Abstract: There have been many reports of the destructive effects of cement on the environment in recent years. In the present research, it has been attempted to reduce the destructive effects of cement by replacing silica fume as adhesive materials instead of cement. The present study has attempted to improve the mechanical properties of cement slurry by using waste material from a glass production factory, located in Qazvin city of Iran, in which accumulation volume has become an environmental threat. The chemical analysis of the waste material indicates that this material contains about 94% of SiO2 and AL2O3 and has a close structure to silica fume. Also, the particle grain size test was performed on the mentioned waste. Then, the unconfined compressive strength test of the slurry was performed by preparing a mixture of water and adhesives with different percentages of cement and silica fume. The water to an adhesive ratio of this mixture is 1:3, and the curing process last 28 days. It was found that the sample had an unconfined compressive strength of about 300 kg/cm2 in a mixture with equal proportions of cement and silica fume. Besides, the sample had a brittle fracture in the slurry sample made of pure cement, however, the fracture in cement-silica fume slurry mixture is flexible and the structure of the specimen remains coherent after fracture. Therefore, considering the flexibility that is achieved by replacing this waste, it can be used to stabilize soils with cracking potential.
Abstract: The aim of the present study is to investigate the changes in the mechanical properties of mortars including additions of Condensed Silica Fume (CSF), Hydrated Lime (CH) or both at various amounts (5% to 15% of cement replacement) and high water ratios (w/b) (0.4 to 0.7). The physical and mechanical changes in the mixes were evaluated using non-destructive tests (Ultrasonic Pulse Velocity (UPV)) and destructive tests (crushing tests) on 28 day-long specimens consecutively, in order to assess CSF and CH replacement rate influence on the mechanical and physical properties of the mortars, as well as CSF-CH pre-mixing on the improvement of these properties. A significant improvement of the mechanical properties of the CSF, CSF-CH mortars, has been noted. CSF-CH mixes showed the best improvements exceeding 50% improvement, showing the sizable pozzolanic reaction contribution to the specimen strength development. UPV tests have shown increased velocities for CSF and CSH mixes, however no proportional evolution with compressive strengths could be noted. The results of the study show that CSF-CH addition could represent a suitable solution to significantly increase the mechanical properties of mortars.
Abstract: The exemplary mechanical performance and durability of ultra-high performance concrete (UHPC) has led to its rapid emergence as an advanced cementitious material. The uncharacteristically high mechanical strength and ductility of UHPC makes it a promising potential material for defense structures which may be subject to highly dynamic loads like impact or blast. However, the mechanical response of UHPC under dynamic loading has not been fully characterized. In particular, there is a need to characterize the energy absorption of UHPC under high-frequency shear loading. This paper presents preliminary results from a parametric study of the dynamic shear energy absorption of UHPC using the Charpy impact test. UHPC mixtures with compressive strengths in the range of 100-150 MPa exhibited dynamic shear energy absorption in the range of 0.9-1.5 kJ/m. Energy absorption is shown to be sensitive to the water/cement ratio, silica fume content, and aggregate gradation. Energy absorption was weakly correlated to compressive strength. Results are highly sensitive to specimen preparation methods, and there is a demonstrated need for a standardized test method for high frequency shear in cementitious composites.
Abstract: Thermal insulating composites help to reduce the total power consumption in a building by creating a barrier between external and internal environment. Such composites can be used in the roofing tiles or wall panels for exterior surfaces. This study purposes to develop lightweight cement-based composites for thermal insulating applications. Waste materials like silica fume (an industrial by-product) and fly ash cenosphere (FAC) (hollow micro-spherical shells obtained as a waste residue from coal fired power plants) were used as partial replacement of cement and lightweight filler, respectively. Moreover, aerogel, a nano-porous material made of silica, was also used in different dosages for improved thermal insulating behavior, while poly vinyl alcohol (PVA) fibers were added for enhanced toughness. The raw materials including binders and fillers were characterized by X-Ray Diffraction (XRD), X-Ray Fluorescence spectroscopy (XRF), and Brunauer–Emmett–Teller (BET) analysis techniques in which various physical and chemical properties of the raw materials were evaluated like specific surface area, chemical composition (oxide form), and pore size distribution (if any). Ultra-lightweight cementitious composites were developed by varying the amounts of FAC and aerogel with 28-day unit weight ranging from 1551.28 kg/m3 to 1027.85 kg/m3. Excellent mechanical and thermal insulating properties of the resulting composites were obtained ranging from 53.62 MPa to 8.66 MPa compressive strength, 9.77 MPa to 3.98 MPa flexural strength, and 0.3025 W/m-K to 0.2009 W/m-K as thermal conductivity coefficient (QTM-500). The composites were also tested for peak temperature difference between outer and inner surfaces when subjected to heating (in a specially designed experimental set-up) by a 275W infrared lamp. The temperature difference up to 16.78 oC was achieved, which indicated outstanding properties of the developed composites to act as a thermal barrier for building envelopes. Microstructural studies were carried out by Scanning Electron Microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDS) for characterizing the inner structure of the composite specimen. Also, the hydration products were quantified using the surface area mapping and line scale technique in EDS. The microstructural analyses indicated excellent bonding of FAC and aerogel in the cementitious system. Also, selective reactivity of FAC was ascertained from the SEM imagery where the partially consumed FAC shells were observed. All in all, the lightweight fillers, FAC, and aerogel helped to produce the lightweight composites due to their physical characteristics, while exceptional mechanical properties, owing to FAC partial reactivity, were achieved.
