Abstract: Composite of Celatom-ZeoliteY (Cel-ZY) was used to
remove cobalt ion from an aqueous solution using batch mode.
ZeoliteY has successfully superimposed on Celatom FW-14 surface
using hydrothermal treatment .The product was synthesized as a
novel of hierarchical porous material. It was observed from the
results that Cel-ZY has higher ability to remove cobalt ions than the
pure ZeoliteY powder (PZY) synthesized under the same conditions.
Several parameters were studied in this project to investigate the
effect of removal cobalt ion such as pH and initial cobalt
concentration. It was clearly observed that the uptake of cobalt ions
was affected with increase these parameters. The results proved that
the product can be used effectively to remove Co2+ ions from
wastewater as an environmentally friendly alternative.
Abstract: In this study, the sorption of Malachite green (MG) on Hydrilla verticillata biomass, a submerged aquatic plant, was investigated in a batch system. The effects of operating parameters such as temperature, adsorbent dosage, contact time, adsorbent size, and agitation speed on the sorption of Malachite green were analyzed using response surface methodology (RSM). The proposed quadratic model for central composite design (CCD) fitted very well to the experimental data that it could be used to navigate the design space according to ANOVA results. The optimum sorption conditions were determined as temperature - 43.5oC, adsorbent dosage - 0.26g, contact time - 200min, adsorbent size - 0.205mm (65mesh), and agitation speed - 230rpm. The Langmuir and Freundlich isotherm models were applied to the equilibrium data. The maximum monolayer coverage capacity of Hydrilla verticillata biomass for MG was found to be 91.97 mg/g at an initial pH 8.0 indicating that the optimum sorption initial pH. The external and intra particle diffusion models were also applied to sorption data of Hydrilla verticillata biomass with MG, and it was found that both the external diffusion as well as intra particle diffusion contributes to the actual sorption process. The pseudo-second order kinetic model described the MG sorption process with a good fitting.
Abstract: Sol-gel method has been used to fabricate
nanocomposite films on glass substrates composed halloysite clay
mineral and nanocrystalline TiO2. The methodology for the synthesis
involves a simple chemistry method utilized nonionic surfactant
molecule as pore directing agent along with the acetic acid-based solgel
route with the absence of water molecules. The thermal treatment
of composite films at 450oC ensures elimination of organic material
and lead to the formation of TiO2 nanoparticles onto the surface of
the halloysite nanotubes. Microscopy techniques and porosimetry
methods used in order to delineate the structural characteristics of the
materials. The nanocomposite films produced have no cracks and
active anatase crystal phase with small crystallite size were deposited
on halloysite nanotubes. The photocatalytic properties for the new
materials were examined for the decomposition of the Basic Blue 41
azo dye in solution. These, nanotechnology based composite films
show high efficiency for dye’s discoloration in spite of different
halloysite quantities and small amount of halloysite/TiO2 catalyst
immobilized onto glass substrates. Moreover, we examined the
modification of the halloysite/TiO2 films with silver particles in order
to improve the photocatalytic properties of the films. Indeed, the
presence of silver nanoparticles enhances the discoloration rate of the
Basic Blue 41 compared to the efficiencies obtained for unmodified
films.
Abstract: High strength concrete has been used in situations
where it may be exposed to elevated temperatures. Numerous authors
have shown the significant contribution of polypropylene fiber to the
spalling resistance of high strength concrete.
When cement-based composite that reinforced by polypropylene
fibers heated up to 170 °C, polypropylene fibers readily melt and
volatilize, creating additional porosity and small channels in to the
matrix that cause the poor structure and low strength.
This investigation develops on the mechanical properties of mortar
incorporating polypropylene fibers exposed to high temperature.
Also effects of different pozzolans on strength behaviour of samples
at elevated temperature have been studied.
To reach this purpose, the specimens were produced by partial
replacement of cement with finely ground glass, silica fume and rice
husk ash as high reactive pozzolans. The amount of this replacement
was 10% by weight of cement to find the effects of pozzolans as a
partial replacement of cement on the mechanical properties of
mortars. In this way, lots of mixtures with 0%, 0.5%, 1% and 1.5% of
polypropylene fibers were cast and tested for compressive and
flexural strength, accordance to ASTM standard. After that
specimens being heated to temperatures of 300, 600 °C, respectively,
the mechanical properties of heated samples were tested.
Mechanical tests showed significant reduction in compressive
strength which could be due to polypropylene fiber melting. Also
pozzolans improve the mechanical properties of sampels.
