETRONAS-s iCON process
simulation software. This hydrogen prediction model is conducted at
operating temperature between 600 to 1000oC at atmospheric
pressure. Effects of temperature, steam-to-biomass ratio and
adsorbent-to-biomass ratio were studied and 0.85 mol fraction of
hydrogen is predicted in the product gas. Comparisons of the results
are also made with experimental data from literature. The
preliminary economic potential of developed system is RM 12.57 x
106 which equivalent to USD 3.77 x 106 annually shows economic
viability of this process.
Abstract: This work concerns the topological optimization
problem for determining the optimal petroleum refinery
configuration. We are interested in further investigating and
hopefully advancing the existing optimization approaches and
strategies employing logic propositions to conceptual process
synthesis problems. In particular, we seek to contribute to this
increasingly exciting area of chemical process modeling by
addressing the following potentially important issues: (a) how the
formulation of design specifications in a mixed-logical-and-integer
optimization model can be employed in a synthesis problem to enrich
the problem representation by incorporating past design experience,
engineering knowledge, and heuristics; and (b) how structural
specifications on the interconnectivity relationships by space (states)
and by function (tasks) in a superstructure should be properly
formulated within a mixed-integer linear programming (MILP)
model. The proposed modeling technique is illustrated on a case
study involving the alternative processing routes of naphtha, in which
significant improvement in the solution quality is obtained.
Abstract: Radial flow reactor was focused for large scale
methanol synthesis and in which the heat transfer type was cross-flow.
The effects of operating conditions including the reactor inlet air
temperature, the heating pipe temperature and the air flow rate on the
cross-flow heat transfer was investigated and the results showed that
the temperature profile of the area in front of the heating pipe was
slightly affected by all the operating conditions. The main area whose
temperature profile was influenced was the area behind the heating
pipe. The heat transfer direction according to the air flow directions. In
order to provide the basis for radial flow reactor design calculation, the
dimensionless number group method was used for data fitting of the
bed effective thermal conductivity and the wall heat transfer
coefficient which was calculated by the mathematical model with the
product of Reynolds number and Prandtl number. The comparison of
experimental data and calculated value showed that the calculated
value fit the experimental data very well and the formulas could be
used for reactor designing calculation.
Abstract: Performance of a cobalt doped sol-gel derived silica (Co/SiO2) catalyst for Fischer–Tropsch synthesis (FTS) in slurryphase reactor was studied using paraffin wax as initial liquid media. The reactive mixed gas, hydrogen (H2) and carbon monoxide (CO) in a molar ratio of 2:1, was flowed at 50 ml/min. Braunauer-Emmett- Teller (BET) surface area and X-ray diffraction (XRD) techniques were employed to characterize both the specific surface area and crystallinity of the catalyst, respectively. The reduction behavior of Co/SiO2 catalyst was investigated using the Temperature Programmmed Reduction (TPR) method. Operating temperatures were varied from 493 to 533K to find the optimum conditions to maximize liquid fuels production, gasoline and diesel.
Abstract: Novel acrylated epoxidized hemp oil (AEHO) based
bioresins were successfully synthesised, characterized and applied to
biocomposites reinforced with woven jute fibre. Characterisation of
the synthesised AEHO consisted of acid number titrations and FTIR
spectroscopy to assess the success of the acrylation reaction. Three
different matrices were produced (vinylester (VE), 50/50 blend of
AEHO/VE and 100% AEHO) and reinforced with jute fibre to form
three different types of biocomposite samples. Mechanical properties
in the form of flexural and interlaminar shear strength (ILSS) were
investigated and compared for the different samples. Results from the
mechanical tests showed that AEHO and 50/50 based neat bioresins
displayed lower flexural properties compared with the VE samples.
However when applied to biocomposites and compared with VE
based samples, AEHO biocomposites demonstrated comparable
flexural performance and improved ILSS. These results are attributed
to improved fibre-matrix interfacial adhesion due to surface-chemical
compatibility between the natural fibres and bioresin.
Abstract: In order to evaluation the effects of soil organic
matter and biofertilizer on chickpea quality and biological
nitrogen fixation, field experiments were carried out in 2007
and 2008 growing seasons. In this research the effects of
different strategies for soil fertilization were investigated on
grain yield and yield component, minerals, organic compounds
and cooking time of chickpea. Experimental units were
arranged in split-split plots based on randomized complete
blocks with three replications. Main plots consisted of (G1):
establishing a mixed vegetation of Vicia panunica and
Hordeum vulgare and (G2): control, as green manure levels.
Also, five strategies for obtaining the base fertilizer
requirement including (N1): 20 t.ha-1 farmyard manure; (N2):
10 t.ha-1 compost; (N3): 75 kg.ha-1 triple super phosphate;
(N4): 10 t.ha-1 farmyard manure + 5 t.ha-1 compost and (N5):
10 t.ha-1 farmyard manure + 5 t.ha-1 compost + 50 kg.ha-1
triple super phosphate were considered in sub plots.