Abstract: The aim of this article is to access the optimal mix design of self-compacting light weight concrete. The effects of magnetic water, superplasticizer based on polycarboxylic-ether, and silica fume on characteristics of this type of concrete are studied. The workability of fresh concrete and the compressive strength of hardened concrete are considered here. For this purpose, nine mix designs were studied. The percentages of superplasticizer were 0.5, 1, and 2% of the weight of cement, and the percentages of silica fume were 0, 6, and 10% of the weight of cement. The water to cementitious ratios were 0.28, 0.32, and 0.36. The workability of concrete samples was analyzed by the devices such as slump flow, V-funnel, L box, U box, and Urimet with J ring. Then, the compressive strengths of the mixes at the ages of 3, 7, 28, and 90 days were obtained. The results show that by using magnetic water, the compressive strengths are improved at all the ages. In the concrete samples with ordinary water, more superplasticizer dosages were needed. Moreover, the combination of superplasticizer and magnetic water had positive effects on the mixes containing silica fume and they could flow easily.
Abstract: Concrete is an essential building material which is
widely used in construction industry all over the world due to its
compressible strength. Curing of concrete plays a vital role in
durability and other performance necessities. Improper curing can
affect the concrete performance and durability easily. When areas
like scarcity of water, structures is not accessible by humans external
curing cannot be performed, so we opt for internal curing. Internal
curing (or) self curing plays a major role in developing the concrete
pore structure and microstructure. The concept of internal curing is to
enhance the hydration process to maintain the temperature uniformly.
The evaporation of water in the concrete is reduced by self curing
agent (Super Absorbing Polymer – SAP) there by increasing the
water retention capacity of the concrete. The research work was
carried out to reduce water, which is prime material used for concrete
in the construction industry. Concrete curing plays a major role in
developing hydration process. Concept of self curing will reduce the
evaporation of water from concrete. Self curing will increase water
retention capacity as compared to the conventional concrete. Proper
self curing (or) internal curing increases the strength, durability and
performance of concrete. Super absorbing Polymer (SAP) used as
internal curing agent. In this study 0.2% to 0.4% of SAP was varied
in different grade of high strength concrete. In the experiment
replacement of cement by silica fumes with 5%, 10% and 15% are
studied. It is found that replacement of silica fumes by 10 % gives
more strength and durability when compared to others.
Abstract: High temperature is one of the most detrimental
effects that cause important changes in concrete’s mechanical,
physical, and thermo-physical properties. As a result of these
changes, especially high strength concrete (HSC), may exhibit
damages such as cracks and spallings. To overcome this problem,
incorporating polymer fibers such as polypropylene (PP) in concrete
is a very well-known method. In this study, using RRH, as a
sustainable material, instead of PP fiber in HSC to prevent spallings
and improve physical and thermo-physical properties were
investigated. Therefore, seven HSC mixtures with 0.25 water to
binder ratio were prepared incorporating silica fume and blast furnace
slag. PP and RRH were used at 0.2-0.5% and 0.5-3% by weight of
cement, respectively. All specimens were subjected to high
temperatures (20 (control), 300, 600 and 900˚C) with a heating rate
of 2.5˚C/min and after cooling, residual physical and thermo-physical
properties were determined.
