Abstract: Composite metal–polymer materials, in particular titanium alloy (Ti-6Al-4V) to polyamide (PA6.6), fabricated by laser joining, have gained cogent interest among industries and researchers concerned with aerospace and biomedical applications. This work adopts infrared (IR) thermography technique to investigate effects of laser parameters used in the welding process on the three-dimensional temperature profile at the rear-side of titanium, at the region to be welded with polyamide. Cross sectional analysis of welded joints showed correlations between the morphology of titanium and polyamide at the weld zone with the corresponding temperature profile. In particular, spatial temperature profile was found to be correlated with the laser beam energy density, titanium molten pool width and depth, and polyamide heat affected zone depth.
Abstract: Auxetic fibrous structures and composites with negative Poisson’s ratio (NPR) have huge potential for application in ballistic protection due to their high energy absorption and excellent impact resistance. In the present research, re-entrant lozenge auxetic fibrous structures were produced through weft knitting technology using high performance polyamide and para-aramid fibres. Fabric structural parameters (e.g. loop length) and machine parameters (e.g. take down load) were varied in order to investigate their influence on the auxetic behaviours of the produced structures. These auxetic structures were then impregnated with two types of polymeric resins (epoxy and polyester) to produce composite materials, which were subsequently characterized for the auxetic behaviour. It was observed that the knitted fabrics produced using the polyamide yarns exhibited NPR over a wide deformation range, which was strongly dependant on the loop length and take down load. The polymeric composites produced from the auxetic fabrics also showed good auxetic property, which was superior in case of the polyester matrix. The experimental results suggested that these composites made from the auxetic fibrous structures can be properly designed to find potential use in the body amours for personal protection applications.
Abstract: Basic understanding of interfacial mechanisms is of importance for the development of polymer composites. For this purpose, we need techniques to analyze the quality of interphases, their chemical and physical interactions and their strength and fracture resistance. In order to investigate the interfacial phenomena in detail, advanced characterization techniques are favorable. Dynamic mechanical thermal analysis (DMTA) using a rheological system is a sensitive tool. T-peel tests were performed with this system, to investigate the temperature-dependent peel behavior of woven textile composites. A model system was made of polyamide (PA) woven fabric laminated with films of polypropylene (PP) or PP modified by grafting with maleic anhydride (PP-g-MAH). Firstly, control measurements were performed with solely PP matrixes. Polymer melt investigations, as well as the extensional stress, extensional viscosity and extensional relaxation modulus at -10°C, 100 °C and 170 °C, demonstrate similar viscoelastic behavior for films made of PP-g-MAH and its non-modified PP-control. Frequency sweeps have shown that PP-g-MAH has a zero phase viscosity of around 1600 Pa·s and PP-control has a similar zero phase viscosity of 1345 Pa·s. Also, the gelation points are similar at 2.42*104 Pa (118 rad/s) and 2.81*104 Pa (161 rad/s) for PP-control and PP-g-MAH, respectively. Secondly, the textile composite was analyzed. The extensional stress of PA66 fabric laminated with either PP-control or PP-g-MAH at -10 °C, 25 °C and 170 °C for strain rates of 0.001 – 1 s-1 was investigated. The laminates containing the modified PP need more stress for T-peeling. However, the strengthening effect due to the modification decreases by increasing temperature and at 170 °C, just above the melting temperature of the matrix, the difference disappears. Independent of the matrix used in the textile composite, there is a decrease of extensional stress by increasing temperature. It appears that the more viscous is the matrix, the weaker the laminar adhesion. Possibly, the measurement is influenced by the fact that the laminate becomes stiffer at lower temperatures. Adhesive lap-shear testing at room temperature supports the findings obtained with the T-peel test. Additional analysis of the textile composite at the microscopic level ensures that the fibers are well embedded in the matrix. Atomic force microscopy (AFM) imaging of a cross section of the composite shows no gaps between the fibers and matrix. Measurements of the water contact angle show that the MAH grafted PP is more polar than the virgin-PP, and that suggests a more favorable chemical interaction of PP-g-MAH with PA, compared to the non-modified PP. In fact, this study indicates that T-peel testing by DMTA is a technique to achieve more insights into polymeric textile composites.
Abstract: The current study aims to investigate the effect of fillers with different geometries and sizes on the interfacial shear properties of PA6 composites with de-sized carbon fiber. The fillers which have been investigated are namely; nano-layer silicates (nanoclay), sub-micro aluminum titanium (ALTi) particles, and multiwall carbon nanotube (MWCNT). By means of X-ray photoelectron spectroscopy (XPS), epoxide group which defined as a sizing agent, has been removed. Sizing removal can reduce the acid parameter of carbon fibers surface promoting bonding strength at the fiber/matrix interface which is a desirable property for the carbon fiber composites. Microdroplet test showed that the interfacial shear strength (IFSS) has been enhanced with the addition of 10wt% ALTi by about 23% comparing with neat PA6. However, with including other types of fillers into PA6, the results did not show enhancement of IFSS.