Furthermoree four levels of biofertilizers consisted of (B1):
Bacillus lentus + Pseudomonas putida; (B2): Trichoderma
harzianum; (B3): Bacillus lentus + Pseudomonas putida +
Trichoderma harzianum; and (B4): control (without
biofertilizers) were arranged in sub-sub plots. Results showed
that integrating biofertilizers (B3) and green manure (G1)
produced the highest grain yield. The highest amounts of yield
were obtained in G1×N5 interaction. Comparison of all 2-way
and 3-way interactions showed that G1N5B3 was determined
as the superior treatment. Significant increasing of N, P2O5,
K2O, Fe and Mg content in leaves and grains emphasized on
superiority of mentioned treatment because each one of these
nutrients has an approved role in chlorophyll synthesis and
photosynthesis abilities of the crops. The combined application
of compost, farmyard manure and chemical phosphorus (N5)
in addition to having the highest yield, had the best grain
quality due to high protein, starch and total sugar contents, low
crude fiber and reduced cooking time.
Abstract: In this study, the powders of Ni and Ti with 50.5 at.%
Ni for 12 h were blended and cold pressed at the different pressures
(50, 75 and100 MPa).The porous product obtained after Ni-Ti
compacts were synthesized by SHS (self-propagating hightemperature
synthesis) in the different preheating temperatures (200,
250 and 300oC) and heating rates (30, 60 and 90oC/min). The effects
of the pressure, preheating temperature and heating rate were
investigated on biocompatibility in vivo. The porosity in the
synthesized products was in the range of 50.7–59.7 vol. %. The
pressure, preheating temperature and heating rate were found to have
an important effect on the biocompatibility in-vivo of the synthesized
products. Max. fibrotic tissue within the porous implant was found in
vivo periods (6 months), in which compacting pressure 100MPa.
Abstract: Application of nanoparticles as additives in membrane
synthesis for improving the resistance of membranes against fouling
has triggered recent interest in new membrane types. However, most
nanoparticle-enhanced membranes suffer from the tradeoff between
permeability and selectivity. In this study, nano-WS2 was explored as
the additive in membrane synthesis by non-solvent induced phase
separation. Blended PES-WS2 flat-sheet membranes with the
incorporation of ultra-low concentrations of nanoparticles (from 0.025
to 0.25%, WS2/PES ratio) were manufactured and investigated in
terms of permeability, fouling resistance and solute rejection.
Remarkably, a significant enhancement in the permeability was
observed as a result of the incorporation of ultra-low fractions of
nano-WS2 to the membrane structure. Optimal permeability values
were obtained for modified membranes with 0.10%
nanoparticle/polymer concentration ratios. Furthermore, fouling
resistance and solute rejection were significantly improved by the
incorporation of nanoparticles into the membrane matrix. Specifically,
fouling resistance of modified membrane can increase by around 50%.
Abstract: The conceptually construction of axially chiral indolostilbenesi.eN-(2-{(E)-2-[2'-(1-Acetyl-1H-indol-2-yl)-3'chloro-4,4',6,6'-tetramethoxy[1,1'-biphenyl]-2yl]ethenyl}phenyl)acetamide and N-(2-{(E)-2-[2'-(1-Acetyl-1H-indol-2-yl)-3'-chloro-2,4',6,6'-tetramethoxy[1,1'-biphenyl]-4-yl]ethenyl}phenyl) acetamide are described in this paper. These structure, were obtained by the tactical combination of palladium-catalyzed coupling which produced 10-acetamido-3,5-dimethoxystilbene, follow by FeCl3-induced oxidative cyclization/dimerisation. All structures were unambiguously confirmed by 1D (1H, 13C) and 2D NMR experiment, (COSY, HMQC, HMBC) and mass spectrometry.
Abstract: Fast delay estimation methods, as opposed to
simulation techniques, are needed for incremental performance
driven layout synthesis. On-chip inductive effects are becoming
predominant in deep submicron interconnects due to increasing clock
speed and circuit complexity. Inductance causes noise in signal
waveforms, which can adversely affect the performance of the circuit
and signal integrity. Several approaches have been put forward which
consider the inductance for on-chip interconnect modelling. But for
even much higher frequency, of the order of few GHz, the shunt
dielectric lossy component has become comparable to that of other
electrical parameters for high speed VLSI design. In order to cope up
with this effect, on-chip interconnect has to be modelled as
distributed RLCG line. Elmore delay based methods, although
efficient, cannot accurately estimate the delay for RLCG interconnect
line. In this paper, an accurate analytical delay model has been
derived, based on first and second moments of RLCG
interconnection lines. The proposed model considers both the effect
of inductance and conductance matrices. We have performed the
simulation in 0.18μm technology node and an error of as low as less
as 5% has been achieved with the proposed model when compared to
SPICE. The importance of the conductance matrices in interconnect
modelling has also been discussed and it is shown that if G is
neglected for interconnect line modelling, then it will result an delay
error of as high as 6% when compared to SPICE.