Abstract: Concrete durability as an important engineering property of concrete, determining the service life of concrete structures very significantly, can be threatened and even lost due to the interactions of concrete with external environment. Bio-corrosion process caused by presence and activities of microorganisms producing sulphuric acid is a special type of sulphate deterioration of concrete materials. The effects of sulphur-oxidizing bacteria Acidithiobacillus thiooxidans on various concrete samples, based on silica fume and zeolite, were investigated in laboratory during 180 days. A laboratory study was conducted to compare the performance of concrete samples in terms of the concrete deterioration influenced by the leaching of calcium and silicon compounds from the cement matrix. The changes in the elemental concentrations of calcium and silicon in both solid samples and liquid leachates were measured by using X – ray fluorescence method. Experimental studies confirmed the silica fume based concrete samples were found out to have the best performance in terms of both silicon and calcium ions leaching.
Abstract: Structural lightweight concrete is used primarily to reduce the dead-load weight in concrete members such as floors in high-rise buildings and bridge decks. With given materials, it is generally desired to have the highest possible strength/unit weight ratio with the lowest cost of concrete. The work presented herein is part of an ongoing research project that investigates the properties of concrete mixes containing locally available Scoria lightweight aggregates and mineral admixtures. Properties considered included: workability, unit weight, compressive strength, and splitting tensile strength. Test results indicated that developing structural lightweight concretes (SLWC) using locally available Scoria lightweight aggregates and specific blends of silica fume and fly ash seems to be feasible. The stress-strain diagrams plotted for the structural LWC mixes developed in this investigation were comparable to a typical stress-strain diagram for normal weight concrete with relatively larger strain capacity at failure in case of LWC.
Abstract: Silica fume, also known as microsilica (MS) or
condensed silica fume is a by-product of the production of silicon
metal or ferrosilicon alloys. Silica fume is one of the most effective
pozzolanic additives which could be used for ultrahigh performance
and other types of concrete. Despite the fact, however is not entirely
clear, which amount of silica fume is most optimal for UHPC. Main
objective of this experiment was to find optimal amount of silica
fume for UHPC with and without thermal treatment, when different
amount of quartz powder is substituted by silica fume. In this work
were investigated four different composition of UHPC with different
amount of silica fume. Silica fume were added 0, 10, 15 and 20% of
cement (by weight) to UHPC mixture. Optimal amount of silica fume
was determined by slump, viscosity, qualitative and quantitative
XRD analysis and compression strength tests methods.
Abstract: Several review papers exist in literature related to the concrete containing mineral admixtures; however this paper reviews the durability characteristics of the concrete containing fly ash (FA), silica fume (SF), ground granulated blast furnace slag (GGBS), metakaolin (MK) and rice husk ash (RHA). Durability related properties reviewed include permeability, resistance to sulfate attack, alkali-silica reaction (ASR), carbonation, chloride ion penetration, freezing and thawing, abrasion, fire, acid and efflorescence. From review of existing literature, it is found that permeability of concrete depends upon the content of alumina in mineral admixtures, i.e. higher the alumina content, lesser the permeability which results higher resistance to sulfate and chloride ion penetration. Highly reactive mineral admixtures prevent more ASR and reduce efflorescence. The carbonation increases with the mineral admixtures because higher water binder ratio and lesser content of portlandite in concrete due to pozzolanic reaction. Mineral admixtures require air entrainment except MK and RHA for better resistance to freezing and thawing.
Abstract: Implementing significant advantages in the supply of self-compacting concrete (SCC) is necessary because of the, negative features of SCC. Examples of these features are the ductility problem along with the very high cost of its constituted materials. Silica fume with steel fiber can fix this matter by improving the ductility and decreasing the total cost of SCC by varying the cement ingredients. Many different researchers have found that there have not been enough research carried out on the steel fiber-reinforced self-compacting concrete (SFRSCC) produced with silica fume. This paper inspects both the fresh and the mechanical properties of SFRSCC with silica fume, the fresh qualities where slump flow, slump T50 and V- funnel. While, the mechanical characteristics were the compressive strength, ultrasound pulse velocity (UPV) and elastic modulus of the concrete samples. The experimental results have proven that steel fiber can enhance the mechanical features. In addition, the silica fume within the entire hybrid mix may possibly adapt the fiber dispersion and strengthen deficits due to the fibers. It could also improve the strength plus the bond between the fiber and the matrix with a dense calcium silicate-hydrate gel in SFRSCC. The concluded result was predicted using linear mathematical models and was found to be in great agreement with the experimental results.