Abstract: Use of fly ash as a supplementary cementing material
in large volumes can bring both technological and economic benefits
for concrete industry. In this investigation mix proportions for high
volume fly ash concrete were determined at cement replacement
levels of 50%, 55%, 60% and 65% with low calcium fly ash. Flexural
and compressive strengths of different mixes were measured at ages
of 7, 28 and 90 days. Flexural strength of composite section prepared
from pavement quality and lean high volume fly ash concrete was
determined at the age of 28 days. High volume fly ash concrete mixes
exhibited higher rate of strength gain and age factors than
corresponding reference concrete mixes. The optimum cement
replacement level for pavement quality concrete was found to be
60%. The consideration of bond between pavement quality and lean
of high volume fly ash concrete will be beneficial in design of rigid
pavements.
Abstract: This paper describes the crashworthiness assessment and improvement of tlting train made of sandwich composites. The crashworhiness assessment of tilting train was conducted according to four collision scenarios of the Korean railway safety law. Collision analysis was carried out using explicit finite element analysis code LS-DYNA 3D. The finite element model consists of 3-D finite element model and 1-D equivalent model to save the finite element modeling and calculation time. It found that the crashworthiness analysis results were satisfied with the performance requirements except the crash scenario-2. In order to meet the crashworthiness requirements for crash scenario-2, the stiffness reinforcement for the laminate composite cover and metal frames of cabmask structure were proposed. Consequentially, it has satisfied the requirement for crash scenario-2.
Abstract: In this study, single nozzle method used for
electrospinning technique which composite polymer solution with
cellulose nanowiskers (CNW) was treated by ultrasonic sonificator
have been compared with coaxial (double) nozzle method, in terms of
mechanical, thermal and morphological properties of composite
nanofiber. The effect of water content in composite polymer solution
on properties of nanofiber has also been examined. It has been seen
that single nozzle method which polymer solution does not contain
water has better results than that of coaxial method, in terms of
mechanical, thermal and morphological properties of nanofiber.
However, it is necessary to make an optimization study on setting
condition of ultrasonic treatment to get better dispersion of CNW in
composite nanofiber and to get better mechanical and thermal
properties
Abstract: Bionanotechnology deals with nanoscopic interactions between nanostructured materials and biological systems. Polymer nanocomposites with optimized biological activity have attracted great attention. Nanoclay is considered as reinforcing nanofiller in manufacturing of high performance nanocomposites. In current study, organomodified-nanoclay with negatively charged silicate layers was incorporated into biomedical grade silicone rubber. Nanoparticle loading has been tailored to enhance cell behavior. Addition of nanoparticles led to improved mechanical properties of substrate with enhanced strength and stiffness while no toxic effects was observed. Results indicated improved viability and proliferation of cells by addition of nanofillers. The improved mechanical properties of the matrix result in proper cell response through adjustment and arrangement of cytoskeletal fibers. Results can be applied in tissue engineering when enhanced substrates are required for improvement of cell behavior for in vivo applications.
Abstract: The machining of Carbon Fiber Reinforced Plastics
has come to constitute a significant challenge for many fields of
industry. The resulting surface finish of machined parts is of primary
concern for several reasons, including contact quality and impact on
the assembly. Therefore, the characterization and prediction of
roughness based on machining parameters are crucial for costeffective
operations. In this study, a PCD tool comprised of two
straight flutes was used to trim 32-ply carbon fiber laminates in a bid
to analyze the effects of the feed rate and the cutting speed on the
surface roughness. The results show that while the speed has but a
slight impact on the surface finish, the feed rate for its part affects it
strongly. A detailed study was also conducted on the effect of fiber
orientation on surface roughness, for quasi-isotropic laminates used
in aerospace. The resulting roughness profiles for the four-ply
orientation lay-up were compared, and it was found that fiber angle is
a critical parameter relating to surface roughness. One of the four
orientations studied led to very poor surface finishes, and
characteristic roughness profiles were identified and found to only
relate to the ply orientations of multilayer carbon fiber laminates.
Abstract: Tribological behavior and wear regimes of ascast
and heattreted Al-Cu-Mg matrix composites containing SiC
particles were studied using a pin-on-disc wear testing apparatus
against an EN32 steel counterface giving emphasis on wear rate as
a function of applied pressures (0.2, 0.6, 1.0 and 1.4 MPa) at
different sliding distances (1000, 2000, 3000, 4000 and 5000
meters) and at a fixed sliding speed of 3.35m/s. The results showed
that the composite exhibited lower wear rate than that of the matrix
alloy and the wear rate of the composites is noted to be invariant to
the sliding distance and is reducing by heat treatment. Wear
regimes such as low, mild and severe wear were observed as per the
Archard-s wear calculations. It is very interesting to note that the
mild wear is almost constant in all the wear regimes.
