Abstract: Due to the need for a rigorous mathematical model that can help to estimate kinetic properties for soluble-insoluble systems, through voltammetric experiments, a Nicholson Semi Analytical Approach was used in this work for modeling and prediction of theoretical linear sweep voltammetry responses for reversible, quasi reversible or irreversible electron transfer reactions. The redox system of interest is a one-step metal electrodeposition process. A rigorous analysis of simulated linear scan voltammetric responses following variation of dimensionless factors, the rate constant and charge transfer coefficients in a broad range was studied and presented in the form of the so called kinetic zones diagrams. These kinetic diagrams were divided into three kinetics zones. Interpreting these zones leads to empirical mathematical models which can allow the experimenter to determine electrodeposition reactions kinetics whatever the degree of reversibility. The validity of the obtained results was tested and an excellent experiment–theory agreement has been showed.
Abstract: the aim of that work is to study the proton transfer
phenomenon which takes place in the elastic scattering of 12C on 11B
at energies near the coulomb barrier. This reaction was studied at four
different energies 16, 18, 22, 24 MeV. The experimental data of the
angular distribution at these energies were compared to the
calculation prediction using the optical potential codes such as
ECIS88 and SPIVAL. For the raising in the cross section at backward
angles due to the transfer process we could use Distorted Wave Born
Approximation (DWUCK5). Our analysis showed that SPIVAL code
with l-dependent imaginary potential could be used effectively.
Abstract: Elastic and inelastic scattering of α-particles by 9Be nuclei at different incident energies have been analyzed. Optical model parameters (OMPs) of α-particles elastic scattering by 9Be at different energies have been obtained. Coupled Reaction Channel (CRC) of elastic scattering, inelastic scattering and transfer reaction has been calculated using Fresco Code. The effect of involving CRC calculations on the analysis of differential cross section has been studied. The transfer reaction of (5He) in the reaction 9Be(α,9Be)α has been studied. The spectroscopic factor of 9Be≡α+5He has been extracted.
Abstract: A microchannel with two inlets and two outlets was tested as a potential reactor to carry out two-phase catalytic phase transfer reaction with phase separation at the exit of the microchannel. The catalytic phase transfer reaction between benzyl chloride and sodium sulfide was chosen as a model reaction. The effect of operational time on the conversion was studied. By utilizing a multiphase parallel flow inside the microchannel reactor with the aid of a guideline structure, the catalytic phase reaction followed by phase separation could be ensured. The organic phase could be separated completely from one exit and part of the aqueous phase was separated purely and could be reused with slightly affecting the catalytic phase transfer reaction.
Abstract: The aim of this work is to study the elastic transfer
phenomenon which takes place in the elastic scattering of 16O on 12C
at energies near the Coulomb barrier. Where, the angular distribution
decrease steadily with increasing the scattering angle, then the cross
section will increase at backward angles due to the α-transfer process.
This reaction was also studied at different energies for tracking the
nuclear rainbow phenomenon. The experimental data of the angular
distribution at these energies were compared to the calculation
predictions. The optical potential codes such as SPIVAL and
Distorted Wave Born Approximation (DWUCK5) were used in
analysis.