Abstract: This paper presents results of an experimental study performed to investigate effect of incorporating silica fume on physico-mechanical properties and durability of resulting fly ash geopolymers. Geopolymer specimens were prepared by activating fly ash incorporated with additional silica fume in the range of 2.5% to 5%, with a mixture of sodium hydroxide and sodium silicate solution having Na2O content of 8%. For studying durability, 10% magnesium sulphate solution was used to immerse the specimens up to a period of 15 weeks during which visual observation, weight changes and strength changes were monitored regularly. Addition of silica fume lowers performance of geopolymer pastes. However, in mortars, addition of silica fume significantly enhanced physico-mechanical properties and durability.
Abstract: Reinforced concrete has good durability and excellent structural performance. But there are cases of early deterioration due to a number of factors, one prominent factor being corrosion of steel reinforcement. The process of corrosion sets in due to ingress of moisture, oxygen and other ingredients into the body of concrete, which is unsound, permeable and absorbent. Cracks due to structural and other causes such as creep, shrinkage, etc also allow ingress of moisture and other harmful ingredients and thus accelerate the rate of corrosion. There are several interactive factors both external and internal, which lead to corrosion of reinforcement and ultimately failure of structures. Suitable addition of mineral admixture like silica fume (SF) in concrete improves the strength and durability of concrete due to considerable improvement in the microstructure of concrete composites, especially at the transition zone. Secondary reinforcement in the form of fibre is added to concrete, which provides three dimensional random reinforcement in the entire mass of concrete. Reinforced concrete beams of size 0.1 m X 0.15 m and length 1m have been cast using M 35 grade of concrete. The beams after curing process were subjected to corrosion process by impressing an external Direct Current (Galvanostatic Method) for a period of 15 days under stressed and unstressed conditions. The corroded beams were tested by applying two point loads to determine the ultimate load carrying capacity and cracking pattern and the results of specimens were compared with that of the companion specimens. Gravimetric method is used to quantify corrosion that has occurred.
Abstract: This paper presents the results of an experimental
investigation carried out to evaluate the shrinkage of High Strength
Concrete. High Strength Concrete is made by partially replacement of
cement by flyash and silica fume. The shrinkage of High Strength
Concrete has been studied using the different types of coarse and fine
aggregates i.e. Sandstone and Granite of 12.5 mm size and Yamuna
and Badarpur Sand. The Mix proportion of concrete is 1:0.8:2.2 with
water cement ratio as 0.30. Superplasticizer dose @ of 2% by weight
of cement is added to achieve the required degree of workability in
terms of compaction factor.
From the test results of the above investigation it can be concluded
that the shrinkage strain of High Strength Concrete increases with
age. The shrinkage strain of concrete with replacement of cement by
10% of Flyash and Silica fume respectively at various ages are more
(6 to 10%) than the shrinkage strain of concrete without Flyash and
Silica fume. The shrinkage strain of concrete with Badarpur sand as
Fine aggregate at 90 days is slightly less (10%) than that of concrete
with Yamuna Sand. Further, the shrinkage strain of concrete with
Granite as Coarse aggregate at 90 days is slightly less (6 to 7%) than
that of concrete with Sand stone as aggregate of same size. The
shrinkage strain of High Strength Concrete is also compared with that
of normal strength concrete. Test results show that the shrinkage
strain of high strength concrete is less than that of normal strength
concrete.
Abstract: A self-compacting concrete (SCC) is the one that can
be placed in the form and can go through obstructions by its own
weight and without the need of vibration. Since its first development
in Japan in 1988, SCC has gained wider acceptance in Japan, Europe
and USA due to its inherent distinct advantages. Although there are
visible signs of its gradual acceptance in the North Africa through its
limited use in construction, Libya has yet to explore the feasibility
and applicability of SCC in new construction. The contributing
factors to this reluctance appear to be lack of any supportive
evidence of its suitability with local aggregates and the harsh
environmental conditions. The primary aim of this study is to explore
the feasibility of using SCC made with local aggregates of Eastern
Province of Libya by examining its basic properties characteristics.
This research consists of: (i) Development of a suitable mix for SCC
such as the effect of water to cement ratio, limestone and silica fume
that would satisfy the requirements of the plastic state; (ii) Casting of
concrete samples and testing them for compressive strength and unit
weight. Local aggregates, cement, admixtures and industrial waste
materials were used in this research.