Abstract: The field of biomedical materials plays an imperative
requisite and a critical role in manufacturing a variety of biological
artificial replacements in a modern world. Recently, titanium (Ti)
materials are being used as biomaterials because of their superior
corrosion resistance and tremendous specific strength, free- allergic
problems and the greatest biocompatibility compared to other
competing biomaterials such as stainless steel, Co-Cr alloys,
ceramics, polymers, and composite materials. However, regardless of
these excellent performance properties, Implantable Ti materials have
poor shear strength and wear resistance which limited their
applications as biomaterials. Even though the wear properties of Ti
alloys has revealed some improvements, the crucial effectiveness of
biomedical Ti alloys as wear components requires a comprehensive
deep understanding of the wear reasons, mechanisms, and techniques
that can be used to improve wear behavior. This review examines
current information on the effect of thermal and thermomechanical
processing of implantable Ti materials on the long-term prosthetic
requirement which related with wear behavior. This paper focuses
mainly on the evolution, evaluation and development of effective
microstructural features that can improve wear properties of bio
grade Ti materials using thermal and thermomechanical treatments.
Abstract: This paper describes the optimization of a complex
dairy farm simulation model using two quite different methods of
optimization, the Genetic algorithm (GA) and the Lipschitz
Branch-and-Bound (LBB) algorithm. These techniques have been
used to improve an agricultural system model developed by Dexcel
Limited, New Zealand, which describes a detailed representation of
pastoral dairying scenarios and contains an 8-dimensional parameter
space. The model incorporates the sub-models of pasture growth and
animal metabolism, which are themselves complex in many cases.
Each evaluation of the objective function, a composite 'Farm
Performance Index (FPI)', requires simulation of at least a one-year
period of farm operation with a daily time-step, and is therefore
computationally expensive. The problem of visualization of the
objective function (response surface) in high-dimensional spaces is
also considered in the context of the farm optimization problem.
Adaptations of the sammon mapping and parallel coordinates
visualization are described which help visualize some important
properties of the model-s output topography. From this study, it is
found that GA requires fewer function evaluations in optimization
than the LBB algorithm.
Abstract: This paper deals with a new way for designing
external fixators applied in traumatology and orthopaedics. These
fixators can be applied in the treatment of open and unstable
fractures or for lengthening human or animal bones etc. The new
design is based on the development of Ilizarov and other techniques
(i.e. shape and weight optimalization based on composite materials,
application of smart materials, nanotechnology, low x-ray absorption,
antibacterial protection, patient's comfort, reduction in the duration
of the surgical treatment, and cost).
Abstract: Lipases are enzymes particularly amenable for
immobilization by entrapment methods, as they can work equally
well in aqueous or non-conventional media and long-time stability of
enzyme activity and enantioselectivity is needed to elaborate more
efficient bioprocesses. The improvement of Pseudomonas
fluorescens (Amano AK) lipase characteristics was investigated by
optimizing the immobilization procedure in hybrid organic-inorganic
matrices using ionic liquids as additives. Ionic liquids containing a
more hydrophobic alkyl group in the cationic moiety are beneficial
for the activity of immobilized lipase. Silanes with alkyl- or aryl
nonhydrolizable groups used as precursors in combination with
tetramethoxysilane could generate composites with higher
enantioselectivity compared to the native enzyme in acylation
reactions of secondary alcohols. The optimal effect on both activity
and enantioselectivity was achieved for the composite made from
octyltrimethoxysilane and tetramethoxysilane at 1:1 molar ratio (60%
increase of total activity following immobilization and enantiomeric
ratio of 30). Ionic liquids also demonstrated valuable properties as
reaction media for the studied reactions, comparable with the usual
organic solvent, hexane.
Abstract: Studies on Simultaneous Saccharification and Fermentation (SSF) of corn flour, a major agricultural product as the substrate using starch digesting glucoamylase enzyme derived from Aspergillus niger and non starch digesting and sugar fermenting Saccharomyces cerevisiae in a batch fermentation. Experiments based on Central Composite Design (CCD) were conducted to study the effect of substrate concentration, pH, temperature, enzyme concentration on Ethanol Concentration and the above parameters were optimized using Response Surface Methodology (RSM). The optimum values of substrate concentration, pH, temperature and enzyme concentration were found to be 160 g/l, 5.5, 30°C and 50 IU respectively. The effect of inoculums age on ethanol concentration was also investigated. The corn flour solution equivalent to 16% initial starch concentration gave the highest ethanol concentration of 63.04 g/l after 48 h of fermentation at optimum conditions of pH and temperature. Monod model and Logistic model were used for growth kinetics and Leudeking – Piret model was used for product formation kinetics.