Abstract: Nanocomposites based on polypropylene/polyamide 66 (PP/PA66) nanoblends containing organophilic montmorillonite (OMMT) and maleic anhydride grafted polypropylene (PP-g-MAH) were prepared by melt compounding method followed by injection molding. Two different types of nanoclays were used in this work. DELLITE LVF is the untreated nanoclay and DELLITE 67G is the treated one. The morphology of the nanocomposites was studied using the XR diffraction (XRD). The results indicate that the incorporation of treated nanoclay has a significant effect on the impact strength of PP/PA66 nanocomposites. Furthermore, it was found that XRD results revealed the intercalation, exfoliation of nanaclays of nanocomposites.
Abstract: This work aims to investigate the structure–property
relationship in ternary nanocomposites consisting of polypropylene
as the matrix, polyamide 66 as the minor phase and treated nanoclay
DELLITE 67G as the reinforcement. All PP/PA66/Nanoclay systems
with polypropylene grafted maleic anhydride PP-g-MAH as a
compatibilizer were prepared via melt compounding and
characterized in terms of nanoclay content. Morphological structure
was investigated by scanning electron microscopy. The rheological
behavior of the nanocomposites was determined by various methods,
viz melt flow index (MFI) and parallel plate rheological
measurements. The PP/PP-g-MAH/PA66 nanocomposites showed a homogeneous
morphology supporting the compatibility improvement between PP,
PA66, and nanoclay. SEM results revealed the formation of
nanocomposites as the nanoclay was intercalated and exfoliated. In
the ternary nanocomposites, the rheological behavior showed that, the
complex viscosity is increased with increasing the nanoclay. The results showed that the use of nanoclay affects the variations
of storage modulus (G′), loss modulus (G″) and the melt elasticity.
Abstract: The development of composite materials and the
related design and manufacturing technologies is one of the most
important advances in the history of materials. Composites are
multifunctional materials having unprecedented mechanical and
physical properties that can be tailored to meet the requirements of a
particular application. Some composites also exhibit great resistance
to high-temperature corrosion, oxidation, and wear. Polymers are
widely used indoors and outdoors, therefore they are exposed to a
chemical environment which may include atmospheric oxygen, acidic
fumes, acidic rain, moisture heat and thermal shock, ultra-violet light,
high energy radiation, etc. Different polymers are affected differently
by these factors even though the amorphous polymers are more
sensitive. Ageing is also important and it is defined as the process of
deterioration of engineering materials resulting from the combined
effects of atmospheric radiation, heat, oxygen, water, microorganisms
and other atmospheric factors.
Abstract: Below-knee amputees commonly experience
asymmetrical gait patterns. It is generally believed that ischemia is
related to the formation of pressure sores due to uneven distribution
of forces. Micro-vascular responses can reveal local malnutrition.
Changes in local skin blood supply under various external loading
conditions have been studied for a number of years. Radionuclide
clearance, photo-plethysmography, trans-cutaneous oxygen tension
along with other studies showed that the blood supply would be
influenced by the epidermal forces, and the rate and the amount of
blood supply would decrease with increased epidermal loads being
shear forces or normal forces. Several cases of socket designs were
investigated using Finite Element Model (FEM) and Design of
Experiment (DOE) to increase flexibility and minimize the pressure
at the limb/socket interface using ultra high molecular weight
polyethylene (UHMWPE) and polyamide 6 (PA6) or Duraform. The
pressure reliefs at designated areas where reducing thickness is
involved are seen to be critical in determination of amputees’ comfort
and are very important to clinical applications. Implementing a hole
between the Patellar Tendon (PT) and Distal Tibia (DT) would
decrease stiffness and increase prosthesis range of motion where
flexibility is needed. In addition, displacement and prosthetic energy
storage increased without compromising mechanical efficiency and
prosthetic design integrity.
Abstract: Forward Osmosis (FO) polyamide thin-film composite
membranes have been prepared by interfacial polymerization using
commercial UF polyethersulfoneas membrane support. Different
interfacial polymerization times (10s, 30s and 60s) in the organic
solution containing trimesoyl chloride (TMC) at constant m-phenylenediamine
(MPD) concentration (2% w/v) were studied. The
synthesized polyamide membranes then tested for treatment of
natural organic matter (NOM) and compared to commercial Cellulose
TriAcetate (CTA) membrane. It was found that membrane prepared
with higher reaction time (30s and 60s) exhibited better membrane
performance (flux and humic acid removal) over commercial CTA
membrane.