The significance of this research lies in its attempt to provide
some performance data of SCC made in the Eastern Province of
Libya so as to draw attention to the possible use of SCC.
Abstract: Natural pozzolan (NP) is one of the potential
prehistoric alternative binders in the construction industry. It has
been investigated as cement replacement in ordinary concrete by
several researchers for many purposes. Various supplementary
cementitious materials (SCMs) such as fly ash, limestone dust and
silica fume are widely used in the production of SCC; however,
limited studies to address the effect of NP on the properties of SCC
are documented. The current research is composed of different SCC
paste and concrete mixtures containing different replacement levels
of local NP as an alternative SCM. The effect of volume of paste
containing different amounts of local NP related to W/B ratio and
cement content on SCC fresh properties was assessed. The variations
in the fresh properties of SCC paste and concrete represented by
slump flow (flowability) and the flow rate were determined and
discussed. The results indicated that the flow properties of SCC paste
and concrete mixtures, at their optimized superplasticizer dosages,
were affected by the binder content of local NP and the total volume
fraction of SCC paste.
Abstract: The main objective of this paper is to determine the
isolated effect of silica fume on tensile, compressive and flexure strengths on high strength lightweight concrete. Many experiments
were carried out by replacing cement with different percentages of silica fume at different constant water-binder ratio keeping other mix
design variables constant. The silica fume was replaced by 0%, 5%,
10%, 15%, 20% and 25% for a water-binder ratios ranging from 0.26
to 0.42. For all mixes, split tensile, compressive and flexure strengths
were determined at 28 days. The results showed that the tensile, compressive and flexure strengths increased with silica fume incorporation but the optimum replacement percentage is not
constant because it depends on the water–cementitious material (w/cm) ratio of the mix. Based on the results, a relationship between
split tensile, compressive and flexure strengths of silica fume concrete was developed using statistical methods.
Abstract: High strength concrete has been used in situations
where it may be exposed to elevated temperatures. Numerous authors
have shown the significant contribution of polypropylene fiber to the
spalling resistance of high strength concrete.
When cement-based composite that reinforced by polypropylene
fibers heated up to 170 °C, polypropylene fibers readily melt and
volatilize, creating additional porosity and small channels in to the
matrix that cause the poor structure and low strength.
This investigation develops on the mechanical properties of mortar
incorporating polypropylene fibers exposed to high temperature.
Also effects of different pozzolans on strength behaviour of samples
at elevated temperature have been studied.
To reach this purpose, the specimens were produced by partial
replacement of cement with finely ground glass, silica fume and rice
husk ash as high reactive pozzolans. The amount of this replacement
was 10% by weight of cement to find the effects of pozzolans as a
partial replacement of cement on the mechanical properties of
mortars. In this way, lots of mixtures with 0%, 0.5%, 1% and 1.5% of
polypropylene fibers were cast and tested for compressive and
flexural strength, accordance to ASTM standard. After that
specimens being heated to temperatures of 300, 600 °C, respectively,
the mechanical properties of heated samples were tested.
Mechanical tests showed significant reduction in compressive
strength which could be due to polypropylene fiber melting. Also
pozzolans improve the mechanical properties of sampels.
Abstract: Steel corrosion in concrete is considered as a main
engineering problems for many countries and lots of expenses has been paid for their repair and maintenance annually. This problem
may occur in all engineering structures whether in coastal and offshore or other areas. Hence, concrete structures should be able to
withstand corrosion factors existing in water or soil. Reinforcing
steel corrosion enhancement can be measured by use of concrete
electrical resistance; and maintaining high electric resistivity in concrete is necessary for steel corrosion prevention. Lots of studies
devoted to different aspects of the subjects worldwide. In this paper, an evaluation of the effects of W/C ratio, cementitious materials, and
percent increase in silica fume were investigated on electric resistivity of high strength concrete. To do that, sixteen mix design
with one aggregate grading was planned. Five of them had varying amount of W/C ratio and other eleven mixes was prepared with
constant W/C ratio but different amount of cementitious materials.
Silica fume and super plasticizer were used with different proportions
in all specimens. Specimens were tested after moist curing for 28 days. A total of 80 cube specimens (50 mm) were tested for concrete
electrical resistance. Results show that concrete electric resistivity can be increased with increasing amount of cementitious materials
and silica fume.