Abstract: Novel acrylated epoxidized hemp oil (AEHO) based
bioresins were successfully synthesised, characterized and applied to
biocomposites reinforced with woven jute fibre. Characterisation of
the synthesised AEHO consisted of acid number titrations and FTIR
spectroscopy to assess the success of the acrylation reaction. Three
different matrices were produced (vinylester (VE), 50/50 blend of
AEHO/VE and 100% AEHO) and reinforced with jute fibre to form
three different types of biocomposite samples. Mechanical properties
in the form of flexural and interlaminar shear strength (ILSS) were
investigated and compared for the different samples. Results from the
mechanical tests showed that AEHO and 50/50 based neat bioresins
displayed lower flexural properties compared with the VE samples.
However when applied to biocomposites and compared with VE
based samples, AEHO biocomposites demonstrated comparable
flexural performance and improved ILSS. These results are attributed
to improved fibre-matrix interfacial adhesion due to surface-chemical
compatibility between the natural fibres and bioresin.
Abstract: The aim of our work is to study phase composition,
particle size and magnetic response of Fe2O3/TiO2 nanocomposites
with respect to the final annealing temperature. Those nanomaterials
are considered as smart catalysts, separable from a liquid/gaseous
phase by applied magnetic field. The starting product was obtained
by an ecologically acceptable route, based on heterogeneous
precipitation of the TiO2 on modified g-Fe2O3 nanocrystals dispersed
in water. The precursor was subsequently annealed on air at
temperatures ranging from 200 oC to 900 oC. The samples were
investigated by synchrotron X-ray powder diffraction (S-PXRD),
magnetic measurements and Mössbauer spectroscopy. As evidenced
by S-PXRD and Mössbauer spectroscopy, increasing the annealing
temperature causes evolution of the phase composition from
anatase/maghemite to rutile/hematite, finally above 700 oC the
pseudobrookite (Fe2TiO5) also forms. The apparent particle size of
the various Fe2O3/TiO2 phases has been determined from the highquality
S-PXRD data by using two different approaches: the Rietveld
refinement and the Debye method. Magnetic response of the samples
is discussed in considering the phase composition and the particle
size.
Abstract: The objective of this paper is to construct a creativity
composite index designed to capture the growing role of creativity in
driving economic and social development for the 27 European Union
countries.
The paper proposes a new approach for the measurement of EU-27
creative potential and for determining its capacity to attract and
develop creative human capital. We apply a modified version of the
3T model developed by Richard Florida and Irene Tinagli for
constructing a Euro-Creativity Index. The resulting indexes establish
a quantitative base for policy makers, supporting their efforts to
determine the contribution of creativity to economic development.
Abstract: Structural behavior of ring stiffened thick walled
cylinders made of functionally graded materials (FGMs) is
investigated in this paper. Functionally graded materials are inhomogeneous composites which are usually made from a mixture
of metal and ceramic. The gradient compositional variation of the
constituents from one surface to the other provides an elegant solution to the problem of high transverse shear stresses that are
induced when two dissimilar materials with large differences in material properties are bonded. FGM formation of the cylinder is
modeled by power-law exponent and the variation of characteristics is supposed to be in radial direction.
A finite element formulation is derived for the analysis. According to the property variation of the constituent materials in the radial
direction of the wall, it is not convenient to use conventional elements to model and analyze the structure of the stiffened FGM
cylinders. In this paper a new cylindrical super-element is used to model the finite element formulation and analyze the static and
modal behavior of stiffened FGM thick walled cylinders. By using
this super-element the number of elements, which are needed for
modeling, will reduce significantly and the process time is less in comparison with conventional finite element formulations. Results for static and modal analysis are evaluated and verified by
comparison to finite element formulation with conventional
elements. Comparison indicates a good conformity between results.
Abstract: The term hybrid composite refers to the composite
containing more than one type of fiber material as reinforcing fillers.
It has become attractive structural material due to the ability of
providing better combination of properties with respect to single fiber
containing composite. The eco-friendly nature as well as processing
advantage, light weight and low cost have enhanced the attraction
and interest of natural fiber reinforced composite. The objective of
present research is to study the mechanical properties of jute-coir
fiber reinforced hybrid polypropylene (PP) composite according to
filler loading variation. In the present work composites were
manufactured by using hot press machine at four levels of fiber
loading (5, 10, 15 and 20 wt %). Jute and coir fibers were utilized at a
ratio of (1:1) during composite manufacturing. Tensile, flexural,
impact and hardness tests were conducted for mechanical
characterization. Tensile test of composite showed a decreasing trend
of tensile strength and increasing trend of the Young-s modulus with
increasing fiber content. During flexural, impact and hardness tests,
the flexural strength, flexural modulus, impact strength and hardness
were found to be increased with increasing fiber loading. Based on
the fiber loading used in this study, 20% fiber reinforced composite
resulted the best set of mechanical properties.