Abstract: Carbon fibers have specific characteristics in
comparison with industrial and structural materials used in different
applications. Special properties of carbon fibers make them attractive
for reinforcing and fabrication of composites. These fibers have been
utilized for composites of metals, ceramics and plastics. However,
it-s mainly used in different forms to reinforce lightweight polymer
materials such as epoxy resin, polyesters or polyamides. The
composites of carbon fiber are stronger than steel, stiffer than
titanium, and lighter than aluminum and nowadays they are used in a
variety of applications. This study explains applications of carbon
fibers in different fields such as space, aviation, transportation,
medical, construction, energy, sporting goods, electronics, and the
other commercial/industrial applications. The last findings of
composites with polymer, metal and ceramic matrices containing
carbon fibers and their applications in the world investigated.
Researches show that carbon fibers-reinforced composites due to
unique properties (including high specific strength and specific
modulus, low thermal expansion coefficient, high fatigue strength,
and high thermal stability) can be replaced with common industrial
and structural materials.
Abstract: This research aimed to modify pineapple leaf paper
(PALP) for using as wet media in the evaporation cooling system by
improving wet mechanical property (tensile strength) without
compromising water absorption property. Polyamideamineepichorohydrin
resin (PAE) and carboxymethylcellulose (CMC)
were used to strengthen the paper, and the PAE and CMC ratio of
80:20 showed the optimum wet and dry tensile index values, which
were higher than those of the commercial cooling pad (CCP).
Compared with CCP, PALP itself and all the PAE/CMC modified
PALP possessed better water absorption. The PAE/CMC modified
PALP had potential to become a new type of wet media.
Abstract: Experiments have been carried out at the Latvia
University of Agriculture Department of Food Technology. The aim
of this work was to assess the effect of thermal treatment in flexible
retort pouch packaging on the quality of potatoes’ produce during the
storage time. Samples were evaluated immediately after retort
thermal treatment; and following 1; 2; 3 and 4 storage months at the
ambient temperature of +18±2ºC in vacuum packaging from
polyamide/polyethylene (PA/PE) and aluminum/polyethylene
(Al/PE) film pouches with barrier properties. Experimentally the
quality of the potatoes’ produce in dry butter and mushroom
dressings was characterized by measuring pH, hardness, color,
microbiological properties and sensory evaluation. The sterilization
was effective in protecting the produce from physical, chemical, and
microbial quality degradation. According to the study of obtained
data, it can be argued that the selected product processing technology
and packaging materials could be applied to provide the safety and
security during four-month storage period.
Abstract: Sport is one of the sectors in which the largest
technical projections regarding the functions of textiles can be found.
He is a large consumer of high performance composite materials and
new fibers. It is one of the sectors where the innovation is the most
important when the greatest numbers of spectacular developments are
aimed at increasing performance. In medicine, textile innovation is
used and contributes in the amelioration of different materials such as
dressing, orthosis, bandages, etc. The hygienic textiles in non-woven
materials record a strong growth. The objective of this study is to
show the different advances of development we obtained in the both
ways (sport and medicine). Polyamide fibers where developed
tacking into account the specification of the high level athlete’s
performance like swimming and triathlon (Olympic Games, Brazil
2016). The first textile utilization was for skiing (Olympic Games,
Sotchi 2014). The different textiles technologies where adapted for
medicine.
Abstract: Toughening of polyamide 6 (PA6)/ Nanoclay (NC) nanocomposites with styrene-ethylene/butadiene-styrene copolymer (SEBS) using maleated styrene-ethylene/butadiene-styrene copolymer (mSEBS)/ as a compatibilizer were investigated by blending them in a co-rotating twin-screw extruder. Response surface method of experimental design was used for optimizing the material and processing parameters. Effect of four factors, including SEBS, mSEBS and NC contents as material variables and order of mixing as a processing factor, on toughness of hybrid nanocomposites were studied. All the prepared samples showed ductile behavior and low temperature Izod impact toughness of some of the hybrid nanocomposites demonstrated 900% improvement compared to the PA6 matrix while the modulus showed maximum enhancement of 20% compared to the pristine PA6 resin.
Abstract: Paper presents knowledge about types of test in area
of materials properties of selected methods of rapid prototyping
technologies. In today used rapid prototyping technologies for
production of models and final parts are used materials in initial state
as solid, liquid or powder material structure. In solid state are used
various forms such as pellets, wire or laminates. Basic range
materials include paper, nylon, wax, resins, metals and ceramics. In
Fused Deposition Modeling (FDM) rapid prototyping technology are
mainly used as basic materials ABS (Acrylonitrile Butadiene
Styrene), polyamide, polycarbonate, polyethylene and polypropylene.
For advanced FDM applications are used special materials as silicon
nitrate, PZT (Piezoceramic Material - Lead Zirconate Titanate),
aluminium oxide, hydroxypatite and stainless steel.